TY - JOUR
T1 - Two zinc(II) coordination polymers of tetrazolate-5-carboxylate with self-penetrating three-dimensional nets
T2 - Synthesis, structure, and luminescence properties
AU - Jia, Qin Xiang
AU - Tian, Hua
AU - Gao, En Qing
PY - 2014/7
Y1 - 2014/7
N2 - Two coordination compounds of the ligand tetrazolate-5-carboxylate (tzc) with zinc(II), namely, [Zn2(tzc)2(bpp)] (1) and [Zn 2(tzc)2(bpea)] (2) [bpp = 1,3-bis(4-pyridyl)propane, bpea = 1,2-bis(4-pyridyl)ethane] were synthesized by hydrothermal methods involving the in situ generation of the ligand from sodium ethyl tetrazolate-5- carboxylate. Both compounds 1 and 2 exhibit a three-dimensional structure with 3,4-connected self-penetrating net topology in which two-dimensional Zn II-tzc layers are interlinked by the bpp or bpea spacers, with the tzc ligand being in the μ3-N1,O1:N4,O2:N2 coordination mode. The luminescence properties of 1 and 2 were also investigated.
AB - Two coordination compounds of the ligand tetrazolate-5-carboxylate (tzc) with zinc(II), namely, [Zn2(tzc)2(bpp)] (1) and [Zn 2(tzc)2(bpea)] (2) [bpp = 1,3-bis(4-pyridyl)propane, bpea = 1,2-bis(4-pyridyl)ethane] were synthesized by hydrothermal methods involving the in situ generation of the ligand from sodium ethyl tetrazolate-5- carboxylate. Both compounds 1 and 2 exhibit a three-dimensional structure with 3,4-connected self-penetrating net topology in which two-dimensional Zn II-tzc layers are interlinked by the bpp or bpea spacers, with the tzc ligand being in the μ3-N1,O1:N4,O2:N2 coordination mode. The luminescence properties of 1 and 2 were also investigated.
KW - 3,4-Connected self-penetrating
KW - Hydrothermal synthesis
KW - Luminescence properties
KW - Zinc
UR - https://www.scopus.com/pages/publications/84904425671
U2 - 10.1002/zaac.201300528
DO - 10.1002/zaac.201300528
M3 - 文章
AN - SCOPUS:84904425671
SN - 0044-2313
VL - 640
SP - 1732
EP - 1736
JO - Zeitschrift fur Anorganische und Allgemeine Chemie
JF - Zeitschrift fur Anorganische und Allgemeine Chemie
IS - 8-9
ER -