Synthesis of Dual Red-Emitting Fluorescent Silver Nanoclusters in Aqueous Lipoic Acid-Based Polymer Solutions and Application for Cu2+ Detection and Cell Imaging

Tao Yang; Yangchun Xie; Sanjun Zhang; Xiaohua He

doi:10.1002/slct.202200185

Synthesis of Dual Red-Emitting Fluorescent Silver Nanoclusters in Aqueous Lipoic Acid-Based Polymer Solutions and Application for Cu²⁺ Detection and Cell Imaging

Tao Yang
, Yangchun Xie
, Sanjun Zhang^*
, Xiaohua He^*

^*Corresponding author for this work

East China Normal University

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Dual red-emitting fluorescent and water-soluble silver nanoclusters (AgNCs) were synthesized in aqueous solutions through the reduce reaction method using lipoic acid-modified-poly(vinyl alcohol) as a novel protective ligand and sodium borohydride as a reducing agent. The obtained AgNCs exhibited a large Stokes shift and high stability. The fluorescence lifetime of the obtained AgNCs was 1.4×10⁴ ns and the corresponding quantum yield reached 7.1 %. The obtained AgNCs showed highly sensitive and selective detection of Cu²⁺, in which the evaluation of Cu²⁺ was allowed in the range of 0–28 μM with a limit of detection (LOD) as low as 0.71 μM. Moreover, the obtained AgNCs are explored to application for bioimaging through incubation with ID8 cells.

Original language	English
Article number	e202200185
Journal	ChemistrySelect
Volume	7
Issue number	12
DOIs	https://doi.org/10.1002/slct.202200185
State	Published - 29 Mar 2022

Keywords

Analytical methods
Cell imaging
Fluorescence
Poly(vinyl alcohol)
Silver nanoclusters

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10.1002/slct.202200185

Cite this

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title = "Synthesis of Dual Red-Emitting Fluorescent Silver Nanoclusters in Aqueous Lipoic Acid-Based Polymer Solutions and Application for Cu2+ Detection and Cell Imaging",

abstract = "Dual red-emitting fluorescent and water-soluble silver nanoclusters (AgNCs) were synthesized in aqueous solutions through the reduce reaction method using lipoic acid-modified-poly(vinyl alcohol) as a novel protective ligand and sodium borohydride as a reducing agent. The obtained AgNCs exhibited a large Stokes shift and high stability. The fluorescence lifetime of the obtained AgNCs was 1.4×104 ns and the corresponding quantum yield reached 7.1 \%. The obtained AgNCs showed highly sensitive and selective detection of Cu2+, in which the evaluation of Cu2+ was allowed in the range of 0–28 μM with a limit of detection (LOD) as low as 0.71 μM. Moreover, the obtained AgNCs are explored to application for bioimaging through incubation with ID8 cells.",

keywords = "Analytical methods, Cell imaging, Fluorescence, Poly(vinyl alcohol), Silver nanoclusters",

author = "Tao Yang and Yangchun Xie and Sanjun Zhang and Xiaohua He",

note = "Publisher Copyright: {\textcopyright} 2022 Wiley-VCH GmbH.",

year = "2022",

month = mar,

day = "29",

doi = "10.1002/slct.202200185",

language = "英语",

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TY - JOUR

T1 - Synthesis of Dual Red-Emitting Fluorescent Silver Nanoclusters in Aqueous Lipoic Acid-Based Polymer Solutions and Application for Cu2+ Detection and Cell Imaging

AU - Yang, Tao

AU - Xie, Yangchun

AU - Zhang, Sanjun

AU - He, Xiaohua

PY - 2022/3/29

Y1 - 2022/3/29

N2 - Dual red-emitting fluorescent and water-soluble silver nanoclusters (AgNCs) were synthesized in aqueous solutions through the reduce reaction method using lipoic acid-modified-poly(vinyl alcohol) as a novel protective ligand and sodium borohydride as a reducing agent. The obtained AgNCs exhibited a large Stokes shift and high stability. The fluorescence lifetime of the obtained AgNCs was 1.4×104 ns and the corresponding quantum yield reached 7.1 %. The obtained AgNCs showed highly sensitive and selective detection of Cu2+, in which the evaluation of Cu2+ was allowed in the range of 0–28 μM with a limit of detection (LOD) as low as 0.71 μM. Moreover, the obtained AgNCs are explored to application for bioimaging through incubation with ID8 cells.

AB - Dual red-emitting fluorescent and water-soluble silver nanoclusters (AgNCs) were synthesized in aqueous solutions through the reduce reaction method using lipoic acid-modified-poly(vinyl alcohol) as a novel protective ligand and sodium borohydride as a reducing agent. The obtained AgNCs exhibited a large Stokes shift and high stability. The fluorescence lifetime of the obtained AgNCs was 1.4×104 ns and the corresponding quantum yield reached 7.1 %. The obtained AgNCs showed highly sensitive and selective detection of Cu2+, in which the evaluation of Cu2+ was allowed in the range of 0–28 μM with a limit of detection (LOD) as low as 0.71 μM. Moreover, the obtained AgNCs are explored to application for bioimaging through incubation with ID8 cells.

KW - Analytical methods

KW - Cell imaging

KW - Fluorescence

KW - Poly(vinyl alcohol)

KW - Silver nanoclusters

UR - https://www.scopus.com/pages/publications/85127366172

U2 - 10.1002/slct.202200185

DO - 10.1002/slct.202200185

M3 - 文章

AN - SCOPUS:85127366172

SN - 2365-6549

VL - 7

JO - ChemistrySelect

JF - ChemistrySelect

IS - 12

M1 - e202200185

ER -

Synthesis of Dual Red-Emitting Fluorescent Silver Nanoclusters in Aqueous Lipoic Acid-Based Polymer Solutions and Application for Cu²⁺ Detection and Cell Imaging

Abstract

Keywords

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