Transition-metal-free visible-light photoredox catalysis at room-temperature for decarboxylative fluorination of aliphatic carboxylic acids by organic dyes

Xinxin Wu; Chunna Meng; Xiaoqian Yuan; Xiaotong Jia; Xuhong Qian; Jinxing Ye

doi:10.1039/c5cc04527d

Transition-metal-free visible-light photoredox catalysis at room-temperature for decarboxylative fluorination of aliphatic carboxylic acids by organic dyes

Xinxin Wu
, Chunna Meng
, Xiaoqian Yuan
, Xiaotong Jia
, Xuhong Qian
, Jinxing Ye^*

^*Corresponding author for this work

East China University of Science and Technology

Research output: Contribution to journal › Article › peer-review

112 Scopus citations

Abstract

We report herein an efficient, general and green method for decarboxylative fluorination of aliphatic carboxylic acids. By using a transition-metal-free, organocatalytic photoredox system, the reaction of various aliphatic carboxylic acids with the Selectfluor reagent afforded the corresponding alkyl fluorides in satisfactory yields under visible light irradiation at room temperature.

Original language	English
Pages (from-to)	11864-11867
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	59
DOIs	https://doi.org/10.1039/c5cc04527d
State	Published - 28 Jul 2015
Externally published	Yes

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title = "Transition-metal-free visible-light photoredox catalysis at room-temperature for decarboxylative fluorination of aliphatic carboxylic acids by organic dyes",

abstract = "We report herein an efficient, general and green method for decarboxylative fluorination of aliphatic carboxylic acids. By using a transition-metal-free, organocatalytic photoredox system, the reaction of various aliphatic carboxylic acids with the Selectfluor reagent afforded the corresponding alkyl fluorides in satisfactory yields under visible light irradiation at room temperature.",

author = "Xinxin Wu and Chunna Meng and Xiaoqian Yuan and Xiaotong Jia and Xuhong Qian and Jinxing Ye",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

month = jul,

day = "28",

doi = "10.1039/c5cc04527d",

language = "英语",

volume = "51",

pages = "11864--11867",

journal = "Chemical Communications",

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TY - JOUR

T1 - Transition-metal-free visible-light photoredox catalysis at room-temperature for decarboxylative fluorination of aliphatic carboxylic acids by organic dyes

AU - Wu, Xinxin

AU - Meng, Chunna

AU - Yuan, Xiaoqian

AU - Jia, Xiaotong

AU - Qian, Xuhong

AU - Ye, Jinxing

PY - 2015/7/28

Y1 - 2015/7/28

N2 - We report herein an efficient, general and green method for decarboxylative fluorination of aliphatic carboxylic acids. By using a transition-metal-free, organocatalytic photoredox system, the reaction of various aliphatic carboxylic acids with the Selectfluor reagent afforded the corresponding alkyl fluorides in satisfactory yields under visible light irradiation at room temperature.

AB - We report herein an efficient, general and green method for decarboxylative fluorination of aliphatic carboxylic acids. By using a transition-metal-free, organocatalytic photoredox system, the reaction of various aliphatic carboxylic acids with the Selectfluor reagent afforded the corresponding alkyl fluorides in satisfactory yields under visible light irradiation at room temperature.

UR - https://www.scopus.com/pages/publications/84936933996

U2 - 10.1039/c5cc04527d

DO - 10.1039/c5cc04527d

M3 - 文章

C2 - 26111079

AN - SCOPUS:84936933996

SN - 1359-7345

VL - 51

SP - 11864

EP - 11867

JO - Chemical Communications

JF - Chemical Communications

IS - 59

ER -

Transition-metal-free visible-light photoredox catalysis at room-temperature for decarboxylative fluorination of aliphatic carboxylic acids by organic dyes

Abstract

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