Synthesis of diamond from polymer seeded with nanometer-sized diamond particles

Xuejun Wang; Jingsheng Chen; Zhihao Zheng; Zhuo Sun; Fengyuan Yan

doi:10.1016/S0022-0248(97)00314-X

Synthesis of diamond from polymer seeded with nanometer-sized diamond particles

Xuejun Wang^*
, Jingsheng Chen
, Zhihao Zheng
, Zhuo Sun
, Fengyuan Yan

^*Corresponding author for this work

Research output: Contribution to journal › Letter › peer-review

12 Scopus citations

Abstract

In a hot-filament chemical vapor deposition reactor a carbon-based random network polymer [C₆H₅C]_n, poly(phenylcarbyne), consisting of randomly constructed rigid network of tetrahedral phenylcarbyne units, has been converted to diamond by heat treatment in a pure hydrogen atmosphere at low pressure. Raman spectroscopy analysis confirmed the conversion of this polymer to diamond by the presence of a sharp diamond characteristic peak at 1331 cm^-1. The morphology of the resulting samples was examined by scanning electron microscopy. The mechanism of conversion is discussed.

Original language	English
Pages (from-to)	308-313
Number of pages	6
Journal	Journal of Crystal Growth
Volume	181
Issue number	3
DOIs	https://doi.org/10.1016/S0022-0248(97)00314-X
State	Published - Nov 1997
Externally published	Yes

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@article{480c642eae7b411c8f6f04c419d321ab,

title = "Synthesis of diamond from polymer seeded with nanometer-sized diamond particles",

abstract = "In a hot-filament chemical vapor deposition reactor a carbon-based random network polymer [C6H5C]n, poly(phenylcarbyne), consisting of randomly constructed rigid network of tetrahedral phenylcarbyne units, has been converted to diamond by heat treatment in a pure hydrogen atmosphere at low pressure. Raman spectroscopy analysis confirmed the conversion of this polymer to diamond by the presence of a sharp diamond characteristic peak at 1331 cm-1. The morphology of the resulting samples was examined by scanning electron microscopy. The mechanism of conversion is discussed.",

author = "Xuejun Wang and Jingsheng Chen and Zhihao Zheng and Zhuo Sun and Fengyuan Yan",

year = "1997",

month = nov,

doi = "10.1016/S0022-0248(97)00314-X",

language = "英语",

volume = "181",

pages = "308--313",

journal = "Journal of Crystal Growth",

issn = "0022-0248",

publisher = "Elsevier B.V.",

number = "3",

}

TY - JOUR

T1 - Synthesis of diamond from polymer seeded with nanometer-sized diamond particles

AU - Wang, Xuejun

AU - Chen, Jingsheng

AU - Zheng, Zhihao

AU - Sun, Zhuo

AU - Yan, Fengyuan

PY - 1997/11

Y1 - 1997/11

N2 - In a hot-filament chemical vapor deposition reactor a carbon-based random network polymer [C6H5C]n, poly(phenylcarbyne), consisting of randomly constructed rigid network of tetrahedral phenylcarbyne units, has been converted to diamond by heat treatment in a pure hydrogen atmosphere at low pressure. Raman spectroscopy analysis confirmed the conversion of this polymer to diamond by the presence of a sharp diamond characteristic peak at 1331 cm-1. The morphology of the resulting samples was examined by scanning electron microscopy. The mechanism of conversion is discussed.

AB - In a hot-filament chemical vapor deposition reactor a carbon-based random network polymer [C6H5C]n, poly(phenylcarbyne), consisting of randomly constructed rigid network of tetrahedral phenylcarbyne units, has been converted to diamond by heat treatment in a pure hydrogen atmosphere at low pressure. Raman spectroscopy analysis confirmed the conversion of this polymer to diamond by the presence of a sharp diamond characteristic peak at 1331 cm-1. The morphology of the resulting samples was examined by scanning electron microscopy. The mechanism of conversion is discussed.

UR - https://www.scopus.com/pages/publications/0031275677

U2 - 10.1016/S0022-0248(97)00314-X

DO - 10.1016/S0022-0248(97)00314-X

M3 - 快报

AN - SCOPUS:0031275677

SN - 0022-0248

VL - 181

SP - 308

EP - 313

JO - Journal of Crystal Growth

JF - Journal of Crystal Growth

IS - 3

ER -

Synthesis of diamond from polymer seeded with nanometer-sized diamond particles

Abstract

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