Temperature control in the synthesis of cubic mesoporous silica materials

Lian Zhou Wang; Jian Lin Shi; Jian Yu; Wen Hua Zhang; Dong Sheng Yan

doi:10.1016/S0167-577X(00)00117-8

Temperature control in the synthesis of cubic mesoporous silica materials

Lian Zhou Wang
, Jian Lin Shi
, Jian Yu
, Wen Hua Zhang
, Dong Sheng Yan

CAS - Shanghai Institute of Ceramics

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

The cubic mesoporous silica MCM-48 materials have been synthesized by temperature control, and the properties of samples were investigated by using XRD, HREM and N₂ adsorption-desorption techniques. XRD results show that the mesophases synthesized at low temperature (≤75 °C) have a poorly ordered hexagonal structure, while hydrothermal treatment at higher temperature (≥95 °C) led to cubic MCM-48 mesophases. The effect of temperature on different mesophases can be due to the polymerization and condensation of silicate species at different temperatures, which results in the formation of curvatured hexagonal or cubic phase. HREM and N₂ isotherms of MCM-48 materials indicates well-ordered three-dimensional meso-channels.

Original language	English
Pages (from-to)	273-278
Number of pages	6
Journal	Materials Letters
Volume	45
Issue number	5
DOIs	https://doi.org/10.1016/S0167-577X(00)00117-8
State	Published - Sep 2000
Externally published	Yes

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10.1016/S0167-577X(00)00117-8

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title = "Temperature control in the synthesis of cubic mesoporous silica materials",

abstract = "The cubic mesoporous silica MCM-48 materials have been synthesized by temperature control, and the properties of samples were investigated by using XRD, HREM and N2 adsorption-desorption techniques. XRD results show that the mesophases synthesized at low temperature (≤75 °C) have a poorly ordered hexagonal structure, while hydrothermal treatment at higher temperature (≥95 °C) led to cubic MCM-48 mesophases. The effect of temperature on different mesophases can be due to the polymerization and condensation of silicate species at different temperatures, which results in the formation of curvatured hexagonal or cubic phase. HREM and N2 isotherms of MCM-48 materials indicates well-ordered three-dimensional meso-channels.",

author = "Wang, \{Lian Zhou\} and Shi, \{Jian Lin\} and Jian Yu and Zhang, \{Wen Hua\} and Yan, \{Dong Sheng\}",

year = "2000",

month = sep,

doi = "10.1016/S0167-577X(00)00117-8",

language = "英语",

volume = "45",

pages = "273--278",

journal = "Materials Letters",

issn = "0167-577X",

publisher = "Elsevier B.V.",

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}

TY - JOUR

T1 - Temperature control in the synthesis of cubic mesoporous silica materials

AU - Wang, Lian Zhou

AU - Shi, Jian Lin

AU - Yu, Jian

AU - Zhang, Wen Hua

AU - Yan, Dong Sheng

PY - 2000/9

Y1 - 2000/9

N2 - The cubic mesoporous silica MCM-48 materials have been synthesized by temperature control, and the properties of samples were investigated by using XRD, HREM and N2 adsorption-desorption techniques. XRD results show that the mesophases synthesized at low temperature (≤75 °C) have a poorly ordered hexagonal structure, while hydrothermal treatment at higher temperature (≥95 °C) led to cubic MCM-48 mesophases. The effect of temperature on different mesophases can be due to the polymerization and condensation of silicate species at different temperatures, which results in the formation of curvatured hexagonal or cubic phase. HREM and N2 isotherms of MCM-48 materials indicates well-ordered three-dimensional meso-channels.

AB - The cubic mesoporous silica MCM-48 materials have been synthesized by temperature control, and the properties of samples were investigated by using XRD, HREM and N2 adsorption-desorption techniques. XRD results show that the mesophases synthesized at low temperature (≤75 °C) have a poorly ordered hexagonal structure, while hydrothermal treatment at higher temperature (≥95 °C) led to cubic MCM-48 mesophases. The effect of temperature on different mesophases can be due to the polymerization and condensation of silicate species at different temperatures, which results in the formation of curvatured hexagonal or cubic phase. HREM and N2 isotherms of MCM-48 materials indicates well-ordered three-dimensional meso-channels.

UR - https://www.scopus.com/pages/publications/0034272463

U2 - 10.1016/S0167-577X(00)00117-8

DO - 10.1016/S0167-577X(00)00117-8

M3 - 文章

AN - SCOPUS:0034272463

SN - 0167-577X

VL - 45

SP - 273

EP - 278

JO - Materials Letters

JF - Materials Letters

IS - 5

ER -

Temperature control in the synthesis of cubic mesoporous silica materials

Abstract

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