Triple-quantum dual-comb two-dimensional coherent spectroscopy resolves velocity-synchronized Dicke states in hot atomic vapors

  • Zejiang Deng
  • , Shiping Xiong
  • , Daping Luo*
  • , Jiayi Pan
  • , Zilin Zhao
  • , Liyuan Hou
  • , Gehui Xie
  • , Zhong Zuo
  • , Shaogang Yu
  • , Zhiwei Zhu
  • , Chenglin Gu*
  • , Jian Wu
  • , Wenxue Li*
  • , Heping Zeng
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

Two-dimensional coherent spectroscopy (2DCS) combined with dual-comb technology offers unprecedented resolution for probing many-body interactions in atomic vapors, yet its application to high-order multi-quantum transitions remains challenging due to weaker nonlinear signals and phase instability. Here, we demonstrate a triple-quantum dual-comb 2DCS technique that achieves λ/110 phase stability through digital correction, enabling the observation of velocity-synchronized Dicke states in a thermal rubidium vapor. By resolving collective hyperfine resonances of ⁸⁵Rb and ⁸⁷Rb isotopes with 100 MHz spectral resolution, the titled and elongated ellipticity of the three-quantum peak line shape (0.94) is higher than that of the two-quantum (0.84), reveals that triple-quantum correlations (0.95) surpass double-quantum counterparts (0.90), indicating tighter velocity matching in higher-order Dicke states. This work provides a pathway for manipulating multi-atom correlations in Doppler-broadened systems, and greatly assists to characterize complex hyperfine many-body interaction in semiconductor exciton and two-dimensional materials.

Original languageEnglish
Article number498
JournalCommunications Physics
Volume8
Issue number1
DOIs
StatePublished - Dec 2025

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