Synthesis of diamond via low pressure polymer precursor using microwave plasma-two dimensional growth phenomena

Z. Sun; X. Shi; X. Wang; Y. Sun

doi:10.1016/S0921-5107(97)00017-2

Synthesis of diamond via low pressure polymer precursor using microwave plasma-two dimensional growth phenomena

Z. Sun, X. Shi, X. Wang, Y. Sun

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Diamond film can be synthesized from a phenylcarbyne polymer [C₆H₅C]_n which consists of randomly constructed rigid network of tetrahedral phenylcarbyne units, in hydrogen-acetone mixture by microwave plasma at low pressure. The diamond film contains diamond crystals with different size (from nanometers to micromerters). The diamond dendritic patterns and two-dimensional flattened diamond crystals has been observed after plasma treatment to the polymer. The experiment suggested that the polymer transformed to diamond is through an amorphous state, and two dimensional growth, i.e. layer by layer growth of diamond is possible using the polymer as a precursor.

Original language	English
Pages (from-to)	167-170
Number of pages	4
Journal	Materials Science and Engineering: B
Volume	47
Issue number	2
DOIs	https://doi.org/10.1016/S0921-5107(97)00017-2
State	Published - 15 Jun 1997
Externally published	Yes

Keywords

Diamond
Fractal pattern
Phase transformation
Polymer precursor

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10.1016/S0921-5107(97)00017-2

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title = "Synthesis of diamond via low pressure polymer precursor using microwave plasma-two dimensional growth phenomena",

abstract = "Diamond film can be synthesized from a phenylcarbyne polymer [C6H5C]n which consists of randomly constructed rigid network of tetrahedral phenylcarbyne units, in hydrogen-acetone mixture by microwave plasma at low pressure. The diamond film contains diamond crystals with different size (from nanometers to micromerters). The diamond dendritic patterns and two-dimensional flattened diamond crystals has been observed after plasma treatment to the polymer. The experiment suggested that the polymer transformed to diamond is through an amorphous state, and two dimensional growth, i.e. layer by layer growth of diamond is possible using the polymer as a precursor.",

keywords = "Diamond, Fractal pattern, Phase transformation, Polymer precursor",

author = "Z. Sun and X. Shi and X. Wang and Y. Sun",

year = "1997",

month = jun,

day = "15",

doi = "10.1016/S0921-5107(97)00017-2",

language = "英语",

volume = "47",

pages = "167--170",

journal = "Materials Science and Engineering: B",

issn = "0921-5107",

publisher = "Elsevier Ltd",

number = "2",

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TY - JOUR

T1 - Synthesis of diamond via low pressure polymer precursor using microwave plasma-two dimensional growth phenomena

AU - Sun, Z.

AU - Shi, X.

AU - Wang, X.

AU - Sun, Y.

PY - 1997/6/15

Y1 - 1997/6/15

N2 - Diamond film can be synthesized from a phenylcarbyne polymer [C6H5C]n which consists of randomly constructed rigid network of tetrahedral phenylcarbyne units, in hydrogen-acetone mixture by microwave plasma at low pressure. The diamond film contains diamond crystals with different size (from nanometers to micromerters). The diamond dendritic patterns and two-dimensional flattened diamond crystals has been observed after plasma treatment to the polymer. The experiment suggested that the polymer transformed to diamond is through an amorphous state, and two dimensional growth, i.e. layer by layer growth of diamond is possible using the polymer as a precursor.

AB - Diamond film can be synthesized from a phenylcarbyne polymer [C6H5C]n which consists of randomly constructed rigid network of tetrahedral phenylcarbyne units, in hydrogen-acetone mixture by microwave plasma at low pressure. The diamond film contains diamond crystals with different size (from nanometers to micromerters). The diamond dendritic patterns and two-dimensional flattened diamond crystals has been observed after plasma treatment to the polymer. The experiment suggested that the polymer transformed to diamond is through an amorphous state, and two dimensional growth, i.e. layer by layer growth of diamond is possible using the polymer as a precursor.

KW - Diamond

KW - Fractal pattern

KW - Phase transformation

KW - Polymer precursor

UR - https://www.scopus.com/pages/publications/0039124041

U2 - 10.1016/S0921-5107(97)00017-2

DO - 10.1016/S0921-5107(97)00017-2

M3 - 文章

AN - SCOPUS:0039124041

SN - 0921-5107

VL - 47

SP - 167

EP - 170

JO - Materials Science and Engineering: B

JF - Materials Science and Engineering: B

IS - 2

ER -

Synthesis of diamond via low pressure polymer precursor using microwave plasma-two dimensional growth phenomena

Abstract

Keywords

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