Synthesis of 2-butanone in carbon dioxide-enriched near-critical water

  • Yan Yang*
  • , Li Yi Dai
  • , Jin Shou Wang
  • , Ai Nong Yu
  • , Xin Yu Shi
  • , Hong Yan Zhou
  • *Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

2-Butaneone was synthesized from pinacol rearrangement of 2,3-butanediol (BDL) dehydration by using a cleaner and more environment benign approcah, which reaction systhem was in near-critical water (NCW). The result showed that the addition of carbon dioxide was benefit for the conversiotn of BDL while was not advantageous for the yeild of 2-butaneone. According the experimental results, the mechanism of dehydration of BDL in NCW was proposed.

Original languageEnglish
Title of host publicationICEOE 2011 - 2011 International Conference on Electronics and Optoelectronics, Proceedings
PagesV1305-V1308
DOIs
StatePublished - 2011
Event2011 International Conference on Electronics and Optoelectronics, ICEOE 2011 - Dalian, China
Duration: 29 Jul 201131 Jul 2011

Publication series

NameICEOE 2011 - 2011 International Conference on Electronics and Optoelectronics, Proceedings
Volume1

Conference

Conference2011 International Conference on Electronics and Optoelectronics, ICEOE 2011
Country/TerritoryChina
CityDalian
Period29/07/1131/07/11

Keywords

  • 2,3-Butanediol
  • Dehydration
  • Near-critical water
  • Rearrangement

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