Synthesis of derivatives of [1,3,4]thiadiazolo[3,2-C]-1,2,3-trihydro-[1,3,5,2]thiadiazaphosphorins

Tian Bao Huang; Ling Fei Liu; Wen Qian Yang; Xiao Ming Yu; Xu Hong Qian; Jing Ling Zhang

doi:10.1080/10426509708043518

Synthesis of derivatives of [1,3,4]thiadiazolo[3,2-C]-1,2,3-trihydro-[1,3,5,2]thiadiazaphosphorins

Tian Bao Huang^*
, Ling Fei Liu
, Wen Qian Yang
, Xiao Ming Yu
, Xu Hong Qian
, Jing Ling Zhang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The first dicyclic fused thiadiazaphosphorin derivatives, namely, [1,3,4]thiadiazolo[3,2-c]-1,2,3-trihydro-[1,3,5,2]thiadiazaphosphorins (3 and 4), were synthesized by intermolecular cyclocondensation of [1,3,4]thiadiazole-2-yl-dithiocarbamic acid (1) or -dithioperoxycarbamic acid (2) with tri(dialkylamino)phosphine. 5-methyl[1,3,4]thiadiazolo[3,2-c]-2-dialkylamino-6-thiono-1,2,3-trihydro-[1,3,5, 2]thiadiazaphosphorin (3) was easily oxided into the 5-methyl [1,3,4]thiadiazolo[3,2-c]-2-dialkylamino-6-thiono-2-oxo-1,2,3-trihydro-[1,3,5,2] thiadiazaphosphorin (4) and 5-methyl-[1,3,4]thiadiazolo[3,2-c]-2-dialkylamino-6-thiono-1,2-dioxo-1,2,3- trihydro-[1,3,5,2]thiadiazaphosphorin (5).

Original language	English
Pages (from-to)	299-305
Number of pages	7
Journal	Phosphorus, Sulfur and Silicon and the Related Elements
Volume	122
DOIs	https://doi.org/10.1080/10426509708043518
State	Published - 1997
Externally published	Yes

Keywords

Cyclocondensation
Tris(dialkylamino)phosphine
[1;3;4]Thiadiazolo[3;2-c][1;3;5;2]thiadiazaphosphorin

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@article{b3516dfc364a459399fc0d6285b5c619,

title = "Synthesis of derivatives of [1,3,4]thiadiazolo[3,2-C]-1,2,3-trihydro-[1,3,5,2]thiadiazaphosphorins",

abstract = "The first dicyclic fused thiadiazaphosphorin derivatives, namely, [1,3,4]thiadiazolo[3,2-c]-1,2,3-trihydro-[1,3,5,2]thiadiazaphosphorins (3 and 4), were synthesized by intermolecular cyclocondensation of [1,3,4]thiadiazole-2-yl-dithiocarbamic acid (1) or -dithioperoxycarbamic acid (2) with tri(dialkylamino)phosphine. 5-methyl[1,3,4]thiadiazolo[3,2-c]-2-dialkylamino-6-thiono-1,2,3-trihydro-[1,3,5, 2]thiadiazaphosphorin (3) was easily oxided into the 5-methyl [1,3,4]thiadiazolo[3,2-c]-2-dialkylamino-6-thiono-2-oxo-1,2,3-trihydro-[1,3,5,2] thiadiazaphosphorin (4) and 5-methyl-[1,3,4]thiadiazolo[3,2-c]-2-dialkylamino-6-thiono-1,2-dioxo-1,2,3- trihydro-[1,3,5,2]thiadiazaphosphorin (5).",

keywords = "Cyclocondensation, Tris(dialkylamino)phosphine, [1;3;4]Thiadiazolo[3;2-c][1;3;5;2]thiadiazaphosphorin",

author = "Huang, \{Tian Bao\} and Liu, \{Ling Fei\} and Yang, \{Wen Qian\} and Yu, \{Xiao Ming\} and Qian, \{Xu Hong\} and Zhang, \{Jing Ling\}",

year = "1997",

doi = "10.1080/10426509708043518",

language = "英语",

volume = "122",

pages = "299--305",

journal = "Phosphorus, Sulfur and Silicon and the Related Elements",

issn = "1042-6507",

publisher = "Taylor and Francis Ltd.",

}

TY - JOUR

T1 - Synthesis of derivatives of [1,3,4]thiadiazolo[3,2-C]-1,2,3-trihydro-[1,3,5,2]thiadiazaphosphorins

AU - Huang, Tian Bao

AU - Liu, Ling Fei

AU - Yang, Wen Qian

AU - Yu, Xiao Ming

AU - Qian, Xu Hong

AU - Zhang, Jing Ling

PY - 1997

Y1 - 1997

N2 - The first dicyclic fused thiadiazaphosphorin derivatives, namely, [1,3,4]thiadiazolo[3,2-c]-1,2,3-trihydro-[1,3,5,2]thiadiazaphosphorins (3 and 4), were synthesized by intermolecular cyclocondensation of [1,3,4]thiadiazole-2-yl-dithiocarbamic acid (1) or -dithioperoxycarbamic acid (2) with tri(dialkylamino)phosphine. 5-methyl[1,3,4]thiadiazolo[3,2-c]-2-dialkylamino-6-thiono-1,2,3-trihydro-[1,3,5, 2]thiadiazaphosphorin (3) was easily oxided into the 5-methyl [1,3,4]thiadiazolo[3,2-c]-2-dialkylamino-6-thiono-2-oxo-1,2,3-trihydro-[1,3,5,2] thiadiazaphosphorin (4) and 5-methyl-[1,3,4]thiadiazolo[3,2-c]-2-dialkylamino-6-thiono-1,2-dioxo-1,2,3- trihydro-[1,3,5,2]thiadiazaphosphorin (5).

AB - The first dicyclic fused thiadiazaphosphorin derivatives, namely, [1,3,4]thiadiazolo[3,2-c]-1,2,3-trihydro-[1,3,5,2]thiadiazaphosphorins (3 and 4), were synthesized by intermolecular cyclocondensation of [1,3,4]thiadiazole-2-yl-dithiocarbamic acid (1) or -dithioperoxycarbamic acid (2) with tri(dialkylamino)phosphine. 5-methyl[1,3,4]thiadiazolo[3,2-c]-2-dialkylamino-6-thiono-1,2,3-trihydro-[1,3,5, 2]thiadiazaphosphorin (3) was easily oxided into the 5-methyl [1,3,4]thiadiazolo[3,2-c]-2-dialkylamino-6-thiono-2-oxo-1,2,3-trihydro-[1,3,5,2] thiadiazaphosphorin (4) and 5-methyl-[1,3,4]thiadiazolo[3,2-c]-2-dialkylamino-6-thiono-1,2-dioxo-1,2,3- trihydro-[1,3,5,2]thiadiazaphosphorin (5).

KW - Cyclocondensation

KW - Tris(dialkylamino)phosphine

KW - [1;3;4]Thiadiazolo[3;2-c][1;3;5;2]thiadiazaphosphorin

UR - https://www.scopus.com/pages/publications/0031326280

U2 - 10.1080/10426509708043518

DO - 10.1080/10426509708043518

M3 - 文章

AN - SCOPUS:0031326280

SN - 1042-6507

VL - 122

SP - 299

EP - 305

JO - Phosphorus, Sulfur and Silicon and the Related Elements

JF - Phosphorus, Sulfur and Silicon and the Related Elements

ER -

Synthesis of derivatives of [1,3,4]thiadiazolo[3,2-C]-1,2,3-trihydro-[1,3,5,2]thiadiazaphosphorins

Abstract

Keywords

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