Synthesis of novel linear PEO-b-PS-b-PCL triblock copolymers by the combination of ATRP, ROP, and a click reaction

Xiaohua He; Liyuan Liang; Meiran Xie; Yiqun Zhang; Shaoliang Lin; Deyue Yan

doi:10.1002/macp.200700153

Synthesis of novel linear PEO-b-PS-b-PCL triblock copolymers by the combination of ATRP, ROP, and a click reaction

Xiaohua He, Liyuan Liang, Meiran Xie, Yiqun Zhang, Shaoliang Lin, Deyue Yan

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

50 Scopus citations

Abstract

A new strategy to synthesize a series of well-defined amphiphilic PEO-b-PS-b-PCL block copolymers is presented. First, bromine-terminated diblock copolymers PEO-b-PS-Br are prepared by ATRP of styrene, and converted into azido-terminated PEO-b-PS-N₃ diblock copolymers. Then propargyl-terminated PCL is prepared by ROP of ε-caprolactone. The PEO-b-PS-b-PCL triblock copolymers with M̄_n from 1.62 × 10⁴ to 1.96 × 10⁴ and a narrow PDI from 1.09 to 1.19 are finally synthesized from these precursors. The structures of these triblock copolymers and their precursors have been characterized by NMR, IR, and GPC analysis.

Original language	English
Pages (from-to)	1797-1802
Number of pages	6
Journal	Macromolecular Chemistry and Physics
Volume	208
Issue number	16
DOIs	https://doi.org/10.1002/macp.200700153
State	Published - 20 Aug 2007

Keywords

Atom transfer radical polymerization (ATRP)
Block copolymers
Click reaction
Ring-opening polymerization

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10.1002/macp.200700153

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title = "Synthesis of novel linear PEO-b-PS-b-PCL triblock copolymers by the combination of ATRP, ROP, and a click reaction",

abstract = "A new strategy to synthesize a series of well-defined amphiphilic PEO-b-PS-b-PCL block copolymers is presented. First, bromine-terminated diblock copolymers PEO-b-PS-Br are prepared by ATRP of styrene, and converted into azido-terminated PEO-b-PS-N3 diblock copolymers. Then propargyl-terminated PCL is prepared by ROP of ε-caprolactone. The PEO-b-PS-b-PCL triblock copolymers with {\=M}n from 1.62 × 104 to 1.96 × 104 and a narrow PDI from 1.09 to 1.19 are finally synthesized from these precursors. The structures of these triblock copolymers and their precursors have been characterized by NMR, IR, and GPC analysis.",

keywords = "Atom transfer radical polymerization (ATRP), Block copolymers, Click reaction, Ring-opening polymerization",

author = "Xiaohua He and Liyuan Liang and Meiran Xie and Yiqun Zhang and Shaoliang Lin and Deyue Yan",

year = "2007",

month = aug,

day = "20",

doi = "10.1002/macp.200700153",

language = "英语",

volume = "208",

pages = "1797--1802",

journal = "Macromolecular Chemistry and Physics",

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T1 - Synthesis of novel linear PEO-b-PS-b-PCL triblock copolymers by the combination of ATRP, ROP, and a click reaction

AU - He, Xiaohua

AU - Liang, Liyuan

AU - Xie, Meiran

AU - Zhang, Yiqun

AU - Lin, Shaoliang

AU - Yan, Deyue

PY - 2007/8/20

Y1 - 2007/8/20

N2 - A new strategy to synthesize a series of well-defined amphiphilic PEO-b-PS-b-PCL block copolymers is presented. First, bromine-terminated diblock copolymers PEO-b-PS-Br are prepared by ATRP of styrene, and converted into azido-terminated PEO-b-PS-N3 diblock copolymers. Then propargyl-terminated PCL is prepared by ROP of ε-caprolactone. The PEO-b-PS-b-PCL triblock copolymers with M̄n from 1.62 × 104 to 1.96 × 104 and a narrow PDI from 1.09 to 1.19 are finally synthesized from these precursors. The structures of these triblock copolymers and their precursors have been characterized by NMR, IR, and GPC analysis.

AB - A new strategy to synthesize a series of well-defined amphiphilic PEO-b-PS-b-PCL block copolymers is presented. First, bromine-terminated diblock copolymers PEO-b-PS-Br are prepared by ATRP of styrene, and converted into azido-terminated PEO-b-PS-N3 diblock copolymers. Then propargyl-terminated PCL is prepared by ROP of ε-caprolactone. The PEO-b-PS-b-PCL triblock copolymers with M̄n from 1.62 × 104 to 1.96 × 104 and a narrow PDI from 1.09 to 1.19 are finally synthesized from these precursors. The structures of these triblock copolymers and their precursors have been characterized by NMR, IR, and GPC analysis.

KW - Atom transfer radical polymerization (ATRP)

KW - Block copolymers

KW - Click reaction

KW - Ring-opening polymerization

UR - https://www.scopus.com/pages/publications/34548212305

U2 - 10.1002/macp.200700153

DO - 10.1002/macp.200700153

M3 - 文章

AN - SCOPUS:34548212305

SN - 1022-1352

VL - 208

SP - 1797

EP - 1802

JO - Macromolecular Chemistry and Physics

JF - Macromolecular Chemistry and Physics

IS - 16

ER -

Synthesis of novel linear PEO-b-PS-b-PCL triblock copolymers by the combination of ATRP, ROP, and a click reaction

Abstract

Keywords

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