Synthesis, structure and properties of copper(II) and manganese(II) coordination polymers with l,5-dinitronaphthalene-3,7-dicarboxylate

Hua Tian; Qing Xiang Jia; Jian Yong Zhang; En Qing Gao

doi:10.1016/j.ica.2010.04.011

Synthesis, structure and properties of copper(II) and manganese(II) coordination polymers with l,5-dinitronaphthalene-3,7-dicarboxylate

Hua Tian
, Qing Xiang Jia
, Jian Yong Zhang
, En Qing Gao^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Two new metal-organic coordination polymers with l,5-dinitronaphthalene-3, 7-dicarboxylate (NNDC), [Cu₂(NNDC)₂(DMF), _1.8(DMSO)_2.2(H₂O)₂]-H₂O (1) and [Mn₃(NNDC)₃(DMSO)₄]DMSO (2) have been synthesized under solvothermal conditions and characterized by single crystal X-ray diffraction and Thermogravimetric Analysis (TGA). The structure of compound 1 consists of one-dimensional chains with copper ions being linked by the dicarboxylate ligands. The coordination chains are associated into ladder-like double chains through O-H&O hydrogen bonds and Tt-Jt interactions, and the ladders are packed in a cross fashion through further n-n interactions to give the three-dimensional structure. The Mn(II) compound exhibits a 3D framework with the peu topology, in which [Mn₃(COO) _e] clusters as octahedral secondary building blocks are linked by the naphthalene spacers. Magnetic analyses were carried out based on both temperature- and field-dependent data, consistently suggesting relatively weak antiferromagnetic interactions within the carboxylate bridged [Mn ₃(COO)₆] cluster.

Original language	English
Pages (from-to)	2481-2487
Number of pages	7
Journal	Inorganica Chimica Acta
Volume	363
Issue number	11
DOIs	https://doi.org/10.1016/j.ica.2010.04.011
State	Published - 10 Aug 2010

Keywords

Coordination polymers
Copper(II)
Magnetic properties
Manganese(II)
Structures

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10.1016/j.ica.2010.04.011

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@article{8447591075204963b17372c3ba04bca7,

title = "Synthesis, structure and properties of copper(II) and manganese(II) coordination polymers with l,5-dinitronaphthalene-3,7-dicarboxylate",

abstract = "Two new metal-organic coordination polymers with l,5-dinitronaphthalene-3, 7-dicarboxylate (NNDC), [Cu2(NNDC)2(DMF), 1.8(DMSO)2.2(H2O)2]-H2O (1) and [Mn3(NNDC)3(DMSO)4]DMSO (2) have been synthesized under solvothermal conditions and characterized by single crystal X-ray diffraction and Thermogravimetric Analysis (TGA). The structure of compound 1 consists of one-dimensional chains with copper ions being linked by the dicarboxylate ligands. The coordination chains are associated into ladder-like double chains through O-H\&O hydrogen bonds and Tt-Jt interactions, and the ladders are packed in a cross fashion through further n-n interactions to give the three-dimensional structure. The Mn(II) compound exhibits a 3D framework with the peu topology, in which [Mn3(COO) e] clusters as octahedral secondary building blocks are linked by the naphthalene spacers. Magnetic analyses were carried out based on both temperature- and field-dependent data, consistently suggesting relatively weak antiferromagnetic interactions within the carboxylate bridged [Mn 3(COO)6] cluster.",

keywords = "Coordination polymers, Copper(II), Magnetic properties, Manganese(II), Structures",

author = "Hua Tian and Jia, \{Qing Xiang\} and Zhang, \{Jian Yong\} and Gao, \{En Qing\}",

year = "2010",

month = aug,

day = "10",

doi = "10.1016/j.ica.2010.04.011",

language = "英语",

volume = "363",

pages = "2481--2487",

journal = "Inorganica Chimica Acta",

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TY - JOUR

T1 - Synthesis, structure and properties of copper(II) and manganese(II) coordination polymers with l,5-dinitronaphthalene-3,7-dicarboxylate

AU - Tian, Hua

AU - Jia, Qing Xiang

AU - Zhang, Jian Yong

AU - Gao, En Qing

PY - 2010/8/10

Y1 - 2010/8/10

N2 - Two new metal-organic coordination polymers with l,5-dinitronaphthalene-3, 7-dicarboxylate (NNDC), [Cu2(NNDC)2(DMF), 1.8(DMSO)2.2(H2O)2]-H2O (1) and [Mn3(NNDC)3(DMSO)4]DMSO (2) have been synthesized under solvothermal conditions and characterized by single crystal X-ray diffraction and Thermogravimetric Analysis (TGA). The structure of compound 1 consists of one-dimensional chains with copper ions being linked by the dicarboxylate ligands. The coordination chains are associated into ladder-like double chains through O-H&O hydrogen bonds and Tt-Jt interactions, and the ladders are packed in a cross fashion through further n-n interactions to give the three-dimensional structure. The Mn(II) compound exhibits a 3D framework with the peu topology, in which [Mn3(COO) e] clusters as octahedral secondary building blocks are linked by the naphthalene spacers. Magnetic analyses were carried out based on both temperature- and field-dependent data, consistently suggesting relatively weak antiferromagnetic interactions within the carboxylate bridged [Mn 3(COO)6] cluster.

AB - Two new metal-organic coordination polymers with l,5-dinitronaphthalene-3, 7-dicarboxylate (NNDC), [Cu2(NNDC)2(DMF), 1.8(DMSO)2.2(H2O)2]-H2O (1) and [Mn3(NNDC)3(DMSO)4]DMSO (2) have been synthesized under solvothermal conditions and characterized by single crystal X-ray diffraction and Thermogravimetric Analysis (TGA). The structure of compound 1 consists of one-dimensional chains with copper ions being linked by the dicarboxylate ligands. The coordination chains are associated into ladder-like double chains through O-H&O hydrogen bonds and Tt-Jt interactions, and the ladders are packed in a cross fashion through further n-n interactions to give the three-dimensional structure. The Mn(II) compound exhibits a 3D framework with the peu topology, in which [Mn3(COO) e] clusters as octahedral secondary building blocks are linked by the naphthalene spacers. Magnetic analyses were carried out based on both temperature- and field-dependent data, consistently suggesting relatively weak antiferromagnetic interactions within the carboxylate bridged [Mn 3(COO)6] cluster.

KW - Coordination polymers

KW - Copper(II)

KW - Magnetic properties

KW - Manganese(II)

KW - Structures

UR - https://www.scopus.com/pages/publications/77957242002

U2 - 10.1016/j.ica.2010.04.011

DO - 10.1016/j.ica.2010.04.011

M3 - 文章

AN - SCOPUS:77957242002

SN - 0020-1693

VL - 363

SP - 2481

EP - 2487

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 11

ER -

Synthesis, structure and properties of copper(II) and manganese(II) coordination polymers with l,5-dinitronaphthalene-3,7-dicarboxylate

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