Tungsten trioxide promoted selective conversion of cellulose into propylene glycol and ethylene glycol on a ruthenium catalyst

Yue Liu; Chen Luo; Haichao Liu

doi:10.1002/anie.201200351

Tungsten trioxide promoted selective conversion of cellulose into propylene glycol and ethylene glycol on a ruthenium catalyst

Yue Liu, Chen Luo, Haichao Liu

Peking University

Research output: Contribution to journal › Article › peer-review

320 Scopus citations

Abstract

Chopped up: The success of the title reaction strongly depends on the domain size of the WO ₃ crystallites, and the type of support. Structurally stable WO ₃ plays a bifunctional role in the promotion of the hydrolysis of cellulose into sugar intermediates, and more significantly in the selective cleavage of the C-C bonds in these sugars.

Original language	English
Pages (from-to)	3249-3253
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	13
DOIs	https://doi.org/10.1002/anie.201200351
State	Published - 26 Mar 2012
Externally published	Yes

Keywords

cellulose
glycols
heterogeneous catalysis
hydrolysis
tungsten trioxide

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10.1002/anie.201200351

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title = "Tungsten trioxide promoted selective conversion of cellulose into propylene glycol and ethylene glycol on a ruthenium catalyst",

abstract = "Chopped up: The success of the title reaction strongly depends on the domain size of the WO 3 crystallites, and the type of support. Structurally stable WO 3 plays a bifunctional role in the promotion of the hydrolysis of cellulose into sugar intermediates, and more significantly in the selective cleavage of the C-C bonds in these sugars.",

keywords = "cellulose, glycols, heterogeneous catalysis, hydrolysis, tungsten trioxide",

author = "Yue Liu and Chen Luo and Haichao Liu",

year = "2012",

month = mar,

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doi = "10.1002/anie.201200351",

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AU - Liu, Yue

AU - Luo, Chen

AU - Liu, Haichao

PY - 2012/3/26

Y1 - 2012/3/26

N2 - Chopped up: The success of the title reaction strongly depends on the domain size of the WO 3 crystallites, and the type of support. Structurally stable WO 3 plays a bifunctional role in the promotion of the hydrolysis of cellulose into sugar intermediates, and more significantly in the selective cleavage of the C-C bonds in these sugars.

AB - Chopped up: The success of the title reaction strongly depends on the domain size of the WO 3 crystallites, and the type of support. Structurally stable WO 3 plays a bifunctional role in the promotion of the hydrolysis of cellulose into sugar intermediates, and more significantly in the selective cleavage of the C-C bonds in these sugars.

KW - cellulose

KW - glycols

KW - heterogeneous catalysis

KW - hydrolysis

KW - tungsten trioxide

UR - https://www.scopus.com/pages/publications/84863337762

U2 - 10.1002/anie.201200351

DO - 10.1002/anie.201200351

M3 - 文章

C2 - 22368071

AN - SCOPUS:84863337762

SN - 1433-7851

VL - 51

SP - 3249

EP - 3253

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 13

ER -

Tungsten trioxide promoted selective conversion of cellulose into propylene glycol and ethylene glycol on a ruthenium catalyst

Abstract

Keywords

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