Tert-butylation of p-cresol catalyzed by Al-MCM-41 mesoporous molecular sieves

Xin yu Yu; Cai hua Liu; Wen ping Cheng; Jian guo Yang; Ming yuan He

Tert-butylation of p-cresol catalyzed by Al-MCM-41 mesoporous molecular sieves

Xin yu Yu^*
, Cai hua Liu
, Wen ping Cheng
, Jian guo Yang
, Ming yuan He

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Mesoporous molecular sieves Al-MCM-1 with n(SiO₂)/n(Al₂O₃) ratios of 20:1, 50:1, and 100:1 were prepared. The as-synthesized Al-MCM-41 exhibited typical hexagonal structure, large surface areas, and narrow pore distribution. The performance of HAl-MCM-41 as catalyst for tert-butylation of p-cresol with MTBE was studied. The mesoporous HAl-MCM-41 molecular sieves (n(SiO₂/n(Al₂O₃) = 20:1) was an efficient catalyst with high activity, selectivity, and stability for the synthesis of 2-tert-butyl-p-cresol from p-cresol and MTBE by tert-butylation.

Original language	English
Pages (from-to)	757-760
Number of pages	4
Journal	Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology
Volume	34
Issue number	6
State	Published - Dec 2006

Keywords

2-tert-butyl-p-cresol
Catalysis
Mesoporous HA1-MCM41 molecular sieves
Methyl tert-butyl-ether
p-Cresol

Cite this

@article{79da72f7e1b542fdb1c925e40261d6b6,

title = "Tert-butylation of p-cresol catalyzed by Al-MCM-41 mesoporous molecular sieves",

abstract = "Mesoporous molecular sieves Al-MCM-1 with n(SiO2)/n(Al2O3) ratios of 20:1, 50:1, and 100:1 were prepared. The as-synthesized Al-MCM-41 exhibited typical hexagonal structure, large surface areas, and narrow pore distribution. The performance of HAl-MCM-41 as catalyst for tert-butylation of p-cresol with MTBE was studied. The mesoporous HAl-MCM-41 molecular sieves (n(SiO2/n(Al2O3) = 20:1) was an efficient catalyst with high activity, selectivity, and stability for the synthesis of 2-tert-butyl-p-cresol from p-cresol and MTBE by tert-butylation.",

keywords = "2-tert-butyl-p-cresol, Catalysis, Mesoporous HA1-MCM41 molecular sieves, Methyl tert-butyl-ether, p-Cresol",

author = "Yu, \{Xin yu\} and Liu, \{Cai hua\} and Cheng, \{Wen ping\} and Yang, \{Jian guo\} and He, \{Ming yuan\}",

year = "2006",

month = dec,

language = "英语",

volume = "34",

pages = "757--760",

journal = "Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology",

issn = "2097-213X",

publisher = "Science Press ",

number = "6",

}

TY - JOUR

T1 - Tert-butylation of p-cresol catalyzed by Al-MCM-41 mesoporous molecular sieves

AU - Yu, Xin yu

AU - Liu, Cai hua

AU - Cheng, Wen ping

AU - Yang, Jian guo

AU - He, Ming yuan

PY - 2006/12

Y1 - 2006/12

N2 - Mesoporous molecular sieves Al-MCM-1 with n(SiO2)/n(Al2O3) ratios of 20:1, 50:1, and 100:1 were prepared. The as-synthesized Al-MCM-41 exhibited typical hexagonal structure, large surface areas, and narrow pore distribution. The performance of HAl-MCM-41 as catalyst for tert-butylation of p-cresol with MTBE was studied. The mesoporous HAl-MCM-41 molecular sieves (n(SiO2/n(Al2O3) = 20:1) was an efficient catalyst with high activity, selectivity, and stability for the synthesis of 2-tert-butyl-p-cresol from p-cresol and MTBE by tert-butylation.

AB - Mesoporous molecular sieves Al-MCM-1 with n(SiO2)/n(Al2O3) ratios of 20:1, 50:1, and 100:1 were prepared. The as-synthesized Al-MCM-41 exhibited typical hexagonal structure, large surface areas, and narrow pore distribution. The performance of HAl-MCM-41 as catalyst for tert-butylation of p-cresol with MTBE was studied. The mesoporous HAl-MCM-41 molecular sieves (n(SiO2/n(Al2O3) = 20:1) was an efficient catalyst with high activity, selectivity, and stability for the synthesis of 2-tert-butyl-p-cresol from p-cresol and MTBE by tert-butylation.

KW - 2-tert-butyl-p-cresol

KW - Catalysis

KW - Mesoporous HA1-MCM41 molecular sieves

KW - Methyl tert-butyl-ether

KW - p-Cresol

UR - https://www.scopus.com/pages/publications/33846785200

M3 - 文章

AN - SCOPUS:33846785200

SN - 2097-213X

VL - 34

SP - 757

EP - 760

JO - Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology

JF - Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology

IS - 6

ER -

Tert-butylation of p-cresol catalyzed by Al-MCM-41 mesoporous molecular sieves

Abstract

Keywords

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