Thermally Reversible Cross-Linking of Recyclable Polyamide Materials Based on Schiff Base and Diels–Alder Reactions

Wenjin Wu; Han Yang; Jiakang Liu; Yiqian Luo; Guanhuan Mo; Zhigao Hu; Lidong Zhang; Kun Huang

doi:10.1002/marc.202300252

Thermally Reversible Cross-Linking of Recyclable Polyamide Materials Based on Schiff Base and Diels–Alder Reactions

Wenjin Wu, Han Yang, Jiakang Liu, Yiqian Luo, Guanhuan Mo, Zhigao Hu, Lidong Zhang^*, Kun Huang^*

^*Corresponding author for this work

East China Normal University

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Recyclability of cross-link polymer materials is essential to alleviate environmental pollution caused by discarded or damaged polymers. Herein, a facile method for producing recyclable polyamide materials is developed. Linear polymer chains are constructed by Schiff base reaction between glutaraldehyde (GD) and furandiamine (FD). The linear polymer chains are crosslinked by bismaleimide (BM) to give rise to polyamide material, named GF-BMs. The resulting GF-BMs polyamide material possesses strong tensile strength (78 MPa) and good solvent resistance from room temperature to 135 °C. Especially, the thermally reversible Diels–Alder covalent bonds and dynamic imine bonds in the polymer network have a synergistic effect on fast-reprocessing, self-healing, and recyclability, which provides a new idea for recyclable materials.

Original language	English
Article number	2300252
Journal	Macromolecular Rapid Communications
Volume	44
Issue number	19
DOIs	https://doi.org/10.1002/marc.202300252
State	Published - Oct 2023

Keywords

Diels–Alder reaction
Schiff base
polyamide materials
recyclability
reprocessability

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1002/marc.202300252

Cite this

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title = "Thermally Reversible Cross-Linking of Recyclable Polyamide Materials Based on Schiff Base and Diels–Alder Reactions",

abstract = "Recyclability of cross-link polymer materials is essential to alleviate environmental pollution caused by discarded or damaged polymers. Herein, a facile method for producing recyclable polyamide materials is developed. Linear polymer chains are constructed by Schiff base reaction between glutaraldehyde (GD) and furandiamine (FD). The linear polymer chains are crosslinked by bismaleimide (BM) to give rise to polyamide material, named GF-BMs. The resulting GF-BMs polyamide material possesses strong tensile strength (78 MPa) and good solvent resistance from room temperature to 135 °C. Especially, the thermally reversible Diels–Alder covalent bonds and dynamic imine bonds in the polymer network have a synergistic effect on fast-reprocessing, self-healing, and recyclability, which provides a new idea for recyclable materials.",

keywords = "Diels–Alder reaction, Schiff base, polyamide materials, recyclability, reprocessability",

author = "Wenjin Wu and Han Yang and Jiakang Liu and Yiqian Luo and Guanhuan Mo and Zhigao Hu and Lidong Zhang and Kun Huang",

note = "Publisher Copyright: {\textcopyright} 2023 Wiley-VCH GmbH.",

year = "2023",

month = oct,

doi = "10.1002/marc.202300252",

language = "英语",

volume = "44",

journal = "Macromolecular Rapid Communications",

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number = "19",

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T1 - Thermally Reversible Cross-Linking of Recyclable Polyamide Materials Based on Schiff Base and Diels–Alder Reactions

AU - Wu, Wenjin

AU - Yang, Han

AU - Liu, Jiakang

AU - Luo, Yiqian

AU - Mo, Guanhuan

AU - Hu, Zhigao

AU - Zhang, Lidong

AU - Huang, Kun

PY - 2023/10

Y1 - 2023/10

N2 - Recyclability of cross-link polymer materials is essential to alleviate environmental pollution caused by discarded or damaged polymers. Herein, a facile method for producing recyclable polyamide materials is developed. Linear polymer chains are constructed by Schiff base reaction between glutaraldehyde (GD) and furandiamine (FD). The linear polymer chains are crosslinked by bismaleimide (BM) to give rise to polyamide material, named GF-BMs. The resulting GF-BMs polyamide material possesses strong tensile strength (78 MPa) and good solvent resistance from room temperature to 135 °C. Especially, the thermally reversible Diels–Alder covalent bonds and dynamic imine bonds in the polymer network have a synergistic effect on fast-reprocessing, self-healing, and recyclability, which provides a new idea for recyclable materials.

AB - Recyclability of cross-link polymer materials is essential to alleviate environmental pollution caused by discarded or damaged polymers. Herein, a facile method for producing recyclable polyamide materials is developed. Linear polymer chains are constructed by Schiff base reaction between glutaraldehyde (GD) and furandiamine (FD). The linear polymer chains are crosslinked by bismaleimide (BM) to give rise to polyamide material, named GF-BMs. The resulting GF-BMs polyamide material possesses strong tensile strength (78 MPa) and good solvent resistance from room temperature to 135 °C. Especially, the thermally reversible Diels–Alder covalent bonds and dynamic imine bonds in the polymer network have a synergistic effect on fast-reprocessing, self-healing, and recyclability, which provides a new idea for recyclable materials.

KW - Diels–Alder reaction

KW - Schiff base

KW - polyamide materials

KW - recyclability

KW - reprocessability

UR - https://www.scopus.com/pages/publications/85165906378

U2 - 10.1002/marc.202300252

DO - 10.1002/marc.202300252

M3 - 文章

AN - SCOPUS:85165906378

SN - 1022-1336

VL - 44

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 19

M1 - 2300252

ER -

Thermally Reversible Cross-Linking of Recyclable Polyamide Materials Based on Schiff Base and Diels–Alder Reactions

Abstract

Keywords

UN SDGs

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