Tunable assembly of vanadium dioxide nanoparticles to create porous film for energy-saving applications

Shangjun Ding; Zhanqiang Liu; Dezeng Li; Wei Zhao; Yaoming Wang; Dongyun Wan; Fuqiang Huang

doi:10.1021/am3023724

Tunable assembly of vanadium dioxide nanoparticles to create porous film for energy-saving applications

Shangjun Ding, Zhanqiang Liu, Dezeng Li, Wei Zhao, Yaoming Wang, Dongyun Wan, Fuqiang Huang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

Nanoparticle-assembled vanadium dioxide (VO₂) films have been easily prepared with the assistance of cetyltrimethylammonium vanadate (CTAV) precursor which exhibits self-assembly properties. The obtained VO₂ film has a micro/nano hierarchical porous structure, so its visible-light transmittance is significantly improved (∼25% increased compared to continuous film). The VO₂ particle density as well as the film porosity can be facilely controlled by adjusting experimental parameters such as dip-coating speed. Accordingly, film optical properties can also be tuned to a large extent, in particular the visible transmittance (T_vis) and near-infrared switching efficiency (ΔT_nir). These VO ₂ nanoparticle-assembled films prepared by this novel method provide a useful model to research the balance between T_vis and ΔT _nir.

Original language	English
Pages (from-to)	1630-1635
Number of pages	6
Journal	ACS Applied Materials and Interfaces
Volume	5
Issue number	5
DOIs	https://doi.org/10.1021/am3023724
State	Published - 13 Mar 2013
Externally published	Yes

Keywords

optical controllability
particulate film
porous film
self-assembly
vanadium dioxide

Access to Document

10.1021/am3023724

Cite this

@article{57721a4d1227475eb576159f283f797f,

title = "Tunable assembly of vanadium dioxide nanoparticles to create porous film for energy-saving applications",

abstract = "Nanoparticle-assembled vanadium dioxide (VO2) films have been easily prepared with the assistance of cetyltrimethylammonium vanadate (CTAV) precursor which exhibits self-assembly properties. The obtained VO2 film has a micro/nano hierarchical porous structure, so its visible-light transmittance is significantly improved (∼25\% increased compared to continuous film). The VO2 particle density as well as the film porosity can be facilely controlled by adjusting experimental parameters such as dip-coating speed. Accordingly, film optical properties can also be tuned to a large extent, in particular the visible transmittance (Tvis) and near-infrared switching efficiency (ΔTnir). These VO 2 nanoparticle-assembled films prepared by this novel method provide a useful model to research the balance between Tvis and ΔT nir.",

keywords = "optical controllability, particulate film, porous film, self-assembly, vanadium dioxide",

author = "Shangjun Ding and Zhanqiang Liu and Dezeng Li and Wei Zhao and Yaoming Wang and Dongyun Wan and Fuqiang Huang",

year = "2013",

month = mar,

day = "13",

doi = "10.1021/am3023724",

language = "英语",

volume = "5",

pages = "1630--1635",

journal = "ACS Applied Materials and Interfaces",

issn = "1944-8244",

publisher = "American Chemical Society",

number = "5",

}

TY - JOUR

T1 - Tunable assembly of vanadium dioxide nanoparticles to create porous film for energy-saving applications

AU - Ding, Shangjun

AU - Liu, Zhanqiang

AU - Li, Dezeng

AU - Zhao, Wei

AU - Wang, Yaoming

AU - Wan, Dongyun

AU - Huang, Fuqiang

PY - 2013/3/13

Y1 - 2013/3/13

N2 - Nanoparticle-assembled vanadium dioxide (VO2) films have been easily prepared with the assistance of cetyltrimethylammonium vanadate (CTAV) precursor which exhibits self-assembly properties. The obtained VO2 film has a micro/nano hierarchical porous structure, so its visible-light transmittance is significantly improved (∼25% increased compared to continuous film). The VO2 particle density as well as the film porosity can be facilely controlled by adjusting experimental parameters such as dip-coating speed. Accordingly, film optical properties can also be tuned to a large extent, in particular the visible transmittance (Tvis) and near-infrared switching efficiency (ΔTnir). These VO 2 nanoparticle-assembled films prepared by this novel method provide a useful model to research the balance between Tvis and ΔT nir.

AB - Nanoparticle-assembled vanadium dioxide (VO2) films have been easily prepared with the assistance of cetyltrimethylammonium vanadate (CTAV) precursor which exhibits self-assembly properties. The obtained VO2 film has a micro/nano hierarchical porous structure, so its visible-light transmittance is significantly improved (∼25% increased compared to continuous film). The VO2 particle density as well as the film porosity can be facilely controlled by adjusting experimental parameters such as dip-coating speed. Accordingly, film optical properties can also be tuned to a large extent, in particular the visible transmittance (Tvis) and near-infrared switching efficiency (ΔTnir). These VO 2 nanoparticle-assembled films prepared by this novel method provide a useful model to research the balance between Tvis and ΔT nir.

KW - optical controllability

KW - particulate film

KW - porous film

KW - self-assembly

KW - vanadium dioxide

UR - https://www.scopus.com/pages/publications/84875041731

U2 - 10.1021/am3023724

DO - 10.1021/am3023724

M3 - 文章

AN - SCOPUS:84875041731

SN - 1944-8244

VL - 5

SP - 1630

EP - 1635

JO - ACS Applied Materials and Interfaces

JF - ACS Applied Materials and Interfaces

IS - 5

ER -

Tunable assembly of vanadium dioxide nanoparticles to create porous film for energy-saving applications

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this