Synthesis of acetals or ketals over zeolite Hβ catalyst

Xuezheng Liang; Xinyu Yu; Huiqi Peng; Shan Gao; Jianguo Yang; Mingyuan He

Synthesis of acetals or ketals over zeolite Hβ catalyst

Xuezheng Liang, Xinyu Yu, Huiqi Peng, Shan Gao, Jianguo Yang, Mingyuan He

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

Abstract

The acetalization and ketalization of various aldehydes or ketones, i.e., cyclohexanone, butanone, acetone, propionaldehyde, butyraldehyde, isobutyraldehyde, valeraldehyde, isopentyl aldehyde, octyl aldehyde, and benzaldehyde, with glycol on zeolite Hβ catalyst were studied. Effects of reaction conditions, (reaction time, mole ratio of aldehydes or ketones to glycol, and catalyst dosage), on reaction were investigated. Zeolite Hβ was an efficient catalyst for acetalization and ketalization with high conversion and selectivity under mild reaction conditions. Optimal reaction conditions were: mole ratio of aldehydes or ketones to glycol 1:1.2, catalyst dosage (1 mole aldehydes or ketones) 2 g, and reaction time 2 hr. Under optimal reaction conditions, conversion of aldehydes or ketones and selectivity of acetals or ketals were > 90 and 98%, respectively.

Original language	English
Pages (from-to)	1083-1085
Number of pages	3
Journal	Petrochemical Technology
Volume	34
Issue number	11
State	Published - 15 Nov 2005

Keywords

Acetal
Aldehyde
Catalyst
Glycol
Ketal
Ketone
Synthesis
Zeolite β

Cite this

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title = "Synthesis of acetals or ketals over zeolite Hβ catalyst",

abstract = "The acetalization and ketalization of various aldehydes or ketones, i.e., cyclohexanone, butanone, acetone, propionaldehyde, butyraldehyde, isobutyraldehyde, valeraldehyde, isopentyl aldehyde, octyl aldehyde, and benzaldehyde, with glycol on zeolite Hβ catalyst were studied. Effects of reaction conditions, (reaction time, mole ratio of aldehydes or ketones to glycol, and catalyst dosage), on reaction were investigated. Zeolite Hβ was an efficient catalyst for acetalization and ketalization with high conversion and selectivity under mild reaction conditions. Optimal reaction conditions were: mole ratio of aldehydes or ketones to glycol 1:1.2, catalyst dosage (1 mole aldehydes or ketones) 2 g, and reaction time 2 hr. Under optimal reaction conditions, conversion of aldehydes or ketones and selectivity of acetals or ketals were > 90 and 98\%, respectively.",

keywords = "Acetal, Aldehyde, Catalyst, Glycol, Ketal, Ketone, Synthesis, Zeolite β",

author = "Xuezheng Liang and Xinyu Yu and Huiqi Peng and Shan Gao and Jianguo Yang and Mingyuan He",

year = "2005",

month = nov,

day = "15",

language = "英语",

volume = "34",

pages = "1083--1085",

journal = "Petrochemical Technology",

issn = "1000-8144",

publisher = "Beijing Research Institute of Chemical Industry",

number = "11",

}

TY - JOUR

T1 - Synthesis of acetals or ketals over zeolite Hβ catalyst

AU - Liang, Xuezheng

AU - Yu, Xinyu

AU - Peng, Huiqi

AU - Gao, Shan

AU - Yang, Jianguo

AU - He, Mingyuan

PY - 2005/11/15

Y1 - 2005/11/15

N2 - The acetalization and ketalization of various aldehydes or ketones, i.e., cyclohexanone, butanone, acetone, propionaldehyde, butyraldehyde, isobutyraldehyde, valeraldehyde, isopentyl aldehyde, octyl aldehyde, and benzaldehyde, with glycol on zeolite Hβ catalyst were studied. Effects of reaction conditions, (reaction time, mole ratio of aldehydes or ketones to glycol, and catalyst dosage), on reaction were investigated. Zeolite Hβ was an efficient catalyst for acetalization and ketalization with high conversion and selectivity under mild reaction conditions. Optimal reaction conditions were: mole ratio of aldehydes or ketones to glycol 1:1.2, catalyst dosage (1 mole aldehydes or ketones) 2 g, and reaction time 2 hr. Under optimal reaction conditions, conversion of aldehydes or ketones and selectivity of acetals or ketals were > 90 and 98%, respectively.

AB - The acetalization and ketalization of various aldehydes or ketones, i.e., cyclohexanone, butanone, acetone, propionaldehyde, butyraldehyde, isobutyraldehyde, valeraldehyde, isopentyl aldehyde, octyl aldehyde, and benzaldehyde, with glycol on zeolite Hβ catalyst were studied. Effects of reaction conditions, (reaction time, mole ratio of aldehydes or ketones to glycol, and catalyst dosage), on reaction were investigated. Zeolite Hβ was an efficient catalyst for acetalization and ketalization with high conversion and selectivity under mild reaction conditions. Optimal reaction conditions were: mole ratio of aldehydes or ketones to glycol 1:1.2, catalyst dosage (1 mole aldehydes or ketones) 2 g, and reaction time 2 hr. Under optimal reaction conditions, conversion of aldehydes or ketones and selectivity of acetals or ketals were > 90 and 98%, respectively.

KW - Acetal

KW - Aldehyde

KW - Catalyst

KW - Glycol

KW - Ketal

KW - Ketone

KW - Synthesis

KW - Zeolite β

UR - https://www.scopus.com/pages/publications/28244465711

M3 - 文章

AN - SCOPUS:28244465711

SN - 1000-8144

VL - 34

SP - 1083

EP - 1085

JO - Petrochemical Technology

JF - Petrochemical Technology

IS - 11

ER -

Synthesis of acetals or ketals over zeolite Hβ catalyst

Abstract

Keywords

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