Tungsten-doped vo2/starch derivative hybrid nanothermochromic hydrogel for smart window

Yu Wang; Fang Zhao; Jie Wang; Li Li; Kaiqiang Zhang; Yulin Shi; Yanfeng Gao; Xuhong Guo

doi:10.3390/nano9070970

Tungsten-doped vo2/starch derivative hybrid nanothermochromic hydrogel for smart window

Yu Wang
, Fang Zhao^*
, Jie Wang
, Li Li
, Kaiqiang Zhang
, Yulin Shi
, Yanfeng Gao
, Xuhong Guo

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

Highly efficient energy-saving windows with high solar modulation properties (ΔTsol) are the everlasting pursuit of research for industrial applications in the smart window field. Hybridization is an effective means of improving both ΔTsol and luminous transmittance (Tlum). In this paper, hybrid thermochromic films were synthesized using tungsten-doped VO2 nanoparticles (NPs) and starch derivatives. Thermoresponsive 2-hydroxy-3-butoxypropyl starch (HBPS) was prepared with a low critical solution temperature (LCST) varying from 32 to 21 °C by the substitution of reactive groups. The hybrid film was obtained by dispersing W-doped VO2 NPs in HBPS hydrogels, which exhibiting remarkable solar modulation property (ΔTsol = 34.3%) with a high average luminous transmittance (Tlum, average = 53.9%).

Original language	English
Article number	970
Journal	Nanomaterials
Volume	9
Issue number	7
DOIs	https://doi.org/10.3390/nano9070970
State	Published - Jul 2019
Externally published	Yes

Keywords

Inorganic and organic hybrid film
Smart window
Starch derivative
Thermochromism
W-doped VO2 (M) NPs

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10.3390/nano9070970

Cite this

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title = "Tungsten-doped vo2/starch derivative hybrid nanothermochromic hydrogel for smart window",

abstract = "Highly efficient energy-saving windows with high solar modulation properties (ΔTsol) are the everlasting pursuit of research for industrial applications in the smart window field. Hybridization is an effective means of improving both ΔTsol and luminous transmittance (Tlum). In this paper, hybrid thermochromic films were synthesized using tungsten-doped VO2 nanoparticles (NPs) and starch derivatives. Thermoresponsive 2-hydroxy-3-butoxypropyl starch (HBPS) was prepared with a low critical solution temperature (LCST) varying from 32 to 21 °C by the substitution of reactive groups. The hybrid film was obtained by dispersing W-doped VO2 NPs in HBPS hydrogels, which exhibiting remarkable solar modulation property (ΔTsol = 34.3\%) with a high average luminous transmittance (Tlum, average = 53.9\%).",

keywords = "Inorganic and organic hybrid film, Smart window, Starch derivative, Thermochromism, W-doped VO2 (M) NPs",

author = "Yu Wang and Fang Zhao and Jie Wang and Li Li and Kaiqiang Zhang and Yulin Shi and Yanfeng Gao and Xuhong Guo",

note = "Publisher Copyright: {\textcopyright} 2019 by the authors. Licensee MDPI, Basel, Switzerland.",

year = "2019",

month = jul,

doi = "10.3390/nano9070970",

language = "英语",

volume = "9",

journal = "Nanomaterials",

issn = "2079-4991",

publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",

number = "7",

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TY - JOUR

T1 - Tungsten-doped vo2/starch derivative hybrid nanothermochromic hydrogel for smart window

AU - Wang, Yu

AU - Zhao, Fang

AU - Wang, Jie

AU - Li, Li

AU - Zhang, Kaiqiang

AU - Shi, Yulin

AU - Gao, Yanfeng

AU - Guo, Xuhong

PY - 2019/7

Y1 - 2019/7

N2 - Highly efficient energy-saving windows with high solar modulation properties (ΔTsol) are the everlasting pursuit of research for industrial applications in the smart window field. Hybridization is an effective means of improving both ΔTsol and luminous transmittance (Tlum). In this paper, hybrid thermochromic films were synthesized using tungsten-doped VO2 nanoparticles (NPs) and starch derivatives. Thermoresponsive 2-hydroxy-3-butoxypropyl starch (HBPS) was prepared with a low critical solution temperature (LCST) varying from 32 to 21 °C by the substitution of reactive groups. The hybrid film was obtained by dispersing W-doped VO2 NPs in HBPS hydrogels, which exhibiting remarkable solar modulation property (ΔTsol = 34.3%) with a high average luminous transmittance (Tlum, average = 53.9%).

AB - Highly efficient energy-saving windows with high solar modulation properties (ΔTsol) are the everlasting pursuit of research for industrial applications in the smart window field. Hybridization is an effective means of improving both ΔTsol and luminous transmittance (Tlum). In this paper, hybrid thermochromic films were synthesized using tungsten-doped VO2 nanoparticles (NPs) and starch derivatives. Thermoresponsive 2-hydroxy-3-butoxypropyl starch (HBPS) was prepared with a low critical solution temperature (LCST) varying from 32 to 21 °C by the substitution of reactive groups. The hybrid film was obtained by dispersing W-doped VO2 NPs in HBPS hydrogels, which exhibiting remarkable solar modulation property (ΔTsol = 34.3%) with a high average luminous transmittance (Tlum, average = 53.9%).

KW - Inorganic and organic hybrid film

KW - Smart window

KW - Starch derivative

KW - Thermochromism

KW - W-doped VO2 (M) NPs

UR - https://www.scopus.com/pages/publications/85069698092

U2 - 10.3390/nano9070970

DO - 10.3390/nano9070970

M3 - 文章

AN - SCOPUS:85069698092

SN - 2079-4991

VL - 9

JO - Nanomaterials

JF - Nanomaterials

IS - 7

M1 - 970

ER -

Tungsten-doped vo2/starch derivative hybrid nanothermochromic hydrogel for smart window

Abstract

Keywords

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