Thin-sheet Ag/Ni-fiber catalyst for gas-phase selective oxidation of benzyl alcohol with molecular oxygen

Jiping Mao; Miaomiao Deng; Qingsong Xue; Li Chen; Yong Lu

doi:10.1016/j.catcom.2009.03.006

Thin-sheet Ag/Ni-fiber catalyst for gas-phase selective oxidation of benzyl alcohol with molecular oxygen

Jiping Mao, Miaomiao Deng, Qingsong Xue, Li Chen, Yong Lu

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

A non-woven microfibrous thin-sheet structure with 5 vol% 8 μm diameter nickel fibers was built up using wet-lay papermaking and sintering process. Silver was then placed onto the sinter-locked Ni-fiber by the incipient wetness impregnation with AgNO₃ aqueous solution. As-made Ag/Ni-fiber catalysts exhibited much higher activity/selectivity for the gas-phase selective oxidation of benzyl alcohol to benzaldehyde, and provided significant increase in the steady-state volumetric reaction rate with dramatic saving of Ag, in comparison with the electrolytic silver and Ag/α-Al₂O₃ catalysts. Conversion of 84% was achievable with benzaldehyde selectivity of 94% at 380 °C using a high WHSV of 30 h^-1.

Original language	English
Pages (from-to)	1376-1379
Number of pages	4
Journal	Catalysis Communications
Volume	10
Issue number	10
DOIs	https://doi.org/10.1016/j.catcom.2009.03.006
State	Published - 20 May 2009

Keywords

Benzyl alcohol oxidation
Gas-phase
Nickel microfibers
Silver-based catalysis

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10.1016/j.catcom.2009.03.006

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title = "Thin-sheet Ag/Ni-fiber catalyst for gas-phase selective oxidation of benzyl alcohol with molecular oxygen",

abstract = "A non-woven microfibrous thin-sheet structure with 5 vol\% 8 μm diameter nickel fibers was built up using wet-lay papermaking and sintering process. Silver was then placed onto the sinter-locked Ni-fiber by the incipient wetness impregnation with AgNO3 aqueous solution. As-made Ag/Ni-fiber catalysts exhibited much higher activity/selectivity for the gas-phase selective oxidation of benzyl alcohol to benzaldehyde, and provided significant increase in the steady-state volumetric reaction rate with dramatic saving of Ag, in comparison with the electrolytic silver and Ag/α-Al2O3 catalysts. Conversion of 84\% was achievable with benzaldehyde selectivity of 94\% at 380 °C using a high WHSV of 30 h-1.",

keywords = "Benzyl alcohol oxidation, Gas-phase, Nickel microfibers, Silver-based catalysis",

author = "Jiping Mao and Miaomiao Deng and Qingsong Xue and Li Chen and Yong Lu",

year = "2009",

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doi = "10.1016/j.catcom.2009.03.006",

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TY - JOUR

T1 - Thin-sheet Ag/Ni-fiber catalyst for gas-phase selective oxidation of benzyl alcohol with molecular oxygen

AU - Mao, Jiping

AU - Deng, Miaomiao

AU - Xue, Qingsong

AU - Chen, Li

AU - Lu, Yong

PY - 2009/5/20

Y1 - 2009/5/20

N2 - A non-woven microfibrous thin-sheet structure with 5 vol% 8 μm diameter nickel fibers was built up using wet-lay papermaking and sintering process. Silver was then placed onto the sinter-locked Ni-fiber by the incipient wetness impregnation with AgNO3 aqueous solution. As-made Ag/Ni-fiber catalysts exhibited much higher activity/selectivity for the gas-phase selective oxidation of benzyl alcohol to benzaldehyde, and provided significant increase in the steady-state volumetric reaction rate with dramatic saving of Ag, in comparison with the electrolytic silver and Ag/α-Al2O3 catalysts. Conversion of 84% was achievable with benzaldehyde selectivity of 94% at 380 °C using a high WHSV of 30 h-1.

AB - A non-woven microfibrous thin-sheet structure with 5 vol% 8 μm diameter nickel fibers was built up using wet-lay papermaking and sintering process. Silver was then placed onto the sinter-locked Ni-fiber by the incipient wetness impregnation with AgNO3 aqueous solution. As-made Ag/Ni-fiber catalysts exhibited much higher activity/selectivity for the gas-phase selective oxidation of benzyl alcohol to benzaldehyde, and provided significant increase in the steady-state volumetric reaction rate with dramatic saving of Ag, in comparison with the electrolytic silver and Ag/α-Al2O3 catalysts. Conversion of 84% was achievable with benzaldehyde selectivity of 94% at 380 °C using a high WHSV of 30 h-1.

KW - Benzyl alcohol oxidation

KW - Gas-phase

KW - Nickel microfibers

KW - Silver-based catalysis

UR - https://www.scopus.com/pages/publications/67349122309

U2 - 10.1016/j.catcom.2009.03.006

DO - 10.1016/j.catcom.2009.03.006

M3 - 文章

AN - SCOPUS:67349122309

SN - 1566-7367

VL - 10

SP - 1376

EP - 1379

JO - Catalysis Communications

JF - Catalysis Communications

IS - 10

ER -

Thin-sheet Ag/Ni-fiber catalyst for gas-phase selective oxidation of benzyl alcohol with molecular oxygen

Abstract

Keywords

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