The ionic palladium porphyrin as a highly efficient and recyclable catalyst for heck reaction in ionic liquid solution under aerobic conditions

The ionic palladium porphyrin featured with pyridinium tags at four meso-positions, palladium tetrakis-(N-methyl-4-pyridinium)-porphyrin iodide ([Pd(II)TMPy)P][I]₄ (3), embedded in the similar structured ionic liquid of N-butyl pyridinium tetrafluoroborate ([Bpy]BF₄) was found to be a highly efficient and recyclable catalytic system for the Heck cross-coupling of iodobenzene (derivatives) and ethyl acylate, with high turnover frequency of 56,000 h^-1 under aerobic conditions. The active charge transfer transition occurred in 3-[Bpy]BF₄ system during the Heck reaction could account for the efficiency in the catalytic coupling, which was observed in the UV-visible spectra.