Synthesis of a hierarchically macro-/mesoporous zeolite based on a micro-emulsion mechanism

Hua Li; Junjiang Jin; Wei Wu; Chongcheng Chen; Liang Li; Yongshen Li; Wenru Zhao; Jinlou Gu; Guorong Chen; Jian Lin Shi

doi:10.1039/c1jm14249f

Synthesis of a hierarchically macro-/mesoporous zeolite based on a micro-emulsion mechanism

Hua Li
, Junjiang Jin
, Wei Wu
, Chongcheng Chen
, Liang Li
, Yongshen Li
, Wenru Zhao
, Jinlou Gu
, Guorong Chen
, Jian Lin Shi^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

A new type of hierarchically porous ZSM-5-type zeolite, Hp-ZSM, with well defined macro-/meso-/microporous structures was facilely synthesized via a simple steam-assisted conversion route in the presence of ethanol. This novel material exhibits a tri-modal porous structure: a macroporous network with macropore sizes of 50-200 nm; a well defined mesoporous structure of pore size around 2.5 nm in the macroporous framework and a typical microporous ZSM-5 structure in the mesoporous framework. A micro-emulsion mechanism was proposed for the formation of the macroporosity where ethanol is assumed to form 'oil' droplets in the water phase in the presence of surfactants.

Original language	English
Pages (from-to)	19395-19401
Number of pages	7
Journal	Journal of Materials Chemistry
Volume	21
Issue number	48
DOIs	https://doi.org/10.1039/c1jm14249f
State	Published - 28 Dec 2011
Externally published	Yes

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abstract = "A new type of hierarchically porous ZSM-5-type zeolite, Hp-ZSM, with well defined macro-/meso-/microporous structures was facilely synthesized via a simple steam-assisted conversion route in the presence of ethanol. This novel material exhibits a tri-modal porous structure: a macroporous network with macropore sizes of 50-200 nm; a well defined mesoporous structure of pore size around 2.5 nm in the macroporous framework and a typical microporous ZSM-5 structure in the mesoporous framework. A micro-emulsion mechanism was proposed for the formation of the macroporosity where ethanol is assumed to form 'oil' droplets in the water phase in the presence of surfactants.",

author = "Hua Li and Junjiang Jin and Wei Wu and Chongcheng Chen and Liang Li and Yongshen Li and Wenru Zhao and Jinlou Gu and Guorong Chen and Shi, \{Jian Lin\}",

year = "2011",

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doi = "10.1039/c1jm14249f",

language = "英语",

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AU - Li, Hua

AU - Jin, Junjiang

AU - Wu, Wei

AU - Chen, Chongcheng

AU - Li, Liang

AU - Li, Yongshen

AU - Zhao, Wenru

AU - Gu, Jinlou

AU - Chen, Guorong

AU - Shi, Jian Lin

PY - 2011/12/28

Y1 - 2011/12/28

N2 - A new type of hierarchically porous ZSM-5-type zeolite, Hp-ZSM, with well defined macro-/meso-/microporous structures was facilely synthesized via a simple steam-assisted conversion route in the presence of ethanol. This novel material exhibits a tri-modal porous structure: a macroporous network with macropore sizes of 50-200 nm; a well defined mesoporous structure of pore size around 2.5 nm in the macroporous framework and a typical microporous ZSM-5 structure in the mesoporous framework. A micro-emulsion mechanism was proposed for the formation of the macroporosity where ethanol is assumed to form 'oil' droplets in the water phase in the presence of surfactants.

AB - A new type of hierarchically porous ZSM-5-type zeolite, Hp-ZSM, with well defined macro-/meso-/microporous structures was facilely synthesized via a simple steam-assisted conversion route in the presence of ethanol. This novel material exhibits a tri-modal porous structure: a macroporous network with macropore sizes of 50-200 nm; a well defined mesoporous structure of pore size around 2.5 nm in the macroporous framework and a typical microporous ZSM-5 structure in the mesoporous framework. A micro-emulsion mechanism was proposed for the formation of the macroporosity where ethanol is assumed to form 'oil' droplets in the water phase in the presence of surfactants.

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DO - 10.1039/c1jm14249f

M3 - 文章

AN - SCOPUS:82455174301

SN - 0959-9428

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SP - 19395

EP - 19401

JO - Journal of Materials Chemistry

JF - Journal of Materials Chemistry

IS - 48

ER -

Synthesis of a hierarchically macro-/mesoporous zeolite based on a micro-emulsion mechanism

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