Tunable-Sized Polymeric Micelles and Their Assembly for the Preparation of Large Mesoporous Platinum Nanoparticles

Bo Jiang; Cuiling Li; Jing Tang; Toshiaki Takei; Jung Ho Kim; Yusuke Ide; Joel Henzie; Satoshi Tominaka; Yusuke Yamauchi

doi:10.1002/anie.201603967

Tunable-Sized Polymeric Micelles and Their Assembly for the Preparation of Large Mesoporous Platinum Nanoparticles

Bo Jiang
, Cuiling Li^*
, Jing Tang
, Toshiaki Takei
, Jung Ho Kim
, Yusuke Ide
, Joel Henzie
, Satoshi Tominaka
, Yusuke Yamauchi

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

133 Scopus citations

Abstract

Platinum nanoparticles with continuously tunable mesoporous structures were prepared by a simple, one-step polymeric approach. By virtue of their large pore size, these structures have a high surface area that is accessible to reagents. In the synthetic method, variation of the solvent composition plays an essential role in the systematic control of pore size and particle shape. The mesoporous Pt catalyst exhibited superior electrocatalytic activity for the methanol oxidation reaction compared to commercially available Pt catalysts. This polymeric-micelle approach provides an additional design concept for the creation of next generation of metallic catalysts.

Original language	English
Pages (from-to)	10037-10041
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	55
Issue number	34
DOIs	https://doi.org/10.1002/anie.201603967
State	Published - 16 Aug 2016
Externally published	Yes

Keywords

mesoporous materials
micelle assembly
platinum
polymeric micelles
solvent composition

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10.1002/anie.201603967

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title = "Tunable-Sized Polymeric Micelles and Their Assembly for the Preparation of Large Mesoporous Platinum Nanoparticles",

abstract = "Platinum nanoparticles with continuously tunable mesoporous structures were prepared by a simple, one-step polymeric approach. By virtue of their large pore size, these structures have a high surface area that is accessible to reagents. In the synthetic method, variation of the solvent composition plays an essential role in the systematic control of pore size and particle shape. The mesoporous Pt catalyst exhibited superior electrocatalytic activity for the methanol oxidation reaction compared to commercially available Pt catalysts. This polymeric-micelle approach provides an additional design concept for the creation of next generation of metallic catalysts.",

keywords = "mesoporous materials, micelle assembly, platinum, polymeric micelles, solvent composition",

author = "Bo Jiang and Cuiling Li and Jing Tang and Toshiaki Takei and Kim, \{Jung Ho\} and Yusuke Ide and Joel Henzie and Satoshi Tominaka and Yusuke Yamauchi",

note = "Publisher Copyright: {\textcopyright} 2016 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2016",

month = aug,

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doi = "10.1002/anie.201603967",

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T1 - Tunable-Sized Polymeric Micelles and Their Assembly for the Preparation of Large Mesoporous Platinum Nanoparticles

AU - Jiang, Bo

AU - Li, Cuiling

AU - Tang, Jing

AU - Takei, Toshiaki

AU - Kim, Jung Ho

AU - Ide, Yusuke

AU - Henzie, Joel

AU - Tominaka, Satoshi

AU - Yamauchi, Yusuke

PY - 2016/8/16

Y1 - 2016/8/16

N2 - Platinum nanoparticles with continuously tunable mesoporous structures were prepared by a simple, one-step polymeric approach. By virtue of their large pore size, these structures have a high surface area that is accessible to reagents. In the synthetic method, variation of the solvent composition plays an essential role in the systematic control of pore size and particle shape. The mesoporous Pt catalyst exhibited superior electrocatalytic activity for the methanol oxidation reaction compared to commercially available Pt catalysts. This polymeric-micelle approach provides an additional design concept for the creation of next generation of metallic catalysts.

AB - Platinum nanoparticles with continuously tunable mesoporous structures were prepared by a simple, one-step polymeric approach. By virtue of their large pore size, these structures have a high surface area that is accessible to reagents. In the synthetic method, variation of the solvent composition plays an essential role in the systematic control of pore size and particle shape. The mesoporous Pt catalyst exhibited superior electrocatalytic activity for the methanol oxidation reaction compared to commercially available Pt catalysts. This polymeric-micelle approach provides an additional design concept for the creation of next generation of metallic catalysts.

KW - mesoporous materials

KW - micelle assembly

KW - platinum

KW - polymeric micelles

KW - solvent composition

UR - https://www.scopus.com/pages/publications/84978795398

U2 - 10.1002/anie.201603967

DO - 10.1002/anie.201603967

M3 - 文章

AN - SCOPUS:84978795398

SN - 1433-7851

VL - 55

SP - 10037

EP - 10041

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 34

ER -

Tunable-Sized Polymeric Micelles and Their Assembly for the Preparation of Large Mesoporous Platinum Nanoparticles

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Keywords

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