Synthesis of mesoporous silica with novel structures using rigid bolaform ammonium surfactants

S. Shen; Q. Lu; F. Gao; Y. Yan; C. Yu; B. Tu; D. Zhao

doi:10.1016/s0167-2991(04)80846-2

Synthesis of mesoporous silica with novel structures using rigid bolaform ammonium surfactants

S. Shen
, Q. Lu
, F. Gao
, Y. Yan
, C. Yu
, B. Tu
, D. Zhao^*

^*Corresponding author for this work

Fudan University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Mesoporous silica with a novel structure (FDU-11) has been prepared for the first time by using a rigid bolaform tetra-head-group quaternary ammonium surfactant: [(CH₃)₃NCH₂CH₂CH ₂N(CH₃)₂CH₂(CH₂) ₁₁OC₆H₄C₆H₄O(CH ₂)₁₁CH₂N(CH₃)₂CH ₂CH₂CH₂N (CH₃)₃] ⁴⁺·4Br^- under an alkaline condition. X-ray diffraction (XRD) and transmission electron microscope (TEM) studies show that the mesoporous silica FDU-11 may have a low symmetric tetragonal mesostructure with P4/mmm space group. N₂ sorption isotherms show that calcined mesoporous silica FDU-11 has the BET surface area of 281 m²/g, pore size of 2.05 nm and the pore volume of 0.36 cm³/g. A phase transformation from FDU-11 into another unknown mesoporous silica structure by a hydrothermal treatment is observed, suggesting the intermediate nature of the FDU-11 mesophase.

Original language	English
Pages (from-to)	528-532
Number of pages	5
Journal	Studies in Surface Science and Catalysis
Volume	154 A
DOIs	https://doi.org/10.1016/s0167-2991(04)80846-2
State	Published - 2004
Externally published	Yes

Keywords

Mesoporous silica
Structure
Surfactant
Synthesis

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10.1016/s0167-2991(04)80846-2

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title = "Synthesis of mesoporous silica with novel structures using rigid bolaform ammonium surfactants",

abstract = "Mesoporous silica with a novel structure (FDU-11) has been prepared for the first time by using a rigid bolaform tetra-head-group quaternary ammonium surfactant: [(CH3)3NCH2CH2CH 2N(CH3)2CH2(CH2) 11OC6H4C6H4O(CH 2)11CH2N(CH3)2CH 2CH2CH2N (CH3)3] 4+·4Br- under an alkaline condition. X-ray diffraction (XRD) and transmission electron microscope (TEM) studies show that the mesoporous silica FDU-11 may have a low symmetric tetragonal mesostructure with P4/mmm space group. N2 sorption isotherms show that calcined mesoporous silica FDU-11 has the BET surface area of 281 m2/g, pore size of 2.05 nm and the pore volume of 0.36 cm3/g. A phase transformation from FDU-11 into another unknown mesoporous silica structure by a hydrothermal treatment is observed, suggesting the intermediate nature of the FDU-11 mesophase.",

keywords = "Mesoporous silica, Structure, Surfactant, Synthesis",

author = "S. Shen and Q. Lu and F. Gao and Y. Yan and C. Yu and B. Tu and D. Zhao",

year = "2004",

doi = "10.1016/s0167-2991(04)80846-2",

language = "英语",

volume = "154 A",

pages = "528--532",

journal = "Studies in Surface Science and Catalysis",

issn = "0167-2991",

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TY - JOUR

T1 - Synthesis of mesoporous silica with novel structures using rigid bolaform ammonium surfactants

AU - Shen, S.

AU - Lu, Q.

AU - Gao, F.

AU - Yan, Y.

AU - Yu, C.

AU - Tu, B.

AU - Zhao, D.

PY - 2004

Y1 - 2004

N2 - Mesoporous silica with a novel structure (FDU-11) has been prepared for the first time by using a rigid bolaform tetra-head-group quaternary ammonium surfactant: [(CH3)3NCH2CH2CH 2N(CH3)2CH2(CH2) 11OC6H4C6H4O(CH 2)11CH2N(CH3)2CH 2CH2CH2N (CH3)3] 4+·4Br- under an alkaline condition. X-ray diffraction (XRD) and transmission electron microscope (TEM) studies show that the mesoporous silica FDU-11 may have a low symmetric tetragonal mesostructure with P4/mmm space group. N2 sorption isotherms show that calcined mesoporous silica FDU-11 has the BET surface area of 281 m2/g, pore size of 2.05 nm and the pore volume of 0.36 cm3/g. A phase transformation from FDU-11 into another unknown mesoporous silica structure by a hydrothermal treatment is observed, suggesting the intermediate nature of the FDU-11 mesophase.

AB - Mesoporous silica with a novel structure (FDU-11) has been prepared for the first time by using a rigid bolaform tetra-head-group quaternary ammonium surfactant: [(CH3)3NCH2CH2CH 2N(CH3)2CH2(CH2) 11OC6H4C6H4O(CH 2)11CH2N(CH3)2CH 2CH2CH2N (CH3)3] 4+·4Br- under an alkaline condition. X-ray diffraction (XRD) and transmission electron microscope (TEM) studies show that the mesoporous silica FDU-11 may have a low symmetric tetragonal mesostructure with P4/mmm space group. N2 sorption isotherms show that calcined mesoporous silica FDU-11 has the BET surface area of 281 m2/g, pore size of 2.05 nm and the pore volume of 0.36 cm3/g. A phase transformation from FDU-11 into another unknown mesoporous silica structure by a hydrothermal treatment is observed, suggesting the intermediate nature of the FDU-11 mesophase.

KW - Mesoporous silica

KW - Structure

KW - Surfactant

KW - Synthesis

UR - https://www.scopus.com/pages/publications/11844295980

U2 - 10.1016/s0167-2991(04)80846-2

DO - 10.1016/s0167-2991(04)80846-2

M3 - 文章

AN - SCOPUS:11844295980

SN - 0167-2991

VL - 154 A

SP - 528

EP - 532

JO - Studies in Surface Science and Catalysis

JF - Studies in Surface Science and Catalysis

ER -

Synthesis of mesoporous silica with novel structures using rigid bolaform ammonium surfactants

Abstract

Keywords

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