Synthesis of bi-((N-methyl-N′-benzyl)ethylenediamine) nickel(II) dichloride and studies on interaction of cucurbit[n=6-8]urils with nickel complex guest

Hang Cong; Fan Yang; Zhu Tao; Jian Xin Zhang

Synthesis of bi-((N-methyl-N′-benzyl)ethylenediamine) nickel(II) dichloride and studies on interaction of cucurbit[n=6-8]urils with nickel complex guest

Hang Cong^*
, Fan Yang
, Zhu Tao
, Jian Xin Zhang

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Bi-((N-methyl-N′-benzyl)ethylenediamine) Nickel(II) dichloride was synthesized and characterized by elemental analyses, IR and ¹H NMR techniques. The self-assembled structures of cucurbit[n]urils (n=6-8) with the title Ni complex guest were studied by ¹H NMR and UV-spectroscopy. The experimental results revealed clearly that the cucurbit [n=6 or 7] urils can form supermolecule structure with the metal complex guest in 1:2 mole ratio, and the complex guest can enter or leave the cavity of cucurbit[8]uril without obvious hindrance.

Original language	English
Article number	1001-4861(2005)03-0349-08
Pages (from-to)	349-356
Number of pages	8
Journal	Chinese Journal of Inorganic Chemistry
Volume	21
Issue number	3
State	Published - 1 Mar 2005

Keywords

Complex
Cucurbit[n]urils
Host-guest
Interaction

Cite this

@article{5f503196f85346e1b7807bbcf6a9e04c,

title = "Synthesis of bi-((N-methyl-N′-benzyl)ethylenediamine) nickel(II) dichloride and studies on interaction of cucurbit[n=6-8]urils with nickel complex guest",

abstract = "Bi-((N-methyl-N′-benzyl)ethylenediamine) Nickel(II) dichloride was synthesized and characterized by elemental analyses, IR and 1H NMR techniques. The self-assembled structures of cucurbit[n]urils (n=6-8) with the title Ni complex guest were studied by 1H NMR and UV-spectroscopy. The experimental results revealed clearly that the cucurbit [n=6 or 7] urils can form supermolecule structure with the metal complex guest in 1:2 mole ratio, and the complex guest can enter or leave the cavity of cucurbit[8]uril without obvious hindrance.",

keywords = "Complex, Cucurbit[n]urils, Host-guest, Interaction",

author = "Hang Cong and Fan Yang and Zhu Tao and Zhang, \{Jian Xin\}",

year = "2005",

month = mar,

day = "1",

language = "英语",

volume = "21",

pages = "349--356",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

number = "3",

}

Synthesis of bi-((N-methyl-N′-benzyl)ethylenediamine) nickel(II) dichloride and studies on interaction of cucurbit[n=6-8]urils with nickel complex guest. / Cong, Hang; Yang, Fan; Tao, Zhu et al.
In: Chinese Journal of Inorganic Chemistry, Vol. 21, No. 3, 1001-4861(2005)03-0349-08, 01.03.2005, p. 349-356.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis of bi-((N-methyl-N′-benzyl)ethylenediamine) nickel(II) dichloride and studies on interaction of cucurbit[n=6-8]urils with nickel complex guest

AU - Cong, Hang

AU - Yang, Fan

AU - Tao, Zhu

AU - Zhang, Jian Xin

PY - 2005/3/1

Y1 - 2005/3/1

N2 - Bi-((N-methyl-N′-benzyl)ethylenediamine) Nickel(II) dichloride was synthesized and characterized by elemental analyses, IR and 1H NMR techniques. The self-assembled structures of cucurbit[n]urils (n=6-8) with the title Ni complex guest were studied by 1H NMR and UV-spectroscopy. The experimental results revealed clearly that the cucurbit [n=6 or 7] urils can form supermolecule structure with the metal complex guest in 1:2 mole ratio, and the complex guest can enter or leave the cavity of cucurbit[8]uril without obvious hindrance.

AB - Bi-((N-methyl-N′-benzyl)ethylenediamine) Nickel(II) dichloride was synthesized and characterized by elemental analyses, IR and 1H NMR techniques. The self-assembled structures of cucurbit[n]urils (n=6-8) with the title Ni complex guest were studied by 1H NMR and UV-spectroscopy. The experimental results revealed clearly that the cucurbit [n=6 or 7] urils can form supermolecule structure with the metal complex guest in 1:2 mole ratio, and the complex guest can enter or leave the cavity of cucurbit[8]uril without obvious hindrance.

KW - Complex

KW - Cucurbit[n]urils

KW - Host-guest

KW - Interaction

UR - https://www.scopus.com/pages/publications/15944403973

M3 - 文章

AN - SCOPUS:15944403973

SN - 1001-4861

VL - 21

SP - 349

EP - 356

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 3

M1 - 1001-4861(2005)03-0349-08

ER -

Synthesis of bi-((N-methyl-N′-benzyl)ethylenediamine) nickel(II) dichloride and studies on interaction of cucurbit[n=6-8]urils with nickel complex guest

Abstract

Keywords

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