Synthesis of chiral guanidinium-based ionic liquids

Nan Wu; Hai Hong Wu; Yong Wen Jiang

Synthesis of chiral guanidinium-based ionic liquids

Nan Wu^*
, Hai Hong Wu
, Yong Wen Jiang

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Chiral guanidinium chloride salts were synthesized from 1,3-dimethyl-2-imidazolidinone and (S)-1-phenylethylamine. 14 ionic liquids with different anions were obtained by metathesis reactions of the chiral guanidinium chloride with MX and characterized by ¹H NMR, ¹³C NMR, ESI-MS, [α]_D²⁰ and TGA methods. These guanidinium-based ionic liquids are potential catalysts to some reactions such as asymmetric Henry reaction or Michael addition.

Original language	English
Pages (from-to)	104-110
Number of pages	7
Journal	Chinese Journal of Organic Chemistry
Volume	28
Issue number	1
State	Published - Jan 2008

Keywords

(S)-1-Phenylethylamine
1,3-Dimethyl-2-imidazolidinone
Chiral guanidine
Ionic liquid

Cite this

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title = "Synthesis of chiral guanidinium-based ionic liquids",

abstract = "Chiral guanidinium chloride salts were synthesized from 1,3-dimethyl-2-imidazolidinone and (S)-1-phenylethylamine. 14 ionic liquids with different anions were obtained by metathesis reactions of the chiral guanidinium chloride with MX and characterized by 1H NMR, 13C NMR, ESI-MS, [α]D20 and TGA methods. These guanidinium-based ionic liquids are potential catalysts to some reactions such as asymmetric Henry reaction or Michael addition.",

keywords = "(S)-1-Phenylethylamine, 1,3-Dimethyl-2-imidazolidinone, Chiral guanidine, Ionic liquid",

author = "Nan Wu and Wu, \{Hai Hong\} and Jiang, \{Yong Wen\}",

year = "2008",

month = jan,

language = "英语",

volume = "28",

pages = "104--110",

journal = "Chinese Journal of Organic Chemistry",

issn = "0253-2786",

publisher = "Science Press ",

number = "1",

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TY - JOUR

T1 - Synthesis of chiral guanidinium-based ionic liquids

AU - Wu, Nan

AU - Wu, Hai Hong

AU - Jiang, Yong Wen

PY - 2008/1

Y1 - 2008/1

N2 - Chiral guanidinium chloride salts were synthesized from 1,3-dimethyl-2-imidazolidinone and (S)-1-phenylethylamine. 14 ionic liquids with different anions were obtained by metathesis reactions of the chiral guanidinium chloride with MX and characterized by 1H NMR, 13C NMR, ESI-MS, [α]D20 and TGA methods. These guanidinium-based ionic liquids are potential catalysts to some reactions such as asymmetric Henry reaction or Michael addition.

AB - Chiral guanidinium chloride salts were synthesized from 1,3-dimethyl-2-imidazolidinone and (S)-1-phenylethylamine. 14 ionic liquids with different anions were obtained by metathesis reactions of the chiral guanidinium chloride with MX and characterized by 1H NMR, 13C NMR, ESI-MS, [α]D20 and TGA methods. These guanidinium-based ionic liquids are potential catalysts to some reactions such as asymmetric Henry reaction or Michael addition.

KW - (S)-1-Phenylethylamine

KW - 1,3-Dimethyl-2-imidazolidinone

KW - Chiral guanidine

KW - Ionic liquid

UR - https://www.scopus.com/pages/publications/41649106072

M3 - 文章

AN - SCOPUS:41649106072

SN - 0253-2786

VL - 28

SP - 104

EP - 110

JO - Chinese Journal of Organic Chemistry

JF - Chinese Journal of Organic Chemistry

IS - 1

ER -

Synthesis of chiral guanidinium-based ionic liquids

Abstract

Keywords

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