Synthesis of diamond-like carbon films from Polymer

Zhihao Zheng; Zhuo Sun; Qiheng Yang; Ning Xu

doi:10.1117/12.190824

Synthesis of diamond-like carbon films from Polymer

Zhihao Zheng, Zhuo Sun, Qiheng Yang, Ning Xu

School of Physics and Electronic Science

Research output: Contribution to journal › Conference article › peer-review

Abstract

Polymer (C₆H₆C)_n, (i.e.(RC)_n, R=Ph=Phenyl), synthesized by chemical reaction, is a pyrolytic precursor to carbon. The carbon-based network backbone structure in polymer, under pyrolysis, could be converted to hard, abrasive and highly reflective solid. The powder of this solid can easily scratch glass and quartz plates. After pyrolysis, the films, coated by using (RC)_n on various substracts Si, silica, Al₂O₃, exhibit linear temperature-dependence property of its electrical surface resistance. By SEM, diamond crystallites with grain size from several tens nanometers to several microns have been observed. It proves that under heat decomposition, carbon-based network backbone structures have converted to sp³-bonded carbon phases.

Original language	English
Pages (from-to)	566-569
Number of pages	4
Journal	Proceedings of SPIE - The International Society for Optical Engineering
Volume	2364
DOIs	https://doi.org/10.1117/12.190824
State	Published - 26 Oct 1994
Event	2nd International Conference on Thin Film Physics and Applications 1994 - Shanghai, China Duration: 15 Apr 1994 → 17 Apr 1994

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@article{36fa9cabe9f8409789ce253ed489458f,

title = "Synthesis of diamond-like carbon films from Polymer",

abstract = "Polymer (C6H6C)n, (i.e.(RC)n, R=Ph=Phenyl), synthesized by chemical reaction, is a pyrolytic precursor to carbon. The carbon-based network backbone structure in polymer, under pyrolysis, could be converted to hard, abrasive and highly reflective solid. The powder of this solid can easily scratch glass and quartz plates. After pyrolysis, the films, coated by using (RC)n on various substracts Si, silica, Al2O3, exhibit linear temperature-dependence property of its electrical surface resistance. By SEM, diamond crystallites with grain size from several tens nanometers to several microns have been observed. It proves that under heat decomposition, carbon-based network backbone structures have converted to sp3-bonded carbon phases.",

author = "Zhihao Zheng and Zhuo Sun and Qiheng Yang and Ning Xu",

note = "Publisher Copyright: {\textcopyright} 1994 SPIE. All rights reserved.; 2nd International Conference on Thin Film Physics and Applications 1994 ; Conference date: 15-04-1994 Through 17-04-1994",

year = "1994",

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day = "26",

doi = "10.1117/12.190824",

language = "英语",

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TY - JOUR

T1 - Synthesis of diamond-like carbon films from Polymer

AU - Zheng, Zhihao

AU - Sun, Zhuo

AU - Yang, Qiheng

AU - Xu, Ning

PY - 1994/10/26

Y1 - 1994/10/26

N2 - Polymer (C6H6C)n, (i.e.(RC)n, R=Ph=Phenyl), synthesized by chemical reaction, is a pyrolytic precursor to carbon. The carbon-based network backbone structure in polymer, under pyrolysis, could be converted to hard, abrasive and highly reflective solid. The powder of this solid can easily scratch glass and quartz plates. After pyrolysis, the films, coated by using (RC)n on various substracts Si, silica, Al2O3, exhibit linear temperature-dependence property of its electrical surface resistance. By SEM, diamond crystallites with grain size from several tens nanometers to several microns have been observed. It proves that under heat decomposition, carbon-based network backbone structures have converted to sp3-bonded carbon phases.

AB - Polymer (C6H6C)n, (i.e.(RC)n, R=Ph=Phenyl), synthesized by chemical reaction, is a pyrolytic precursor to carbon. The carbon-based network backbone structure in polymer, under pyrolysis, could be converted to hard, abrasive and highly reflective solid. The powder of this solid can easily scratch glass and quartz plates. After pyrolysis, the films, coated by using (RC)n on various substracts Si, silica, Al2O3, exhibit linear temperature-dependence property of its electrical surface resistance. By SEM, diamond crystallites with grain size from several tens nanometers to several microns have been observed. It proves that under heat decomposition, carbon-based network backbone structures have converted to sp3-bonded carbon phases.

UR - https://www.scopus.com/pages/publications/0028747331

U2 - 10.1117/12.190824

DO - 10.1117/12.190824

M3 - 会议文章

AN - SCOPUS:0028747331

SN - 0277-786X

VL - 2364

SP - 566

EP - 569

JO - Proceedings of SPIE - The International Society for Optical Engineering

JF - Proceedings of SPIE - The International Society for Optical Engineering

T2 - 2nd International Conference on Thin Film Physics and Applications 1994

Y2 - 15 April 1994 through 17 April 1994

ER -

Synthesis of diamond-like carbon films from Polymer

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