TY - JOUR
T1 - The decomposition and ecological risk of DDTs and HCHs in the soil-water system of the Meijiang River
AU - He, Wenming
AU - Ye, Mengling
AU - He, Hongming
AU - Zhu, Mingyong
AU - Li, Yu
N1 - Publisher Copyright:
© 2019
PY - 2020/1
Y1 - 2020/1
N2 - This research project was designed to study the residues of OCPs (organochlorine pesticides) in the sediments of the Meijiang River Basin. Samples from the Meijiang River Basin were analyzed by gas chromatography-mass spectrometry after being pretreated by Soxhlet extraction, and their compositions, distributions and sources were evaluated. The current study presents the distribution of OCPs in the soils and sediments of the Meijiang River Basin. The results demonstrate that OCPs contamination is an important environmental concern due to the excessive use of these compounds in the agricultural and industrial sectors. The ratios of α-HCH/γ-HCH, (DDE + DDD)/∑DDTs, p,p-DDT/o,p-DDT, and DDD/DDE were used as indices for identifying the possible pollution sources and assessing the decomposition of the parent compounds and the recent γ-HCH and DDT inputs. At the XY (Xiyang) and DSGYY (Dongshenggongyeyan) sites, the pollutants had industrial origins. At other sites (QTH (Qutianhu), LXC (Longxichun), ZJC (Zhenjiaochun), HKC (Hekouchun), GS (Guangshan) and RGQ (Raogongqiao)), the pollution was caused by dissolved organic matter. The SHB site was polluted by transportation and upstream pollutants. At the SXC (Shixichun), YZX (Youzhihe), DSH (Dongshihe) and ZGG (Zhegupai) sites, the metabolite was p,p'-DDD and was produced in an environment with anaerobic conditions. At the FJC (Fujiangkou), QTH (Qiutianhu), GS (Guangshang) and MX (Meixi) sites, the metabolite was DDE and was produced under aerobic conditions. In view of the health risks, the risk quotients for these contaminants were evaluated, and all risk quotients were less than 1 under the best-case scenario. This result suggests that the investigated pollutants may pose little hazard to the local ecosystem. The sediments containing toxic pesticides had a less than 55% ecological risk, indicating that the ecological risk of HCHs in the soils from the Meijiang River Basin is low.
AB - This research project was designed to study the residues of OCPs (organochlorine pesticides) in the sediments of the Meijiang River Basin. Samples from the Meijiang River Basin were analyzed by gas chromatography-mass spectrometry after being pretreated by Soxhlet extraction, and their compositions, distributions and sources were evaluated. The current study presents the distribution of OCPs in the soils and sediments of the Meijiang River Basin. The results demonstrate that OCPs contamination is an important environmental concern due to the excessive use of these compounds in the agricultural and industrial sectors. The ratios of α-HCH/γ-HCH, (DDE + DDD)/∑DDTs, p,p-DDT/o,p-DDT, and DDD/DDE were used as indices for identifying the possible pollution sources and assessing the decomposition of the parent compounds and the recent γ-HCH and DDT inputs. At the XY (Xiyang) and DSGYY (Dongshenggongyeyan) sites, the pollutants had industrial origins. At other sites (QTH (Qutianhu), LXC (Longxichun), ZJC (Zhenjiaochun), HKC (Hekouchun), GS (Guangshan) and RGQ (Raogongqiao)), the pollution was caused by dissolved organic matter. The SHB site was polluted by transportation and upstream pollutants. At the SXC (Shixichun), YZX (Youzhihe), DSH (Dongshihe) and ZGG (Zhegupai) sites, the metabolite was p,p'-DDD and was produced in an environment with anaerobic conditions. At the FJC (Fujiangkou), QTH (Qiutianhu), GS (Guangshang) and MX (Meixi) sites, the metabolite was DDE and was produced under aerobic conditions. In view of the health risks, the risk quotients for these contaminants were evaluated, and all risk quotients were less than 1 under the best-case scenario. This result suggests that the investigated pollutants may pose little hazard to the local ecosystem. The sediments containing toxic pesticides had a less than 55% ecological risk, indicating that the ecological risk of HCHs in the soils from the Meijiang River Basin is low.
KW - Meijiang river basin
KW - Organochlorine
KW - Sediments
KW - Soil-water system
UR - https://www.scopus.com/pages/publications/85075363151
U2 - 10.1016/j.envres.2019.108897
DO - 10.1016/j.envres.2019.108897
M3 - 文章
C2 - 31733727
AN - SCOPUS:85075363151
SN - 0013-9351
VL - 180
JO - Environmental Research
JF - Environmental Research
M1 - 108897
ER -
