TY - JOUR
T1 - Transition metal complexes of the benzoin Schiff base of S-benzyldithiocarbazate
AU - Gao, Enqing
AU - Bi, Siwei
AU - Sun, Haiying
AU - Liu, Shuxiang
PY - 1997
Y1 - 1997
N2 - The benzoin Schiff base, H2BBDT, derived from S-benzyldithiocarbazate, and its metal complexes of the general formula M(HBBDT)2 [M = Mn(II), Ni(II), Co(II), Zn(II) and Cd(II)] have been synthesized and characterized by means of elemental analyses, IR and electronic spectra, conductivity and magnetic susceptibility measurements. The Schiff base functions as a uninegative, tridentate ligand formed by enethiolization and deprotonation of the thioamide group and bonds through the hydroxyl oxygen, thiolate sulphur, and azomethine nitrogen. Based on magnetic and spectral studies, an octahedral or distorted octahedral geometry is proposed for the complexes.
AB - The benzoin Schiff base, H2BBDT, derived from S-benzyldithiocarbazate, and its metal complexes of the general formula M(HBBDT)2 [M = Mn(II), Ni(II), Co(II), Zn(II) and Cd(II)] have been synthesized and characterized by means of elemental analyses, IR and electronic spectra, conductivity and magnetic susceptibility measurements. The Schiff base functions as a uninegative, tridentate ligand formed by enethiolization and deprotonation of the thioamide group and bonds through the hydroxyl oxygen, thiolate sulphur, and azomethine nitrogen. Based on magnetic and spectral studies, an octahedral or distorted octahedral geometry is proposed for the complexes.
UR - https://www.scopus.com/pages/publications/0031530953
U2 - 10.1080/00945719708000251
DO - 10.1080/00945719708000251
M3 - 文章
AN - SCOPUS:0031530953
SN - 0094-5714
VL - 27
SP - 1115
EP - 1125
JO - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
JF - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
IS - 8
ER -