Terbium Tetra-Sulfosalicylate Complex as Quantitative Luminescent Sensing of Chromate Ions with High Selectivity and Sensitivity

Wei Yang; Jinfeng Xia; Guohong Zhou; Tianxi Hu; Danwang Ye; Danyu Jiang; Qiang Li

doi:10.1002/bkcs.11495

Terbium Tetra-Sulfosalicylate Complex as Quantitative Luminescent Sensing of Chromate Ions with High Selectivity and Sensitivity

Wei Yang, Jinfeng Xia, Guohong Zhou, Tianxi Hu, Danwang Ye, Danyu Jiang, Qiang Li

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

In this study, a terbium(Ш) complex, Tb(SSA) ₄ (SSA = sulfosalicylate), was synthesized and employed to detect toxic chromate anion (CrO ₄ ²⁻ ) as a visually identifiable probe. Luminescence investigations confirmed that the Tb complex is an excellent probe with high selectivity, high sensitivity (I ₀ /I _{100 μM} = 9.5), and a low detection limit (2.8 × 10 ⁻⁸ M), targeting CrO ₄ ²⁻ in aqueous solution. The simple fluorescence-based probe can be quickly and easily prepared, and enables the reliable, visual detection of CrO ₄ ²⁻ ion in daily applications.

Original language	English
Pages (from-to)	399-403
Number of pages	5
Journal	Bulletin of the Korean Chemical Society
Volume	40
Issue number	5
DOIs	https://doi.org/10.1002/bkcs.11495
State	Published - May 2019

Keywords

CrO
Fluorescence-based probe
Terbium(Ш) complex

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10.1002/bkcs.11495

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@article{847f4a8da8004500920fc03640c509a4,

title = "Terbium Tetra-Sulfosalicylate Complex as Quantitative Luminescent Sensing of Chromate Ions with High Selectivity and Sensitivity",

abstract = " In this study, a terbium(Ш) complex, Tb(SSA) 4 (SSA = sulfosalicylate), was synthesized and employed to detect toxic chromate anion (CrO 4 2− ) as a visually identifiable probe. Luminescence investigations confirmed that the Tb complex is an excellent probe with high selectivity, high sensitivity (I 0 /I 100 μM = 9.5), and a low detection limit (2.8 × 10 −8 M), targeting CrO 4 2− in aqueous solution. The simple fluorescence-based probe can be quickly and easily prepared, and enables the reliable, visual detection of CrO 4 2− ion in daily applications.",

keywords = "CrO, Fluorescence-based probe, Terbium(Ш) complex",

author = "Wei Yang and Jinfeng Xia and Guohong Zhou and Tianxi Hu and Danwang Ye and Danyu Jiang and Qiang Li",

note = "Publisher Copyright: {\textcopyright} 2019 Korean Chemical Society, Seoul \& Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2019",

month = may,

doi = "10.1002/bkcs.11495",

language = "英语",

volume = "40",

pages = "399--403",

journal = "Bulletin of the Korean Chemical Society",

issn = "0253-2964",

publisher = "Wiley-Blackwell",

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TY - JOUR

T1 - Terbium Tetra-Sulfosalicylate Complex as Quantitative Luminescent Sensing of Chromate Ions with High Selectivity and Sensitivity

AU - Yang, Wei

AU - Xia, Jinfeng

AU - Zhou, Guohong

AU - Hu, Tianxi

AU - Ye, Danwang

AU - Jiang, Danyu

AU - Li, Qiang

PY - 2019/5

Y1 - 2019/5

N2 - In this study, a terbium(Ш) complex, Tb(SSA) 4 (SSA = sulfosalicylate), was synthesized and employed to detect toxic chromate anion (CrO 4 2− ) as a visually identifiable probe. Luminescence investigations confirmed that the Tb complex is an excellent probe with high selectivity, high sensitivity (I 0 /I 100 μM = 9.5), and a low detection limit (2.8 × 10 −8 M), targeting CrO 4 2− in aqueous solution. The simple fluorescence-based probe can be quickly and easily prepared, and enables the reliable, visual detection of CrO 4 2− ion in daily applications.

AB - In this study, a terbium(Ш) complex, Tb(SSA) 4 (SSA = sulfosalicylate), was synthesized and employed to detect toxic chromate anion (CrO 4 2− ) as a visually identifiable probe. Luminescence investigations confirmed that the Tb complex is an excellent probe with high selectivity, high sensitivity (I 0 /I 100 μM = 9.5), and a low detection limit (2.8 × 10 −8 M), targeting CrO 4 2− in aqueous solution. The simple fluorescence-based probe can be quickly and easily prepared, and enables the reliable, visual detection of CrO 4 2− ion in daily applications.

KW - CrO

KW - Fluorescence-based probe

KW - Terbium(Ш) complex

UR - https://www.scopus.com/pages/publications/85062982633

U2 - 10.1002/bkcs.11495

DO - 10.1002/bkcs.11495

M3 - 文章

AN - SCOPUS:85062982633

SN - 0253-2964

VL - 40

SP - 399

EP - 403

JO - Bulletin of the Korean Chemical Society

JF - Bulletin of the Korean Chemical Society

IS - 5

ER -

Terbium Tetra-Sulfosalicylate Complex as Quantitative Luminescent Sensing of Chromate Ions with High Selectivity and Sensitivity

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Keywords

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