Three-Arm Branched Microporous Organic Nanotube Networks

Zidong He; Aiqing Zhong; Hui Zhang; Linfeng Xiong; Yang Xu; Tianqi Wang; Minghong Zhou; Kun Huang

doi:10.1002/marc.201600327

Three-Arm Branched Microporous Organic Nanotube Networks

Zidong He, Aiqing Zhong, Hui Zhang, Linfeng Xiong, Yang Xu, Tianqi Wang, Minghong Zhou, Kun Huang

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Here, a novel method is demonstrated for the preparation of three-arm branched microporous organic nanotube networks (TAB-MONNs) based on molecular templating of three-arm branched core-shell bottlebrush copolymers and Friedel-Crafts alkylation reaction. The unique three-arm branched bottlebrush copolymers are synthesized by a combination of atom transfer radical polymerization, reversible addition-fragmentation chain transfer polymerization, and ring-opening polymerization techniques. In this approach, the length and diameter of branched tube units can be well-controlled by rational molecular design. Moreover, the as-prepared TAB-MONNs possess a high surface area and exhibit a superior adsorption capacity for Rhodamine 6G (R6G) and p-cresol.

Original language	English
Pages (from-to)	1566-1572
Number of pages	7
Journal	Macromolecular Rapid Communications
Volume	37
Issue number	19
DOIs	https://doi.org/10.1002/marc.201600327
State	Published - 1 Oct 2016

Keywords

Friedel-Crafts alkylation reaction
bottlebrush copolymer
three-arm branched microporous organic nanotube networks

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10.1002/marc.201600327

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title = "Three-Arm Branched Microporous Organic Nanotube Networks",

abstract = "Here, a novel method is demonstrated for the preparation of three-arm branched microporous organic nanotube networks (TAB-MONNs) based on molecular templating of three-arm branched core-shell bottlebrush copolymers and Friedel-Crafts alkylation reaction. The unique three-arm branched bottlebrush copolymers are synthesized by a combination of atom transfer radical polymerization, reversible addition-fragmentation chain transfer polymerization, and ring-opening polymerization techniques. In this approach, the length and diameter of branched tube units can be well-controlled by rational molecular design. Moreover, the as-prepared TAB-MONNs possess a high surface area and exhibit a superior adsorption capacity for Rhodamine 6G (R6G) and p-cresol.",

keywords = "Friedel-Crafts alkylation reaction, bottlebrush copolymer, three-arm branched microporous organic nanotube networks",

author = "Zidong He and Aiqing Zhong and Hui Zhang and Linfeng Xiong and Yang Xu and Tianqi Wang and Minghong Zhou and Kun Huang",

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doi = "10.1002/marc.201600327",

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T1 - Three-Arm Branched Microporous Organic Nanotube Networks

AU - He, Zidong

AU - Zhong, Aiqing

AU - Zhang, Hui

AU - Xiong, Linfeng

AU - Xu, Yang

AU - Wang, Tianqi

AU - Zhou, Minghong

AU - Huang, Kun

PY - 2016/10/1

Y1 - 2016/10/1

N2 - Here, a novel method is demonstrated for the preparation of three-arm branched microporous organic nanotube networks (TAB-MONNs) based on molecular templating of three-arm branched core-shell bottlebrush copolymers and Friedel-Crafts alkylation reaction. The unique three-arm branched bottlebrush copolymers are synthesized by a combination of atom transfer radical polymerization, reversible addition-fragmentation chain transfer polymerization, and ring-opening polymerization techniques. In this approach, the length and diameter of branched tube units can be well-controlled by rational molecular design. Moreover, the as-prepared TAB-MONNs possess a high surface area and exhibit a superior adsorption capacity for Rhodamine 6G (R6G) and p-cresol.

AB - Here, a novel method is demonstrated for the preparation of three-arm branched microporous organic nanotube networks (TAB-MONNs) based on molecular templating of three-arm branched core-shell bottlebrush copolymers and Friedel-Crafts alkylation reaction. The unique three-arm branched bottlebrush copolymers are synthesized by a combination of atom transfer radical polymerization, reversible addition-fragmentation chain transfer polymerization, and ring-opening polymerization techniques. In this approach, the length and diameter of branched tube units can be well-controlled by rational molecular design. Moreover, the as-prepared TAB-MONNs possess a high surface area and exhibit a superior adsorption capacity for Rhodamine 6G (R6G) and p-cresol.

KW - Friedel-Crafts alkylation reaction

KW - bottlebrush copolymer

KW - three-arm branched microporous organic nanotube networks

UR - https://www.scopus.com/pages/publications/85027954792

U2 - 10.1002/marc.201600327

DO - 10.1002/marc.201600327

M3 - 文章

C2 - 27493017

AN - SCOPUS:85027954792

SN - 1022-1336

VL - 37

SP - 1566

EP - 1572

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 19

ER -

Three-Arm Branched Microporous Organic Nanotube Networks

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Keywords

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