The synthesis of new 60° organometallic subunits and self-assembly of three-dimensional M3L2 trigonal-bipyramidal cages

Hai Bo Yang; Koushik Ghosh; Atta M. Arif; Peter J. Stang

doi:10.1021/jo061779j

The synthesis of new 60° organometallic subunits and self-assembly of three-dimensional M₃L₂ trigonal-bipyramidal cages

Hai Bo Yang, Koushik Ghosh, Atta M. Arif, Peter J. Stang

University of Utah

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

(Figure Presented) By employing the coupling reaction of trans-PtI ₂(Et₃)₂ with C-H bonds in alkynes as the key step, two new 60° organometallic subunits with different size from 3,6-dibromophenanthrene were prepared in reasonable yields. The X-ray structures of both di-Pt(II) diiodide complexes showed that they were indeed suitable candidates for 60° building units. By utilizing these novel linkers as ditopic acceptor subunits, three M₃L₂ trigonal-bipyramidal (TBP) cages were formed. All three TBP cages were characterized with multinuclear NMR and electrospray ionization mass spectrometry (ESI-MS) along with element analysis.

Original language	English
Pages (from-to)	9464-9469
Number of pages	6
Journal	Journal of Organic Chemistry
Volume	71
Issue number	25
DOIs	https://doi.org/10.1021/jo061779j
State	Published - 8 Dec 2006
Externally published	Yes

Access to Document

10.1021/jo061779j

Cite this

@article{f5459cd7fe1f4ac39ff70820292090af,

title = "The synthesis of new 60° organometallic subunits and self-assembly of three-dimensional M3L2 trigonal-bipyramidal cages",

abstract = "(Figure Presented) By employing the coupling reaction of trans-PtI 2(Et3)2 with C-H bonds in alkynes as the key step, two new 60° organometallic subunits with different size from 3,6-dibromophenanthrene were prepared in reasonable yields. The X-ray structures of both di-Pt(II) diiodide complexes showed that they were indeed suitable candidates for 60° building units. By utilizing these novel linkers as ditopic acceptor subunits, three M3L2 trigonal-bipyramidal (TBP) cages were formed. All three TBP cages were characterized with multinuclear NMR and electrospray ionization mass spectrometry (ESI-MS) along with element analysis.",

author = "Yang, \{Hai Bo\} and Koushik Ghosh and Arif, \{Atta M.\} and Stang, \{Peter J.\}",

year = "2006",

month = dec,

day = "8",

doi = "10.1021/jo061779j",

language = "英语",

volume = "71",

pages = "9464--9469",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "25",

}

TY - JOUR

T1 - The synthesis of new 60° organometallic subunits and self-assembly of three-dimensional M3L2 trigonal-bipyramidal cages

AU - Yang, Hai Bo

AU - Ghosh, Koushik

AU - Arif, Atta M.

AU - Stang, Peter J.

PY - 2006/12/8

Y1 - 2006/12/8

N2 - (Figure Presented) By employing the coupling reaction of trans-PtI 2(Et3)2 with C-H bonds in alkynes as the key step, two new 60° organometallic subunits with different size from 3,6-dibromophenanthrene were prepared in reasonable yields. The X-ray structures of both di-Pt(II) diiodide complexes showed that they were indeed suitable candidates for 60° building units. By utilizing these novel linkers as ditopic acceptor subunits, three M3L2 trigonal-bipyramidal (TBP) cages were formed. All three TBP cages were characterized with multinuclear NMR and electrospray ionization mass spectrometry (ESI-MS) along with element analysis.

AB - (Figure Presented) By employing the coupling reaction of trans-PtI 2(Et3)2 with C-H bonds in alkynes as the key step, two new 60° organometallic subunits with different size from 3,6-dibromophenanthrene were prepared in reasonable yields. The X-ray structures of both di-Pt(II) diiodide complexes showed that they were indeed suitable candidates for 60° building units. By utilizing these novel linkers as ditopic acceptor subunits, three M3L2 trigonal-bipyramidal (TBP) cages were formed. All three TBP cages were characterized with multinuclear NMR and electrospray ionization mass spectrometry (ESI-MS) along with element analysis.

UR - https://www.scopus.com/pages/publications/33845525182

U2 - 10.1021/jo061779j

DO - 10.1021/jo061779j

M3 - 文章

C2 - 17137374

AN - SCOPUS:33845525182

SN - 0022-3263

VL - 71

SP - 9464

EP - 9469

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 25

ER -

The synthesis of new 60° organometallic subunits and self-assembly of three-dimensional M₃L₂ trigonal-bipyramidal cages

Abstract

Access to Document

Other files and links

Fingerprint

Cite this