Synthesis, Structure and Properties of Formamidine-templated Metal Formate Crystals

Chunhua Luo; Minjie Fang; Qianqian Luo; Hechun Lin; Yuanyuan Zhang; Fangyu Yue; Pinghua Xiang; Hui Peng

doi:10.1002/crat.201700195

Synthesis, Structure and Properties of Formamidine-templated Metal Formate Crystals

Chunhua Luo
, Minjie Fang
, Qianqian Luo
, Hechun Lin^*
, Yuanyuan Zhang
, Fangyu Yue
, Pinghua Xiang
, Hui Peng

^*Corresponding author for this work

School of Physics and Electronic Science

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

This work reports the preparation of crystals of two metal organic frameworks [(NH₂CHNH₂)][Zn(HCOO)₃] (1) and [(NH₂CHNH₂)₂][Cu₂(HCOO)₆] (2) by using the solvent evaporation method. Under the same experimental conditions, the obtained crystals show different crystal structures. The complex 1 forms 3D structure geometry with one Zn(Ⅱ) ion in the center of an octahedral coordination environment, which is bridged with six nearest Zn(Ⅱ) ions by the formate ligands. The 3D scaffold of the complex 2 consists of two copper ions (Cu1 and Cu2) in the center of an octahedral coordination environment bridged by formate ligands. Magnetic study shows diamagnetic susceptibility for [NH₂CHNH₂][Zn(HCOO)₃] and antiferromagnetic coupling between the Cu(Ⅱ) ions for [(NH₂CHNH₂)₂][Cu₂(HCOO)₆].

Original language	English
Article number	1700195
Journal	Crystal Research and Technology
Volume	52
Issue number	12
DOIs	https://doi.org/10.1002/crat.201700195
State	Published - Dec 2017

Keywords

formamidine
magnetization
metal organic framework

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10.1002/crat.201700195

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@article{53868ce5eb894f6ea03cd52c08d314f7,

title = "Synthesis, Structure and Properties of Formamidine-templated Metal Formate Crystals",

abstract = "This work reports the preparation of crystals of two metal organic frameworks [(NH2CHNH2)][Zn(HCOO)3] (1) and [(NH2CHNH2)2][Cu2(HCOO)6] (2) by using the solvent evaporation method. Under the same experimental conditions, the obtained crystals show different crystal structures. The complex 1 forms 3D structure geometry with one Zn(Ⅱ) ion in the center of an octahedral coordination environment, which is bridged with six nearest Zn(Ⅱ) ions by the formate ligands. The 3D scaffold of the complex 2 consists of two copper ions (Cu1 and Cu2) in the center of an octahedral coordination environment bridged by formate ligands. Magnetic study shows diamagnetic susceptibility for [NH2CHNH2][Zn(HCOO)3] and antiferromagnetic coupling between the Cu(Ⅱ) ions for [(NH2CHNH2)2][Cu2(HCOO)6].",

keywords = "formamidine, magnetization, metal organic framework",

author = "Chunhua Luo and Minjie Fang and Qianqian Luo and Hechun Lin and Yuanyuan Zhang and Fangyu Yue and Pinghua Xiang and Hui Peng",

note = "Publisher Copyright: {\textcopyright} 2017 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2017",

month = dec,

doi = "10.1002/crat.201700195",

language = "英语",

volume = "52",

journal = "Crystal Research and Technology",

issn = "0232-1300",

publisher = "John Wiley \& Sons Inc.",

number = "12",

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TY - JOUR

T1 - Synthesis, Structure and Properties of Formamidine-templated Metal Formate Crystals

AU - Luo, Chunhua

AU - Fang, Minjie

AU - Luo, Qianqian

AU - Lin, Hechun

AU - Zhang, Yuanyuan

AU - Yue, Fangyu

AU - Xiang, Pinghua

AU - Peng, Hui

PY - 2017/12

Y1 - 2017/12

N2 - This work reports the preparation of crystals of two metal organic frameworks [(NH2CHNH2)][Zn(HCOO)3] (1) and [(NH2CHNH2)2][Cu2(HCOO)6] (2) by using the solvent evaporation method. Under the same experimental conditions, the obtained crystals show different crystal structures. The complex 1 forms 3D structure geometry with one Zn(Ⅱ) ion in the center of an octahedral coordination environment, which is bridged with six nearest Zn(Ⅱ) ions by the formate ligands. The 3D scaffold of the complex 2 consists of two copper ions (Cu1 and Cu2) in the center of an octahedral coordination environment bridged by formate ligands. Magnetic study shows diamagnetic susceptibility for [NH2CHNH2][Zn(HCOO)3] and antiferromagnetic coupling between the Cu(Ⅱ) ions for [(NH2CHNH2)2][Cu2(HCOO)6].

AB - This work reports the preparation of crystals of two metal organic frameworks [(NH2CHNH2)][Zn(HCOO)3] (1) and [(NH2CHNH2)2][Cu2(HCOO)6] (2) by using the solvent evaporation method. Under the same experimental conditions, the obtained crystals show different crystal structures. The complex 1 forms 3D structure geometry with one Zn(Ⅱ) ion in the center of an octahedral coordination environment, which is bridged with six nearest Zn(Ⅱ) ions by the formate ligands. The 3D scaffold of the complex 2 consists of two copper ions (Cu1 and Cu2) in the center of an octahedral coordination environment bridged by formate ligands. Magnetic study shows diamagnetic susceptibility for [NH2CHNH2][Zn(HCOO)3] and antiferromagnetic coupling between the Cu(Ⅱ) ions for [(NH2CHNH2)2][Cu2(HCOO)6].

KW - formamidine

KW - magnetization

KW - metal organic framework

UR - https://www.scopus.com/pages/publications/85033452233

U2 - 10.1002/crat.201700195

DO - 10.1002/crat.201700195

M3 - 文章

AN - SCOPUS:85033452233

SN - 0232-1300

VL - 52

JO - Crystal Research and Technology

JF - Crystal Research and Technology

IS - 12

M1 - 1700195

ER -

Synthesis, Structure and Properties of Formamidine-templated Metal Formate Crystals

Abstract

Keywords

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