The intermediate temperature T* revealed in relaxor polymers

B. L. Liu; B. B. Tian; S. Geiger; Z. G. Hu; X. L. Zhao; Y. H. Zou; J. L. Wang; J. L. Sun; S. Sun; B. Dkhil; X. J. Meng; J. H. Chu

doi:10.1063/1.4881268

The intermediate temperature T* revealed in relaxor polymers

B. L. Liu, B. B. Tian, S. Geiger, Z. G. Hu, X. L. Zhao, Y. H. Zou, J. L. Wang, J. L. Sun, S. Sun, B. Dkhil, X. J. Meng, J. H. Chu

School of Physics and Electronic Science

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The temperature dependence of the dielectric and optical properties, crystal structure, and infrared spectra of the relaxor poly(vinylidenefluoride- trifluoroethylene-chlorofluoroethylene) terpolymer films obtained from Langmuir-Blodgett method have been comprehensively investigated. All the results suggest that there exists a peculiar point at ∼370 K, which is attributed to the intermediate temperature T* recently discovered in inorganic relaxors. Here, T* results from the change in the growth rate of the trans gauche T₃GT₃G′ chain conformations with temperature, which is similar to the transformation from dynamic to static behavior of the so-called polar nano-regions in inorganic relaxors.

Original language	English
Article number	222907
Journal	Applied Physics Letters
Volume	104
Issue number	22
DOIs	https://doi.org/10.1063/1.4881268
State	Published - 2 Jun 2014

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title = "The intermediate temperature T* revealed in relaxor polymers",

abstract = "The temperature dependence of the dielectric and optical properties, crystal structure, and infrared spectra of the relaxor poly(vinylidenefluoride- trifluoroethylene-chlorofluoroethylene) terpolymer films obtained from Langmuir-Blodgett method have been comprehensively investigated. All the results suggest that there exists a peculiar point at ∼370 K, which is attributed to the intermediate temperature T* recently discovered in inorganic relaxors. Here, T* results from the change in the growth rate of the trans gauche T3GT3G′ chain conformations with temperature, which is similar to the transformation from dynamic to static behavior of the so-called polar nano-regions in inorganic relaxors.",

author = "Liu, \{B. L.\} and Tian, \{B. B.\} and S. Geiger and Hu, \{Z. G.\} and Zhao, \{X. L.\} and Zou, \{Y. H.\} and Wang, \{J. L.\} and Sun, \{J. L.\} and S. Sun and B. Dkhil and Meng, \{X. J.\} and Chu, \{J. H.\}",

year = "2014",

month = jun,

day = "2",

doi = "10.1063/1.4881268",

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T1 - The intermediate temperature T* revealed in relaxor polymers

AU - Liu, B. L.

AU - Tian, B. B.

AU - Geiger, S.

AU - Hu, Z. G.

AU - Zhao, X. L.

AU - Zou, Y. H.

AU - Wang, J. L.

AU - Sun, J. L.

AU - Sun, S.

AU - Dkhil, B.

AU - Meng, X. J.

AU - Chu, J. H.

PY - 2014/6/2

Y1 - 2014/6/2

N2 - The temperature dependence of the dielectric and optical properties, crystal structure, and infrared spectra of the relaxor poly(vinylidenefluoride- trifluoroethylene-chlorofluoroethylene) terpolymer films obtained from Langmuir-Blodgett method have been comprehensively investigated. All the results suggest that there exists a peculiar point at ∼370 K, which is attributed to the intermediate temperature T* recently discovered in inorganic relaxors. Here, T* results from the change in the growth rate of the trans gauche T3GT3G′ chain conformations with temperature, which is similar to the transformation from dynamic to static behavior of the so-called polar nano-regions in inorganic relaxors.

AB - The temperature dependence of the dielectric and optical properties, crystal structure, and infrared spectra of the relaxor poly(vinylidenefluoride- trifluoroethylene-chlorofluoroethylene) terpolymer films obtained from Langmuir-Blodgett method have been comprehensively investigated. All the results suggest that there exists a peculiar point at ∼370 K, which is attributed to the intermediate temperature T* recently discovered in inorganic relaxors. Here, T* results from the change in the growth rate of the trans gauche T3GT3G′ chain conformations with temperature, which is similar to the transformation from dynamic to static behavior of the so-called polar nano-regions in inorganic relaxors.

UR - https://www.scopus.com/pages/publications/84902449329

U2 - 10.1063/1.4881268

DO - 10.1063/1.4881268

M3 - 文章

AN - SCOPUS:84902449329

SN - 0003-6951

VL - 104

JO - Applied Physics Letters

JF - Applied Physics Letters

IS - 22

M1 - 222907

ER -

The intermediate temperature T* revealed in relaxor polymers

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