The iffect of aetiwation/deactivation processes on the microcomposition and microsequence structure of controlled/owing copolymers

Ying Shi; Xuelian Qin; Yumei Guo; Meiran Xie; Yiqun Zhang

doi:10.1002/mats.200700082

The iffect of aetiwation/deactivation processes on the microcomposition and microsequence structure of controlled/owing copolymers

Ying Shi
, Xuelian Qin
, Yumei Guo
, Meiran Xie
, Yiqun Zhang^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

A new method is proposed to study the process of controlled/living radical copolymerization as well as the structures of the products. Computer simulation has been carried out to produce this LRP or CRP propagation including the activation/deactivation process. The information about segment distribution was obtained for the first time. The results show that under a stationary condition, controlled/living copolymer's composition and sequence distribution are totally identical to those prepared from the conventional free radical copolymerization (FRcP). In other words, the activation/deactivation process of controlled/liYing radical copolymerization has no effect on copolymer's microcomposition and microsequence structure.

Original language	English
Pages (from-to)	130-136
Number of pages	7
Journal	Macromolecular Theory and Simulations
Volume	17
Issue number	2-3
DOIs	https://doi.org/10.1002/mats.200700082
State	Published - 16 Apr 2008

Keywords

Activation/deactivation process
Controlled/living polymerization
Segment distribution
Simulations

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10.1002/mats.200700082

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title = "The iffect of aetiwation/deactivation processes on the microcomposition and microsequence structure of controlled/owing copolymers",

abstract = "A new method is proposed to study the process of controlled/living radical copolymerization as well as the structures of the products. Computer simulation has been carried out to produce this LRP or CRP propagation including the activation/deactivation process. The information about segment distribution was obtained for the first time. The results show that under a stationary condition, controlled/living copolymer's composition and sequence distribution are totally identical to those prepared from the conventional free radical copolymerization (FRcP). In other words, the activation/deactivation process of controlled/liYing radical copolymerization has no effect on copolymer's microcomposition and microsequence structure.",

keywords = "Activation/deactivation process, Controlled/living polymerization, Segment distribution, Simulations",

author = "Ying Shi and Xuelian Qin and Yumei Guo and Meiran Xie and Yiqun Zhang",

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T1 - The iffect of aetiwation/deactivation processes on the microcomposition and microsequence structure of controlled/owing copolymers

AU - Shi, Ying

AU - Qin, Xuelian

AU - Guo, Yumei

AU - Xie, Meiran

AU - Zhang, Yiqun

PY - 2008/4/16

Y1 - 2008/4/16

N2 - A new method is proposed to study the process of controlled/living radical copolymerization as well as the structures of the products. Computer simulation has been carried out to produce this LRP or CRP propagation including the activation/deactivation process. The information about segment distribution was obtained for the first time. The results show that under a stationary condition, controlled/living copolymer's composition and sequence distribution are totally identical to those prepared from the conventional free radical copolymerization (FRcP). In other words, the activation/deactivation process of controlled/liYing radical copolymerization has no effect on copolymer's microcomposition and microsequence structure.

AB - A new method is proposed to study the process of controlled/living radical copolymerization as well as the structures of the products. Computer simulation has been carried out to produce this LRP or CRP propagation including the activation/deactivation process. The information about segment distribution was obtained for the first time. The results show that under a stationary condition, controlled/living copolymer's composition and sequence distribution are totally identical to those prepared from the conventional free radical copolymerization (FRcP). In other words, the activation/deactivation process of controlled/liYing radical copolymerization has no effect on copolymer's microcomposition and microsequence structure.

KW - Activation/deactivation process

KW - Controlled/living polymerization

KW - Segment distribution

KW - Simulations

UR - https://www.scopus.com/pages/publications/55349117475

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DO - 10.1002/mats.200700082

M3 - 文章

AN - SCOPUS:55349117475

SN - 1022-1344

VL - 17

SP - 130

EP - 136

JO - Macromolecular Theory and Simulations

JF - Macromolecular Theory and Simulations

IS - 2-3

ER -

The iffect of aetiwation/deactivation processes on the microcomposition and microsequence structure of controlled/owing copolymers

Abstract

Keywords

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