Total synthesis of (+)-fusarisetin A: A biomimetic approach

Jun Yin; Shuanhu Gao

doi:10.1055/s-0033-1340153

Total synthesis of (+)-fusarisetin A: A biomimetic approach

Jun Yin
, Shuanhu Gao^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

This article outlines our recent efforts to synthesize (+)-fusarisetin A, a naturally occurring 3-acyltetramic acid, by a route based on a hypothetical biosynthesis. Our research suggests that the biosynthesis of (+)-fusarisetin A might involve the aerobic oxidation of equisetin, possibly mediated by metal oxidants or by photochemically produced reactive oxygen species.

Original language	English
Article number	ST-2013-P0821-SP
Pages (from-to)	1-7
Number of pages	7
Journal	Synlett
Volume	25
Issue number	1
DOIs	https://doi.org/10.1055/s-0033-1340153
State	Published - 2 Jan 2014

Keywords

biosynthesis
heterocycles
polycycles
radical reactions
total synthesis

Access to Document

10.1055/s-0033-1340153

Cite this

@article{3e2212f9e7f945bfa18e93d110a79db7,

title = "Total synthesis of (+)-fusarisetin A: A biomimetic approach",

abstract = "This article outlines our recent efforts to synthesize (+)-fusarisetin A, a naturally occurring 3-acyltetramic acid, by a route based on a hypothetical biosynthesis. Our research suggests that the biosynthesis of (+)-fusarisetin A might involve the aerobic oxidation of equisetin, possibly mediated by metal oxidants or by photochemically produced reactive oxygen species.",

keywords = "biosynthesis, heterocycles, polycycles, radical reactions, total synthesis",

author = "Jun Yin and Shuanhu Gao",

year = "2014",

month = jan,

day = "2",

doi = "10.1055/s-0033-1340153",

language = "英语",

volume = "25",

pages = "1--7",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

number = "1",

}

TY - JOUR

T1 - Total synthesis of (+)-fusarisetin A

T2 - A biomimetic approach

AU - Yin, Jun

AU - Gao, Shuanhu

PY - 2014/1/2

Y1 - 2014/1/2

N2 - This article outlines our recent efforts to synthesize (+)-fusarisetin A, a naturally occurring 3-acyltetramic acid, by a route based on a hypothetical biosynthesis. Our research suggests that the biosynthesis of (+)-fusarisetin A might involve the aerobic oxidation of equisetin, possibly mediated by metal oxidants or by photochemically produced reactive oxygen species.

AB - This article outlines our recent efforts to synthesize (+)-fusarisetin A, a naturally occurring 3-acyltetramic acid, by a route based on a hypothetical biosynthesis. Our research suggests that the biosynthesis of (+)-fusarisetin A might involve the aerobic oxidation of equisetin, possibly mediated by metal oxidants or by photochemically produced reactive oxygen species.

KW - biosynthesis

KW - heterocycles

KW - polycycles

KW - radical reactions

KW - total synthesis

UR - https://www.scopus.com/pages/publications/84890551059

U2 - 10.1055/s-0033-1340153

DO - 10.1055/s-0033-1340153

M3 - 文章

AN - SCOPUS:84890551059

SN - 0936-5214

VL - 25

SP - 1

EP - 7

JO - Synlett

JF - Synlett

IS - 1

M1 - ST-2013-P0821-SP

ER -

Total synthesis of (+)-fusarisetin A: A biomimetic approach

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this