Synthetic studies on daphniglaucins

Yuanyou Qiu; Jiaxin Zhong; Shan Du; Shuanhu Gao

doi:10.1039/c8cc03063d

Synthetic studies on daphniglaucins

Yuanyou Qiu, Jiaxin Zhong, Shan Du, Shuanhu Gao

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

The synthetic approach to the core framework of daphniglaucin-type Daphniphyllum alkaloids is described herein. The B-C ring was constructed via a Rh-catalyzed [3+2] cycloaddition. Continuous quaternary centers were installed through [3+2] cycloaddition and alkylation. The attempt to build the A-D ring motif using dipolar cycloaddition of azomethine ylides was extensively investigated.

Original language	English
Pages (from-to)	5554-5557
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	44
DOIs	https://doi.org/10.1039/c8cc03063d
State	Published - 2018

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10.1039/c8cc03063d

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title = "Synthetic studies on daphniglaucins",

abstract = "The synthetic approach to the core framework of daphniglaucin-type Daphniphyllum alkaloids is described herein. The B-C ring was constructed via a Rh-catalyzed [3+2] cycloaddition. Continuous quaternary centers were installed through [3+2] cycloaddition and alkylation. The attempt to build the A-D ring motif using dipolar cycloaddition of azomethine ylides was extensively investigated.",

author = "Yuanyou Qiu and Jiaxin Zhong and Shan Du and Shuanhu Gao",

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year = "2018",

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AU - Qiu, Yuanyou

AU - Zhong, Jiaxin

AU - Du, Shan

AU - Gao, Shuanhu

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N2 - The synthetic approach to the core framework of daphniglaucin-type Daphniphyllum alkaloids is described herein. The B-C ring was constructed via a Rh-catalyzed [3+2] cycloaddition. Continuous quaternary centers were installed through [3+2] cycloaddition and alkylation. The attempt to build the A-D ring motif using dipolar cycloaddition of azomethine ylides was extensively investigated.

AB - The synthetic approach to the core framework of daphniglaucin-type Daphniphyllum alkaloids is described herein. The B-C ring was constructed via a Rh-catalyzed [3+2] cycloaddition. Continuous quaternary centers were installed through [3+2] cycloaddition and alkylation. The attempt to build the A-D ring motif using dipolar cycloaddition of azomethine ylides was extensively investigated.

UR - https://www.scopus.com/pages/publications/85047769622

U2 - 10.1039/c8cc03063d

DO - 10.1039/c8cc03063d

M3 - 文章

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AN - SCOPUS:85047769622

SN - 1359-7345

VL - 54

SP - 5554

EP - 5557

JO - Chemical Communications

JF - Chemical Communications

IS - 44

ER -

Synthetic studies on daphniglaucins

Abstract

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