Triphenylmethanethiol: A novel rigid capping agent for gold nanoclusters

Di Li, Jinghong Li

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

In this article, we employed triphenylmethanethiol (TPMT) as a novel rigid agent for capping gold nanoparticles and the TPMT monolayer-protected gold nanoparticles were characterized by various analytical techniques. High-resolution transmission electron microscopy showed a narrow dispersed gold core with an average core diameter of ca. 3.6 nm. The UV/vis spectrum revealed the surface plasmon absorbance at 528 nm. The p-π conjugated structure of the TPMT ligand was confirmed by nuclear magnetic resonance. Differential scanning calorimetry and Fourier transform infrared spectroscopy revealed the rigid nature of the TPMT chains.

Original languageEnglish
Pages (from-to)498-501
Number of pages4
JournalNew Journal of Chemistry
Volume27
Issue number3
DOIs
StatePublished - 1 Mar 2003
Externally publishedYes

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