Tetra-aqua-diazido-cobalt(II) 4,4′-dicarboxyl-ato-1,1′-ethyl- enedi-pyridinium dihydrate

Kun Wang; Yan Qin Wang; Jian Yong Zhang; En Qing Gao

doi:10.1107/S1600536809049848

Tetra-aqua-diazido-cobalt(II) 4,4′-dicarboxyl-ato-1,1′-ethyl- enedi-pyridinium dihydrate

Kun Wang
, Yan Qin Wang
, Jian Yong Zhang
, En Qing Gao^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

In the title compound, [Co(N₃)2(H₂O)4]·C ₁₄H₁₂N₂O₄·2H₂O, the metal complex mol-ecule is centrosymmetric, the Co(II) ion being six-coordinated by two azide N atoms and four aqua O atoms with a trans-octa-hedral geometry. The zwitterionic organic mol-ecule is also centrosymmetric. In the crystal, the components are associated into a two-dimensional network through O - H⋯O hydrogen bonds. Further O - H⋯O and O - H⋯N inter-actions give a three-dimensional structure. The free water molecule is disordered over two positions in a 0.787 (5):0.213 (5) ratio.

Original language	English
Pages (from-to)	m1682
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	65
Issue number	12
DOIs	https://doi.org/10.1107/S1600536809049848
State	Published - 2009

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@article{7bddb8117e4646d89035dfe521856199,

title = "Tetra-aqua-diazido-cobalt(II) 4,4′-dicarboxyl-ato-1,1′-ethyl- enedi-pyridinium dihydrate",

abstract = "In the title compound, [Co(N3)2(H2O)4]·C 14H12N2O4·2H2O, the metal complex mol-ecule is centrosymmetric, the Co(II) ion being six-coordinated by two azide N atoms and four aqua O atoms with a trans-octa-hedral geometry. The zwitterionic organic mol-ecule is also centrosymmetric. In the crystal, the components are associated into a two-dimensional network through O - H⋯O hydrogen bonds. Further O - H⋯O and O - H⋯N inter-actions give a three-dimensional structure. The free water molecule is disordered over two positions in a 0.787 (5):0.213 (5) ratio.",

author = "Kun Wang and Wang, \{Yan Qin\} and Zhang, \{Jian Yong\} and Gao, \{En Qing\}",

year = "2009",

doi = "10.1107/S1600536809049848",

language = "英语",

volume = "65",

pages = "m1682",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "12",

}

TY - JOUR

T1 - Tetra-aqua-diazido-cobalt(II) 4,4′-dicarboxyl-ato-1,1′-ethyl- enedi-pyridinium dihydrate

AU - Wang, Kun

AU - Wang, Yan Qin

AU - Zhang, Jian Yong

AU - Gao, En Qing

PY - 2009

Y1 - 2009

N2 - In the title compound, [Co(N3)2(H2O)4]·C 14H12N2O4·2H2O, the metal complex mol-ecule is centrosymmetric, the Co(II) ion being six-coordinated by two azide N atoms and four aqua O atoms with a trans-octa-hedral geometry. The zwitterionic organic mol-ecule is also centrosymmetric. In the crystal, the components are associated into a two-dimensional network through O - H⋯O hydrogen bonds. Further O - H⋯O and O - H⋯N inter-actions give a three-dimensional structure. The free water molecule is disordered over two positions in a 0.787 (5):0.213 (5) ratio.

AB - In the title compound, [Co(N3)2(H2O)4]·C 14H12N2O4·2H2O, the metal complex mol-ecule is centrosymmetric, the Co(II) ion being six-coordinated by two azide N atoms and four aqua O atoms with a trans-octa-hedral geometry. The zwitterionic organic mol-ecule is also centrosymmetric. In the crystal, the components are associated into a two-dimensional network through O - H⋯O hydrogen bonds. Further O - H⋯O and O - H⋯N inter-actions give a three-dimensional structure. The free water molecule is disordered over two positions in a 0.787 (5):0.213 (5) ratio.

UR - https://www.scopus.com/pages/publications/72049094532

U2 - 10.1107/S1600536809049848

DO - 10.1107/S1600536809049848

M3 - 文章

AN - SCOPUS:72049094532

SN - 1600-5368

VL - 65

SP - m1682

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -

Tetra-aqua-diazido-cobalt(II) 4,4′-dicarboxyl-ato-1,1′-ethyl- enedi-pyridinium dihydrate

Abstract

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