TiO2 and Cu1.5Mn1.5O4 co-modified hierarchically porous zeolite Beta for soot oxidation with excellent sulfur-resistance and stability

X. X. Zhou; H. Zhao; W. M. Huang; H. R. Chen; J. L. Shi

doi:10.1039/c7dt00918f

TiO₂ and Cu_1.5Mn_1.5O₄ co-modified hierarchically porous zeolite Beta for soot oxidation with excellent sulfur-resistance and stability

X. X. Zhou
, H. Zhao
, W. M. Huang
, H. R. Chen^*
, J. L. Shi

^*Corresponding author for this work

CAS - Shanghai Institute of Ceramics

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

TiO₂ and spinel Cu_1.5Mn_1.5O₄ co-modified hierarchically porous zeolite Beta (Ti/Cu_1.5Mn_1.5O₄-HBeta) with 3D interpenetrating micro-mesoporosity has been synthesized, which showed highly efficient catalytic activity to the soot oxidation in the presence of O₂/NO/N₂ due to the rich moderate intensity acidic sites and chemisorbed oxygen species. In the presence of SO₂/O₂/NO/N₂, the SO₂ could be preferentially adsorbed on the Ti/Cu_1.5Mn_1.5O₄-HBeta and the resulting sulfates could easily decompose at elevated temperatures, thus leading to significantly improved sulfur-resistance. Furthermore, the excellent water-resistance and cycling stability were achieved on the catalyst Ti/Cu_1.5Mn_1.5O₄-HBeta owing to its crystalline zeolite framework and highly dispersed active components.

Original language	English
Pages (from-to)	6111-6116
Number of pages	6
Journal	Dalton Transactions
Volume	46
Issue number	18
DOIs	https://doi.org/10.1039/c7dt00918f
State	Published - 2017
Externally published	Yes

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title = "TiO2 and Cu1.5Mn1.5O4 co-modified hierarchically porous zeolite Beta for soot oxidation with excellent sulfur-resistance and stability",

abstract = "TiO2 and spinel Cu1.5Mn1.5O4 co-modified hierarchically porous zeolite Beta (Ti/Cu1.5Mn1.5O4-HBeta) with 3D interpenetrating micro-mesoporosity has been synthesized, which showed highly efficient catalytic activity to the soot oxidation in the presence of O2/NO/N2 due to the rich moderate intensity acidic sites and chemisorbed oxygen species. In the presence of SO2/O2/NO/N2, the SO2 could be preferentially adsorbed on the Ti/Cu1.5Mn1.5O4-HBeta and the resulting sulfates could easily decompose at elevated temperatures, thus leading to significantly improved sulfur-resistance. Furthermore, the excellent water-resistance and cycling stability were achieved on the catalyst Ti/Cu1.5Mn1.5O4-HBeta owing to its crystalline zeolite framework and highly dispersed active components.",

author = "Zhou, \{X. X.\} and H. Zhao and Huang, \{W. M.\} and Chen, \{H. R.\} and Shi, \{J. L.\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2017.",

year = "2017",

doi = "10.1039/c7dt00918f",

language = "英语",

volume = "46",

pages = "6111--6116",

journal = "Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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}

TY - JOUR

T1 - TiO2 and Cu1.5Mn1.5O4 co-modified hierarchically porous zeolite Beta for soot oxidation with excellent sulfur-resistance and stability

AU - Zhou, X. X.

AU - Zhao, H.

AU - Huang, W. M.

AU - Chen, H. R.

AU - Shi, J. L.

N1 - Publisher Copyright: © The Royal Society of Chemistry 2017.

PY - 2017

Y1 - 2017

N2 - TiO2 and spinel Cu1.5Mn1.5O4 co-modified hierarchically porous zeolite Beta (Ti/Cu1.5Mn1.5O4-HBeta) with 3D interpenetrating micro-mesoporosity has been synthesized, which showed highly efficient catalytic activity to the soot oxidation in the presence of O2/NO/N2 due to the rich moderate intensity acidic sites and chemisorbed oxygen species. In the presence of SO2/O2/NO/N2, the SO2 could be preferentially adsorbed on the Ti/Cu1.5Mn1.5O4-HBeta and the resulting sulfates could easily decompose at elevated temperatures, thus leading to significantly improved sulfur-resistance. Furthermore, the excellent water-resistance and cycling stability were achieved on the catalyst Ti/Cu1.5Mn1.5O4-HBeta owing to its crystalline zeolite framework and highly dispersed active components.

AB - TiO2 and spinel Cu1.5Mn1.5O4 co-modified hierarchically porous zeolite Beta (Ti/Cu1.5Mn1.5O4-HBeta) with 3D interpenetrating micro-mesoporosity has been synthesized, which showed highly efficient catalytic activity to the soot oxidation in the presence of O2/NO/N2 due to the rich moderate intensity acidic sites and chemisorbed oxygen species. In the presence of SO2/O2/NO/N2, the SO2 could be preferentially adsorbed on the Ti/Cu1.5Mn1.5O4-HBeta and the resulting sulfates could easily decompose at elevated temperatures, thus leading to significantly improved sulfur-resistance. Furthermore, the excellent water-resistance and cycling stability were achieved on the catalyst Ti/Cu1.5Mn1.5O4-HBeta owing to its crystalline zeolite framework and highly dispersed active components.

UR - https://www.scopus.com/pages/publications/85021767768

U2 - 10.1039/c7dt00918f

DO - 10.1039/c7dt00918f

M3 - 文章

C2 - 28436524

AN - SCOPUS:85021767768

SN - 1477-9226

VL - 46

SP - 6111

EP - 6116

JO - Dalton Transactions

JF - Dalton Transactions

IS - 18

ER -

TiO₂ and Cu_1.5Mn_1.5O₄ co-modified hierarchically porous zeolite Beta for soot oxidation with excellent sulfur-resistance and stability

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