Tetraaquadiazidocobalt(II) 3,3′-dicarboxylato-1,1′- ethylenedipyridinium

Yan Qing Wen; Chun Yan Tian; En Qing Gao

doi:10.1107/S1600536810046143

Tetraaquadiazidocobalt(II) 3,3′-dicarboxylato-1,1′- ethylenedipyridinium

Yan Qing Wen
, Chun Yan Tian
, En Qing Gao^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

Abstract

The asymmetric unit of the title compound, [Co(N₃) ₂(H₂O)₄]·C₁₄H ₁₂N₂O₄, comprises half of the cobalt(II) complex molecule and a half of the 3,3′-dicarboxylato-1,1′- ethylenedipyridinium molecule. The Co^II atom is located on an inversion centre and hence the complex molecule adopts a centrosymmetric trans-octa-hedral geometry. The zwitterionic organic molecule is also centrosymmetric with the centre of the C - C bond of the ethylene moiety coinciding with an inversion centre. The adduct of metal complex and organic molecule is associated into a three-dimenional network through O - H⋯O hydrogen bonds.

Original language	English
Pages (from-to)	m1566-m1567
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	12
DOIs	https://doi.org/10.1107/S1600536810046143
State	Published - Dec 2010

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title = "Tetraaquadiazidocobalt(II) 3,3′-dicarboxylato-1,1′- ethylenedipyridinium",

abstract = "The asymmetric unit of the title compound, [Co(N3) 2(H2O)4]·C14H 12N2O4, comprises half of the cobalt(II) complex molecule and a half of the 3,3′-dicarboxylato-1,1′- ethylenedipyridinium molecule. The CoII atom is located on an inversion centre and hence the complex molecule adopts a centrosymmetric trans-octa-hedral geometry. The zwitterionic organic molecule is also centrosymmetric with the centre of the C - C bond of the ethylene moiety coinciding with an inversion centre. The adduct of metal complex and organic molecule is associated into a three-dimenional network through O - H⋯O hydrogen bonds.",

author = "Wen, \{Yan Qing\} and Tian, \{Chun Yan\} and Gao, \{En Qing\}",

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doi = "10.1107/S1600536810046143",

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T1 - Tetraaquadiazidocobalt(II) 3,3′-dicarboxylato-1,1′- ethylenedipyridinium

AU - Wen, Yan Qing

AU - Tian, Chun Yan

AU - Gao, En Qing

PY - 2010/12

Y1 - 2010/12

N2 - The asymmetric unit of the title compound, [Co(N3) 2(H2O)4]·C14H 12N2O4, comprises half of the cobalt(II) complex molecule and a half of the 3,3′-dicarboxylato-1,1′- ethylenedipyridinium molecule. The CoII atom is located on an inversion centre and hence the complex molecule adopts a centrosymmetric trans-octa-hedral geometry. The zwitterionic organic molecule is also centrosymmetric with the centre of the C - C bond of the ethylene moiety coinciding with an inversion centre. The adduct of metal complex and organic molecule is associated into a three-dimenional network through O - H⋯O hydrogen bonds.

AB - The asymmetric unit of the title compound, [Co(N3) 2(H2O)4]·C14H 12N2O4, comprises half of the cobalt(II) complex molecule and a half of the 3,3′-dicarboxylato-1,1′- ethylenedipyridinium molecule. The CoII atom is located on an inversion centre and hence the complex molecule adopts a centrosymmetric trans-octa-hedral geometry. The zwitterionic organic molecule is also centrosymmetric with the centre of the C - C bond of the ethylene moiety coinciding with an inversion centre. The adduct of metal complex and organic molecule is associated into a three-dimenional network through O - H⋯O hydrogen bonds.

UR - https://www.scopus.com/pages/publications/78650090988

U2 - 10.1107/S1600536810046143

DO - 10.1107/S1600536810046143

M3 - 文章

AN - SCOPUS:78650090988

SN - 1600-5368

VL - 66

SP - m1566-m1567

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -

Tetraaquadiazidocobalt(II) 3,3′-dicarboxylato-1,1′- ethylenedipyridinium

Abstract

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