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Transition-metal-catalyzed unzipping of single-walled carbon nanotubes into narrow graphene nanoribbons at low temperature

  • Jinlan Wang*
  • , Liang Ma
  • , Qinghong Yuan
  • , Liyan Zhu
  • , Feng Ding
  • *Corresponding author for this work
  • Southeast University, Nanjing
  • Hong Kong Polytechnic University

Research output: Contribution to journalArticlepeer-review

Abstract

Open, sesame! Graphene nanoribbons (GNRs) with smooth edges and controllable widths are crucial for graphene electronic and spintronic applications. High-quality narrow GNRs can be synthesized from single-walled carbon nanotubes at 200-300 °C using a Cu-atom catalyst, which dramatically reduces the energy barrier of unzipping from 3.11 to 1.16 eV.

Original languageEnglish
Pages (from-to)8041-8045
Number of pages5
JournalAngewandte Chemie - International Edition
Volume50
Issue number35
DOIs
StatePublished - 22 Aug 2011
Externally publishedYes

Keywords

  • ab initio calculations
  • graphene
  • heterogeneous catalysis
  • nanotubes

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