Synthesis of triangular metallodendrimers via coordination-driven self-assembly

Qing Han; Li Lei Wang; Quan Jie Li; Guang Zhen Zhao; Jiuming He; Bingjie Hu; Hongwei Tan; Zeper Abliz; Yihua Yu; Hai Bo Yang

doi:10.1021/jo300016a

Synthesis of triangular metallodendrimers via coordination-driven self-assembly

Qing Han
, Li Lei Wang
, Quan Jie Li
, Guang Zhen Zhao
, Jiuming He
, Bingjie Hu
, Hongwei Tan
, Zeper Abliz
, Yihua Yu
, Hai Bo Yang^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

A new family of 60° dendritic di-Pt(II) acceptor tectons have been successfully designed and synthesized, from which a series of novel "three-component" triangular metallodendrimers were prepared via [3 + 3] coordination-driven self-assembly. The structures of newly designed triangular metallodendrimers are characterized by multinuclear NMR ( ¹H and ³¹P), ¹H DOSY NMR, mass spectrometry (CSI-TOF-MS), and elemental analysis. The shape and size of all supramolecular dendritic triangles were investigated with PM6 semiempirical molecular orbital methods.

Original language	English
Pages (from-to)	3426-3432
Number of pages	7
Journal	Journal of Organic Chemistry
Volume	77
Issue number	7
DOIs	https://doi.org/10.1021/jo300016a
State	Published - 6 Apr 2012

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title = "Synthesis of triangular metallodendrimers via coordination-driven self-assembly",

abstract = "A new family of 60° dendritic di-Pt(II) acceptor tectons have been successfully designed and synthesized, from which a series of novel {"}three-component{"} triangular metallodendrimers were prepared via [3 + 3] coordination-driven self-assembly. The structures of newly designed triangular metallodendrimers are characterized by multinuclear NMR ( 1H and 31P), 1H DOSY NMR, mass spectrometry (CSI-TOF-MS), and elemental analysis. The shape and size of all supramolecular dendritic triangles were investigated with PM6 semiempirical molecular orbital methods.",

author = "Qing Han and Wang, \{Li Lei\} and Li, \{Quan Jie\} and Zhao, \{Guang Zhen\} and Jiuming He and Bingjie Hu and Hongwei Tan and Zeper Abliz and Yihua Yu and Yang, \{Hai Bo\}",

year = "2012",

month = apr,

day = "6",

doi = "10.1021/jo300016a",

language = "英语",

volume = "77",

pages = "3426--3432",

journal = "Journal of Organic Chemistry",

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TY - JOUR

T1 - Synthesis of triangular metallodendrimers via coordination-driven self-assembly

AU - Han, Qing

AU - Wang, Li Lei

AU - Li, Quan Jie

AU - Zhao, Guang Zhen

AU - He, Jiuming

AU - Hu, Bingjie

AU - Tan, Hongwei

AU - Abliz, Zeper

AU - Yu, Yihua

AU - Yang, Hai Bo

PY - 2012/4/6

Y1 - 2012/4/6

N2 - A new family of 60° dendritic di-Pt(II) acceptor tectons have been successfully designed and synthesized, from which a series of novel "three-component" triangular metallodendrimers were prepared via [3 + 3] coordination-driven self-assembly. The structures of newly designed triangular metallodendrimers are characterized by multinuclear NMR ( 1H and 31P), 1H DOSY NMR, mass spectrometry (CSI-TOF-MS), and elemental analysis. The shape and size of all supramolecular dendritic triangles were investigated with PM6 semiempirical molecular orbital methods.

AB - A new family of 60° dendritic di-Pt(II) acceptor tectons have been successfully designed and synthesized, from which a series of novel "three-component" triangular metallodendrimers were prepared via [3 + 3] coordination-driven self-assembly. The structures of newly designed triangular metallodendrimers are characterized by multinuclear NMR ( 1H and 31P), 1H DOSY NMR, mass spectrometry (CSI-TOF-MS), and elemental analysis. The shape and size of all supramolecular dendritic triangles were investigated with PM6 semiempirical molecular orbital methods.

UR - https://www.scopus.com/pages/publications/84859604721

U2 - 10.1021/jo300016a

DO - 10.1021/jo300016a

M3 - 文章

C2 - 22428775

AN - SCOPUS:84859604721

SN - 0022-3263

VL - 77

SP - 3426

EP - 3432

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 7

ER -

Synthesis of triangular metallodendrimers via coordination-driven self-assembly

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