The study of electrochemical cycle for LiCoO2 by dual-mode EPR

Bei Hu; Fushan Geng; Ming Shen; Bingwen Hu

doi:10.1016/j.mrl.2022.04.002

The study of electrochemical cycle for LiCoO₂ by dual-mode EPR

Bei Hu
, Fushan Geng
, Ming Shen
, Bingwen Hu^*

^*Corresponding author for this work

School of Physics and Electronic Science

East China Normal University

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Dual-mode electron paramagnetic resonance (EPR) spectroscopy was employed to analyze redox mechanisms in lithium cobalt oxide LiCoO₂ (LCO) cathode material during delithiation and lithiation. It was found that the O3-II could not fully convert back to the pristine O3–I phase while oxygen vacancies quickly generate and accumulate during the cycling. Our study paves the way for better understanding the doping effects of different elements on LiCoO₂ in the future.

Original language	English
Pages (from-to)	61-66
Number of pages	6
Journal	Magnetic Resonance Letters
Volume	3
Issue number	1
DOIs	https://doi.org/10.1016/j.mrl.2022.04.002
State	Published - Feb 2023

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

EPR
LiCoO
Lithium-ion battery
Redox mechanism

Access to Document

10.1016/j.mrl.2022.04.002

Cite this

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title = "The study of electrochemical cycle for LiCoO2 by dual-mode EPR",

abstract = "Dual-mode electron paramagnetic resonance (EPR) spectroscopy was employed to analyze redox mechanisms in lithium cobalt oxide LiCoO2 (LCO) cathode material during delithiation and lithiation. It was found that the O3-II could not fully convert back to the pristine O3–I phase while oxygen vacancies quickly generate and accumulate during the cycling. Our study paves the way for better understanding the doping effects of different elements on LiCoO2 in the future.",

keywords = "EPR, LiCoO, Lithium-ion battery, Redox mechanism",

author = "Bei Hu and Fushan Geng and Ming Shen and Bingwen Hu",

note = "Publisher Copyright: {\textcopyright} 2022 The Authors",

year = "2023",

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doi = "10.1016/j.mrl.2022.04.002",

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AU - Hu, Bei

AU - Geng, Fushan

AU - Shen, Ming

AU - Hu, Bingwen

PY - 2023/2

Y1 - 2023/2

N2 - Dual-mode electron paramagnetic resonance (EPR) spectroscopy was employed to analyze redox mechanisms in lithium cobalt oxide LiCoO2 (LCO) cathode material during delithiation and lithiation. It was found that the O3-II could not fully convert back to the pristine O3–I phase while oxygen vacancies quickly generate and accumulate during the cycling. Our study paves the way for better understanding the doping effects of different elements on LiCoO2 in the future.

AB - Dual-mode electron paramagnetic resonance (EPR) spectroscopy was employed to analyze redox mechanisms in lithium cobalt oxide LiCoO2 (LCO) cathode material during delithiation and lithiation. It was found that the O3-II could not fully convert back to the pristine O3–I phase while oxygen vacancies quickly generate and accumulate during the cycling. Our study paves the way for better understanding the doping effects of different elements on LiCoO2 in the future.

KW - EPR

KW - LiCoO

KW - Lithium-ion battery

KW - Redox mechanism

UR - https://www.scopus.com/pages/publications/85150402896

U2 - 10.1016/j.mrl.2022.04.002

DO - 10.1016/j.mrl.2022.04.002

M3 - 文章

AN - SCOPUS:85150402896

SN - 2097-0048

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JO - Magnetic Resonance Letters

JF - Magnetic Resonance Letters

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