Synthesis of Monocrystalline Nanoframes of Prussian Blue Analogues by Controlled Preferential Etching

Wei Zhang; Yanyi Zhao; Victor Malgras; Qingmin Ji; Dongmei Jiang; Ruijuan Qi; Katsuhiko Ariga; Yusuke Yamauchi; Jian Liu; Ji Sen Jiang; Ming Hu

doi:10.1002/anie.201600661

Synthesis of Monocrystalline Nanoframes of Prussian Blue Analogues by Controlled Preferential Etching

Wei Zhang, Yanyi Zhao, Victor Malgras, Qingmin Ji, Dongmei Jiang, Ruijuan Qi, Katsuhiko Ariga, Yusuke Yamauchi, Jian Liu^*, Ji Sen Jiang, Ming Hu

^*Corresponding author for this work

School of Physics and Electronic Science

Research output: Contribution to journal › Article › peer-review

212 Scopus citations

Abstract

Metal cyanide coordination compounds are recognized as promising candidates for broad applications because of their tailorable and adjustable frameworks. Developing the nanostructure of a coordination compound may be an effective way to enhance the performance of that material in application-based roles. A controllable preferential etching method is described for synthesis of monocrystalline Prussian blue analogue (PBA) nanoframes, without the use of organic additives. The PBA nanoframes show remarkable rate performance and cycling stability for sodium/lithium ion insertion/extraction.

Original language	English
Pages (from-to)	8228-8234
Number of pages	7
Journal	Angewandte Chemie - International Edition
Volume	55
Issue number	29
DOIs	https://doi.org/10.1002/anie.201600661
State	Published - 11 Jul 2016

Keywords

alkali metals
coordination compounds
hollow nanostructures
ion insertion/extraction
surface etching

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title = "Synthesis of Monocrystalline Nanoframes of Prussian Blue Analogues by Controlled Preferential Etching",

abstract = "Metal cyanide coordination compounds are recognized as promising candidates for broad applications because of their tailorable and adjustable frameworks. Developing the nanostructure of a coordination compound may be an effective way to enhance the performance of that material in application-based roles. A controllable preferential etching method is described for synthesis of monocrystalline Prussian blue analogue (PBA) nanoframes, without the use of organic additives. The PBA nanoframes show remarkable rate performance and cycling stability for sodium/lithium ion insertion/extraction.",

keywords = "alkali metals, coordination compounds, hollow nanostructures, ion insertion/extraction, surface etching",

author = "Wei Zhang and Yanyi Zhao and Victor Malgras and Qingmin Ji and Dongmei Jiang and Ruijuan Qi and Katsuhiko Ariga and Yusuke Yamauchi and Jian Liu and Jiang, \{Ji Sen\} and Ming Hu",

note = "Publisher Copyright: {\textcopyright} 2016 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim.",

year = "2016",

month = jul,

day = "11",

doi = "10.1002/anie.201600661",

language = "英语",

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journal = "Angewandte Chemie - International Edition",

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T1 - Synthesis of Monocrystalline Nanoframes of Prussian Blue Analogues by Controlled Preferential Etching

AU - Zhang, Wei

AU - Zhao, Yanyi

AU - Malgras, Victor

AU - Ji, Qingmin

AU - Jiang, Dongmei

AU - Qi, Ruijuan

AU - Ariga, Katsuhiko

AU - Yamauchi, Yusuke

AU - Liu, Jian

AU - Jiang, Ji Sen

AU - Hu, Ming

PY - 2016/7/11

Y1 - 2016/7/11

N2 - Metal cyanide coordination compounds are recognized as promising candidates for broad applications because of their tailorable and adjustable frameworks. Developing the nanostructure of a coordination compound may be an effective way to enhance the performance of that material in application-based roles. A controllable preferential etching method is described for synthesis of monocrystalline Prussian blue analogue (PBA) nanoframes, without the use of organic additives. The PBA nanoframes show remarkable rate performance and cycling stability for sodium/lithium ion insertion/extraction.

AB - Metal cyanide coordination compounds are recognized as promising candidates for broad applications because of their tailorable and adjustable frameworks. Developing the nanostructure of a coordination compound may be an effective way to enhance the performance of that material in application-based roles. A controllable preferential etching method is described for synthesis of monocrystalline Prussian blue analogue (PBA) nanoframes, without the use of organic additives. The PBA nanoframes show remarkable rate performance and cycling stability for sodium/lithium ion insertion/extraction.

KW - alkali metals

KW - coordination compounds

KW - hollow nanostructures

KW - ion insertion/extraction

KW - surface etching

UR - https://www.scopus.com/pages/publications/84976876703

U2 - 10.1002/anie.201600661

DO - 10.1002/anie.201600661

M3 - 文章

AN - SCOPUS:84976876703

SN - 1433-7851

VL - 55

SP - 8228

EP - 8234

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 29

ER -

Synthesis of Monocrystalline Nanoframes of Prussian Blue Analogues by Controlled Preferential Etching

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