Total synthesis of (+)-fusarisetin A: A biomimetic approach

Jun Yin; Shuanhu Gao

doi:10.1055/s-0033-1340153

Total synthesis of (+)-fusarisetin A: A biomimetic approach

Jun Yin, Shuanhu Gao^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

This article outlines our recent efforts to synthesize (+)-fusarisetin A, a naturally occurring 3-acyltetramic acid, by a route based on a hypothetical biosynthesis. Our research suggests that the biosynthesis of (+)-fusarisetin A might involve the aerobic oxidation of equisetin, possibly mediated by metal oxidants or by photochemically produced reactive oxygen species.

Original language	English
Article number	ST-2013-P0821-SP
Pages (from-to)	1-7
Number of pages	7
Journal	Synlett
Volume	25
Issue number	1
DOIs	https://doi.org/10.1055/s-0033-1340153
State	Published - 2 Jan 2014

Keywords

biosynthesis
heterocycles
polycycles
radical reactions
total synthesis

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10.1055/s-0033-1340153

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abstract = "This article outlines our recent efforts to synthesize (+)-fusarisetin A, a naturally occurring 3-acyltetramic acid, by a route based on a hypothetical biosynthesis. Our research suggests that the biosynthesis of (+)-fusarisetin A might involve the aerobic oxidation of equisetin, possibly mediated by metal oxidants or by photochemically produced reactive oxygen species.",

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AB - This article outlines our recent efforts to synthesize (+)-fusarisetin A, a naturally occurring 3-acyltetramic acid, by a route based on a hypothetical biosynthesis. Our research suggests that the biosynthesis of (+)-fusarisetin A might involve the aerobic oxidation of equisetin, possibly mediated by metal oxidants or by photochemically produced reactive oxygen species.

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KW - heterocycles

KW - polycycles

KW - radical reactions

KW - total synthesis

UR - https://www.scopus.com/pages/publications/84890551059

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M3 - 文章

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Total synthesis of (+)-fusarisetin A: A biomimetic approach

Abstract

Keywords

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