Synthesis of platinum acetylide derivatives with different shapes and their gel formation behavior

Li Jun Chen; Jing Zhang; Jiuming He; Xing Dong Xu; Nai Wei Wu; De Xian Wang; Zeper Abliz; Hai Bo Yang

doi:10.1021/om2003317

Synthesis of platinum acetylide derivatives with different shapes and their gel formation behavior

Li Jun Chen, Jing Zhang, Jiuming He, Xing Dong Xu, Nai Wei Wu, De Xian Wang, Zeper Abliz, Hai Bo Yang

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

50 Scopus citations

Abstract

The synthesis of a series of platinum acetylide derivatives, featuring linear, triangular, and rectangular shapes, respectively, is described. The structures of these complexes were characterized by multinuclear NMR ( ₁H, ₁₃C, and ₃₁P), CSI-TOF mass spectrometry, and elemental analysis. It was found that these complexes exhibited unexpectedly different gel formation properties in the most common organic solvents. Moreover, the organometallic gels of C1 and C2 exhibited concentration-and temperature-dependent emission properties.

Original language	English
Pages (from-to)	5590-5594
Number of pages	5
Journal	Organometallics
Volume	30
Issue number	21
DOIs	https://doi.org/10.1021/om2003317
State	Published - 14 Nov 2011

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title = "Synthesis of platinum acetylide derivatives with different shapes and their gel formation behavior",

abstract = "The synthesis of a series of platinum acetylide derivatives, featuring linear, triangular, and rectangular shapes, respectively, is described. The structures of these complexes were characterized by multinuclear NMR ( 1H, 13C, and 31P), CSI-TOF mass spectrometry, and elemental analysis. It was found that these complexes exhibited unexpectedly different gel formation properties in the most common organic solvents. Moreover, the organometallic gels of C1 and C2 exhibited concentration-and temperature-dependent emission properties.",

author = "Chen, \{Li Jun\} and Jing Zhang and Jiuming He and Xu, \{Xing Dong\} and Wu, \{Nai Wei\} and Wang, \{De Xian\} and Zeper Abliz and Yang, \{Hai Bo\}",

year = "2011",

month = nov,

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doi = "10.1021/om2003317",

language = "英语",

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journal = "Organometallics",

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T1 - Synthesis of platinum acetylide derivatives with different shapes and their gel formation behavior

AU - Chen, Li Jun

AU - Zhang, Jing

AU - He, Jiuming

AU - Xu, Xing Dong

AU - Wu, Nai Wei

AU - Wang, De Xian

AU - Abliz, Zeper

AU - Yang, Hai Bo

PY - 2011/11/14

Y1 - 2011/11/14

N2 - The synthesis of a series of platinum acetylide derivatives, featuring linear, triangular, and rectangular shapes, respectively, is described. The structures of these complexes were characterized by multinuclear NMR ( 1H, 13C, and 31P), CSI-TOF mass spectrometry, and elemental analysis. It was found that these complexes exhibited unexpectedly different gel formation properties in the most common organic solvents. Moreover, the organometallic gels of C1 and C2 exhibited concentration-and temperature-dependent emission properties.

AB - The synthesis of a series of platinum acetylide derivatives, featuring linear, triangular, and rectangular shapes, respectively, is described. The structures of these complexes were characterized by multinuclear NMR ( 1H, 13C, and 31P), CSI-TOF mass spectrometry, and elemental analysis. It was found that these complexes exhibited unexpectedly different gel formation properties in the most common organic solvents. Moreover, the organometallic gels of C1 and C2 exhibited concentration-and temperature-dependent emission properties.

UR - https://www.scopus.com/pages/publications/80755171511

U2 - 10.1021/om2003317

DO - 10.1021/om2003317

M3 - 文章

AN - SCOPUS:80755171511

SN - 0276-7333

VL - 30

SP - 5590

EP - 5594

JO - Organometallics

JF - Organometallics

IS - 21

ER -

Synthesis of platinum acetylide derivatives with different shapes and their gel formation behavior

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