The Same Oxidation-State Introduction of Hypervalent Sulfur via Transition-Metal Catalysis

Sulfonyl compounds have attracted considerable interest due to their extensive applications in drug discovery, agricultural, and material science. The access to the assembly of SO₂-containing compounds via the same oxidative-state introduction of hypervalent sulfur has come to the fore in the recent years. Especially, the transition-metal-involved synthesis of hypervalent sulfur compounds is the most effective strategy since SO₂ is easy to insert into the metal-carbon bonds. This review discusses the application of the same oxidation-state introduction of hypervalent sulfur strategy under the transition-metal-catalyzed conditions, and presents according to different metal catalysts and the synthesized diversity hypervalent sulfur-containing compounds skeletons, including sulfonamides, sulfones, sulfinamides, sulfonyl acids and sulfonyl fluorides.