Three-dimensional networks based on trinuclear motifs with tricomponent azide-carboxylate-tetrazolate cobridges: Synthesis, structure and magnetic properties

Xiu Bing Li; Kun Wang; Yu Ma; En Qing Gao; Cai Ming Liu

doi:10.1039/c2dt11966h

Three-dimensional networks based on trinuclear motifs with tricomponent azide-carboxylate-tetrazolate cobridges: Synthesis, structure and magnetic properties

Xiu Bing Li
, Kun Wang
, Yu Ma
, En Qing Gao^*
, Cai Ming Liu

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Two 3D coordination polymers of Mn ^II with azide and bifunctional zwitterionic ligands bearing both carboxylate and tetrazolate groups, 1-(carboxylatomethyl)-3-(5-tetrazolato)pyridinium (L ¹) and 1-(carboxylatoethyl)-4-(5-tetrazolato)pyridinium (L ²), were synthesized, and structurally and magnetically characterized. They are formulated as [Mn ₃(L ¹) ₂(N ₃) ₄(H ₂O) ₂] _n·4nH ₂O (1) and [Mn ₃(L ²) ₂(N ₃) ₄(H ₂O) ₃] _n·3.5nH ₂O (2). In both compounds, octahedral Mn ^II ions are linked by the mixed (μ ₂-EO-N ₃)(μ ₂-syn,syn-COO) (μ ₂-N ²,N ³-CN ₄) (CN ₄ = tetrazolate and EO = end-on) triple bridges to give anionic linear trinuclear motifs. The motifs are connected through EE-N ₃ (EE = end-to-end) bridges to give layers and chains in 1 and 2, respectively, and the cationic pyridinium spacers serve to interlink the layers or chains into three-dimensional frameworks with the α-Po and CdSO ₄-type topology, respectively. Magnetic studies demonstrated that the magnetic interactions within and between the trinuclear motifs, through the tricomponent and EE-N ₃ bridges, respectively, are both antiferromagnetic in both compounds.

Original language	English
Pages (from-to)	4188-4194
Number of pages	7
Journal	Dalton Transactions
Volume	41
Issue number	14
DOIs	https://doi.org/10.1039/c2dt11966h
State	Published - 14 Apr 2012

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@article{00bc471e03c54a43a1372562ef1bd557,

title = "Three-dimensional networks based on trinuclear motifs with tricomponent azide-carboxylate-tetrazolate cobridges: Synthesis, structure and magnetic properties",

abstract = "Two 3D coordination polymers of Mn II with azide and bifunctional zwitterionic ligands bearing both carboxylate and tetrazolate groups, 1-(carboxylatomethyl)-3-(5-tetrazolato)pyridinium (L 1) and 1-(carboxylatoethyl)-4-(5-tetrazolato)pyridinium (L 2), were synthesized, and structurally and magnetically characterized. They are formulated as [Mn 3(L 1) 2(N 3) 4(H 2O) 2] n·4nH 2O (1) and [Mn 3(L 2) 2(N 3) 4(H 2O) 3] n·3.5nH 2O (2). In both compounds, octahedral Mn II ions are linked by the mixed (μ 2-EO-N 3)(μ 2-syn,syn-COO) (μ 2-N 2,N 3-CN 4) (CN 4 = tetrazolate and EO = end-on) triple bridges to give anionic linear trinuclear motifs. The motifs are connected through EE-N 3 (EE = end-to-end) bridges to give layers and chains in 1 and 2, respectively, and the cationic pyridinium spacers serve to interlink the layers or chains into three-dimensional frameworks with the α-Po and CdSO 4-type topology, respectively. Magnetic studies demonstrated that the magnetic interactions within and between the trinuclear motifs, through the tricomponent and EE-N 3 bridges, respectively, are both antiferromagnetic in both compounds.",

author = "Li, \{Xiu Bing\} and Kun Wang and Yu Ma and Gao, \{En Qing\} and Liu, \{Cai Ming\}",

year = "2012",

month = apr,

day = "14",

doi = "10.1039/c2dt11966h",

language = "英语",

volume = "41",

pages = "4188--4194",

journal = "Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Three-dimensional networks based on trinuclear motifs with tricomponent azide-carboxylate-tetrazolate cobridges

T2 - Synthesis, structure and magnetic properties

AU - Li, Xiu Bing

AU - Wang, Kun

AU - Ma, Yu

AU - Gao, En Qing

AU - Liu, Cai Ming

PY - 2012/4/14

Y1 - 2012/4/14

N2 - Two 3D coordination polymers of Mn II with azide and bifunctional zwitterionic ligands bearing both carboxylate and tetrazolate groups, 1-(carboxylatomethyl)-3-(5-tetrazolato)pyridinium (L 1) and 1-(carboxylatoethyl)-4-(5-tetrazolato)pyridinium (L 2), were synthesized, and structurally and magnetically characterized. They are formulated as [Mn 3(L 1) 2(N 3) 4(H 2O) 2] n·4nH 2O (1) and [Mn 3(L 2) 2(N 3) 4(H 2O) 3] n·3.5nH 2O (2). In both compounds, octahedral Mn II ions are linked by the mixed (μ 2-EO-N 3)(μ 2-syn,syn-COO) (μ 2-N 2,N 3-CN 4) (CN 4 = tetrazolate and EO = end-on) triple bridges to give anionic linear trinuclear motifs. The motifs are connected through EE-N 3 (EE = end-to-end) bridges to give layers and chains in 1 and 2, respectively, and the cationic pyridinium spacers serve to interlink the layers or chains into three-dimensional frameworks with the α-Po and CdSO 4-type topology, respectively. Magnetic studies demonstrated that the magnetic interactions within and between the trinuclear motifs, through the tricomponent and EE-N 3 bridges, respectively, are both antiferromagnetic in both compounds.

AB - Two 3D coordination polymers of Mn II with azide and bifunctional zwitterionic ligands bearing both carboxylate and tetrazolate groups, 1-(carboxylatomethyl)-3-(5-tetrazolato)pyridinium (L 1) and 1-(carboxylatoethyl)-4-(5-tetrazolato)pyridinium (L 2), were synthesized, and structurally and magnetically characterized. They are formulated as [Mn 3(L 1) 2(N 3) 4(H 2O) 2] n·4nH 2O (1) and [Mn 3(L 2) 2(N 3) 4(H 2O) 3] n·3.5nH 2O (2). In both compounds, octahedral Mn II ions are linked by the mixed (μ 2-EO-N 3)(μ 2-syn,syn-COO) (μ 2-N 2,N 3-CN 4) (CN 4 = tetrazolate and EO = end-on) triple bridges to give anionic linear trinuclear motifs. The motifs are connected through EE-N 3 (EE = end-to-end) bridges to give layers and chains in 1 and 2, respectively, and the cationic pyridinium spacers serve to interlink the layers or chains into three-dimensional frameworks with the α-Po and CdSO 4-type topology, respectively. Magnetic studies demonstrated that the magnetic interactions within and between the trinuclear motifs, through the tricomponent and EE-N 3 bridges, respectively, are both antiferromagnetic in both compounds.

UR - https://www.scopus.com/pages/publications/84863341114

U2 - 10.1039/c2dt11966h

DO - 10.1039/c2dt11966h

M3 - 文章

AN - SCOPUS:84863341114

SN - 1477-9226

VL - 41

SP - 4188

EP - 4194

JO - Dalton Transactions

JF - Dalton Transactions

IS - 14

ER -

Three-dimensional networks based on trinuclear motifs with tricomponent azide-carboxylate-tetrazolate cobridges: Synthesis, structure and magnetic properties

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