TBADT/nickel co-catalyzed three-component radical acylarylation of alkenes with aldehydes and aryl iodides

Zilong Yan; Feifei Chen; Yong Lu; Zhaolin Fu; Weiping Zheng; Shuanhu Gao; Fan Yang; Jie Tang; Ming Liang Ma; Dong Xing

doi:10.1016/j.gresc.2025.10.002

TBADT/nickel co-catalyzed three-component radical acylarylation of alkenes with aldehydes and aryl iodides

Zilong Yan
, Feifei Chen
, Yong Lu
, Zhaolin Fu
, Weiping Zheng
, Shuanhu Gao
, Fan Yang
, Jie Tang
, Ming Liang Ma^*
, Dong Xing^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

Here we report a photo/nickel co-catalyzed three-component acylarylation of alkenes using aldehydes and aryl iodides. Tetrabutylammonium decatungstate (TBADT) serves as a hydrogen-atom-transfer (HAT) photocatalyst and works synergistically with nickel catalyst for this radical acylarylation. This method provides a versatile and modular strategy for synthesizing β -aryl ketones directly from readily available aldehydes under mild conditions.

Original language	English
Journal	Green Synthesis and Catalysis
DOIs	https://doi.org/10.1016/j.gresc.2025.10.002
State	Accepted/In press - 2025

Keywords

Acylarylation
Aldehyde
Nickel catalysis
TBADT

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10.1016/j.gresc.2025.10.002

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@article{4b98c2cf494d4762867eede96039b189,

title = "TBADT/nickel co-catalyzed three-component radical acylarylation of alkenes with aldehydes and aryl iodides",

abstract = "Here we report a photo/nickel co-catalyzed three-component acylarylation of alkenes using aldehydes and aryl iodides. Tetrabutylammonium decatungstate (TBADT) serves as a hydrogen-atom-transfer (HAT) photocatalyst and works synergistically with nickel catalyst for this radical acylarylation. This method provides a versatile and modular strategy for synthesizing β -aryl ketones directly from readily available aldehydes under mild conditions.",

keywords = "Acylarylation, Aldehyde, Nickel catalysis, TBADT",

author = "Zilong Yan and Feifei Chen and Yong Lu and Zhaolin Fu and Weiping Zheng and Shuanhu Gao and Fan Yang and Jie Tang and Ma, \{Ming Liang\} and Dong Xing",

note = "Publisher Copyright: {\textcopyright} 2025 Fudan University.",

year = "2025",

doi = "10.1016/j.gresc.2025.10.002",

language = "英语",

journal = "Green Synthesis and Catalysis",

issn = "2666-5549",

publisher = "KeAi Communications Co.",

}

TY - JOUR

T1 - TBADT/nickel co-catalyzed three-component radical acylarylation of alkenes with aldehydes and aryl iodides

AU - Yan, Zilong

AU - Chen, Feifei

AU - Lu, Yong

AU - Fu, Zhaolin

AU - Zheng, Weiping

AU - Gao, Shuanhu

AU - Yang, Fan

AU - Tang, Jie

AU - Ma, Ming Liang

AU - Xing, Dong

PY - 2025

Y1 - 2025

N2 - Here we report a photo/nickel co-catalyzed three-component acylarylation of alkenes using aldehydes and aryl iodides. Tetrabutylammonium decatungstate (TBADT) serves as a hydrogen-atom-transfer (HAT) photocatalyst and works synergistically with nickel catalyst for this radical acylarylation. This method provides a versatile and modular strategy for synthesizing β -aryl ketones directly from readily available aldehydes under mild conditions.

AB - Here we report a photo/nickel co-catalyzed three-component acylarylation of alkenes using aldehydes and aryl iodides. Tetrabutylammonium decatungstate (TBADT) serves as a hydrogen-atom-transfer (HAT) photocatalyst and works synergistically with nickel catalyst for this radical acylarylation. This method provides a versatile and modular strategy for synthesizing β -aryl ketones directly from readily available aldehydes under mild conditions.

KW - Acylarylation

KW - Aldehyde

KW - Nickel catalysis

KW - TBADT

UR - https://www.scopus.com/pages/publications/105024973708

U2 - 10.1016/j.gresc.2025.10.002

DO - 10.1016/j.gresc.2025.10.002

M3 - 文章

AN - SCOPUS:105024973708

SN - 2666-5549

JO - Green Synthesis and Catalysis

JF - Green Synthesis and Catalysis

ER -

TBADT/nickel co-catalyzed three-component radical acylarylation of alkenes with aldehydes and aryl iodides

Abstract

Keywords

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