Synthesis of six-component metallodendrimers via [3 + 3] coordination-driven self-assembly

Hai Bo Yang; Brian H. Northrop; Yao Rong Zheng; Koushik Ghosh; Matthew M. Lyndon; David C. Muddiman; Peter J. Stang

doi:10.1021/jo900067v

Synthesis of six-component metallodendrimers via [3 + 3] coordination-driven self-assembly

Hai Bo Yang, Brian H. Northrop, Yao Rong Zheng, Koushik Ghosh, Matthew M. Lyndon, David C. Muddiman, Peter J. Stang

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

A new class of 120° dendritic di-Pt(II) acceptor subunits has been designed and synthesized, from which six-component hexagonal metallodendrimers were easily formed with 120° dendritic dipyridine donors via [3 + 3] coordination-driven self-assembly. The structures of all metallodendrimers are confirmed by multinuclear NMR, ESI-TOF-MS/ESI-FTMS, and elemental analysis. MMFF force-field simulations indicates that all metallodendrimers have a hexagonal ring with an internal radius of approximately 1.4 nm.

Original language	English
Pages (from-to)	3524-3527
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	74
Issue number	9
DOIs	https://doi.org/10.1021/jo900067v
State	Published - 1 May 2009

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@article{1bd1738ead5e496d98ab0399089a04ea,

title = "Synthesis of six-component metallodendrimers via [3 + 3] coordination-driven self-assembly",

abstract = "A new class of 120° dendritic di-Pt(II) acceptor subunits has been designed and synthesized, from which six-component hexagonal metallodendrimers were easily formed with 120° dendritic dipyridine donors via [3 + 3] coordination-driven self-assembly. The structures of all metallodendrimers are confirmed by multinuclear NMR, ESI-TOF-MS/ESI-FTMS, and elemental analysis. MMFF force-field simulations indicates that all metallodendrimers have a hexagonal ring with an internal radius of approximately 1.4 nm.",

author = "Yang, \{Hai Bo\} and Northrop, \{Brian H.\} and Zheng, \{Yao Rong\} and Koushik Ghosh and Lyndon, \{Matthew M.\} and Muddiman, \{David C.\} and Stang, \{Peter J.\}",

year = "2009",

month = may,

day = "1",

doi = "10.1021/jo900067v",

language = "英语",

volume = "74",

pages = "3524--3527",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Synthesis of six-component metallodendrimers via [3 + 3] coordination-driven self-assembly

AU - Yang, Hai Bo

AU - Northrop, Brian H.

AU - Zheng, Yao Rong

AU - Ghosh, Koushik

AU - Lyndon, Matthew M.

AU - Muddiman, David C.

AU - Stang, Peter J.

PY - 2009/5/1

Y1 - 2009/5/1

N2 - A new class of 120° dendritic di-Pt(II) acceptor subunits has been designed and synthesized, from which six-component hexagonal metallodendrimers were easily formed with 120° dendritic dipyridine donors via [3 + 3] coordination-driven self-assembly. The structures of all metallodendrimers are confirmed by multinuclear NMR, ESI-TOF-MS/ESI-FTMS, and elemental analysis. MMFF force-field simulations indicates that all metallodendrimers have a hexagonal ring with an internal radius of approximately 1.4 nm.

AB - A new class of 120° dendritic di-Pt(II) acceptor subunits has been designed and synthesized, from which six-component hexagonal metallodendrimers were easily formed with 120° dendritic dipyridine donors via [3 + 3] coordination-driven self-assembly. The structures of all metallodendrimers are confirmed by multinuclear NMR, ESI-TOF-MS/ESI-FTMS, and elemental analysis. MMFF force-field simulations indicates that all metallodendrimers have a hexagonal ring with an internal radius of approximately 1.4 nm.

UR - https://www.scopus.com/pages/publications/66449108585

U2 - 10.1021/jo900067v

DO - 10.1021/jo900067v

M3 - 文章

C2 - 19344131

AN - SCOPUS:66449108585

SN - 0022-3263

VL - 74

SP - 3524

EP - 3527

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 9

ER -

Synthesis of six-component metallodendrimers via [3 + 3] coordination-driven self-assembly

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