Synthesis of two titanosilicates with distinct interlayer connections from similar gels

Peng Ji; Kun Lu; Xinqing Lu; Hao Xu; Peng Wu

doi:10.1039/c7dt00640c

Synthesis of two titanosilicates with distinct interlayer connections from similar gels

Peng Ji, Kun Lu, Xinqing Lu, Hao Xu, Peng Wu

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Ti-SSZ-70 and Ti-ECNU-6, with identical intralayer structures but distinct interlayer connections, were prepared from similar synthetic gels free of alkali metal ions and boric acid. Ti-SSZ-70, composed of vertically misaligned MWW layers, was transferred to Ti-ECNU-6, structurally analogous to the Ti-MWW zeolite with a well-aligned layer stacking, upon the addition of an appropriate amount of hexamethyleneimine to the gel. These two titanosilicate catalysts exhibited outstanding catalytic activities in the liquid-phase alkene epoxidation.

Original language	English
Pages (from-to)	5776-5780
Number of pages	5
Journal	Dalton Transactions
Volume	46
Issue number	18
DOIs	https://doi.org/10.1039/c7dt00640c
State	Published - 2017

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title = "Synthesis of two titanosilicates with distinct interlayer connections from similar gels",

abstract = "Ti-SSZ-70 and Ti-ECNU-6, with identical intralayer structures but distinct interlayer connections, were prepared from similar synthetic gels free of alkali metal ions and boric acid. Ti-SSZ-70, composed of vertically misaligned MWW layers, was transferred to Ti-ECNU-6, structurally analogous to the Ti-MWW zeolite with a well-aligned layer stacking, upon the addition of an appropriate amount of hexamethyleneimine to the gel. These two titanosilicate catalysts exhibited outstanding catalytic activities in the liquid-phase alkene epoxidation.",

author = "Peng Ji and Kun Lu and Xinqing Lu and Hao Xu and Peng Wu",

note = "Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/c7dt00640c",

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volume = "46",

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journal = "Dalton Transactions",

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T1 - Synthesis of two titanosilicates with distinct interlayer connections from similar gels

AU - Ji, Peng

AU - Lu, Kun

AU - Lu, Xinqing

AU - Xu, Hao

AU - Wu, Peng

PY - 2017

Y1 - 2017

N2 - Ti-SSZ-70 and Ti-ECNU-6, with identical intralayer structures but distinct interlayer connections, were prepared from similar synthetic gels free of alkali metal ions and boric acid. Ti-SSZ-70, composed of vertically misaligned MWW layers, was transferred to Ti-ECNU-6, structurally analogous to the Ti-MWW zeolite with a well-aligned layer stacking, upon the addition of an appropriate amount of hexamethyleneimine to the gel. These two titanosilicate catalysts exhibited outstanding catalytic activities in the liquid-phase alkene epoxidation.

AB - Ti-SSZ-70 and Ti-ECNU-6, with identical intralayer structures but distinct interlayer connections, were prepared from similar synthetic gels free of alkali metal ions and boric acid. Ti-SSZ-70, composed of vertically misaligned MWW layers, was transferred to Ti-ECNU-6, structurally analogous to the Ti-MWW zeolite with a well-aligned layer stacking, upon the addition of an appropriate amount of hexamethyleneimine to the gel. These two titanosilicate catalysts exhibited outstanding catalytic activities in the liquid-phase alkene epoxidation.

UR - https://www.scopus.com/pages/publications/85021721181

U2 - 10.1039/c7dt00640c

DO - 10.1039/c7dt00640c

M3 - 文章

C2 - 28401221

AN - SCOPUS:85021721181

SN - 1477-9226

VL - 46

SP - 5776

EP - 5780

JO - Dalton Transactions

JF - Dalton Transactions

IS - 18

ER -

Synthesis of two titanosilicates with distinct interlayer connections from similar gels

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