Synthesis of 1,4-diarylfluorenone and 1,4-diarylfluorene

Yanmei Wang; Qiancai Liu; Xiaoli Xiong; Shiming Deng; Jun Zhang; Min Zhu; Hangmin Ge

doi:10.3987/COM-13-12813

Synthesis of 1,4-diarylfluorenone and 1,4-diarylfluorene

Yanmei Wang^*, Qiancai Liu, Xiaoli Xiong, Shiming Deng, Jun Zhang, Min Zhu, Hangmin Ge

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

Abstract

A novel synthetic route to 1,4-diarylfluorenone and 1,4-diarylfluorene is presented by starting with ninhydrin. The retro-Diels-Alder cycloaddition was employed as a key step to construct the target fluorenones, while a highly efficient reduction from 1,4-diarylfluorenones to 1,4-diarylfluorenes is developed by using of sodium sulfide nonahydrate as reductant. The final products are confirmed by 1H NMR, 13C NMR and mass spectrometry.

Original language	English
Pages (from-to)	2333-2341
Number of pages	9
Journal	Heterocycles
Volume	87
Issue number	11
DOIs	https://doi.org/10.3987/COM-13-12813
State	Published - 2013

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title = "Synthesis of 1,4-diarylfluorenone and 1,4-diarylfluorene",

abstract = "A novel synthetic route to 1,4-diarylfluorenone and 1,4-diarylfluorene is presented by starting with ninhydrin. The retro-Diels-Alder cycloaddition was employed as a key step to construct the target fluorenones, while a highly efficient reduction from 1,4-diarylfluorenones to 1,4-diarylfluorenes is developed by using of sodium sulfide nonahydrate as reductant. The final products are confirmed by 1H NMR, 13C NMR and mass spectrometry.",

author = "Yanmei Wang and Qiancai Liu and Xiaoli Xiong and Shiming Deng and Jun Zhang and Min Zhu and Hangmin Ge",

year = "2013",

doi = "10.3987/COM-13-12813",

language = "英语",

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pages = "2333--2341",

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T1 - Synthesis of 1,4-diarylfluorenone and 1,4-diarylfluorene

AU - Wang, Yanmei

AU - Liu, Qiancai

AU - Xiong, Xiaoli

AU - Deng, Shiming

AU - Zhang, Jun

AU - Zhu, Min

AU - Ge, Hangmin

PY - 2013

Y1 - 2013

N2 - A novel synthetic route to 1,4-diarylfluorenone and 1,4-diarylfluorene is presented by starting with ninhydrin. The retro-Diels-Alder cycloaddition was employed as a key step to construct the target fluorenones, while a highly efficient reduction from 1,4-diarylfluorenones to 1,4-diarylfluorenes is developed by using of sodium sulfide nonahydrate as reductant. The final products are confirmed by 1H NMR, 13C NMR and mass spectrometry.

AB - A novel synthetic route to 1,4-diarylfluorenone and 1,4-diarylfluorene is presented by starting with ninhydrin. The retro-Diels-Alder cycloaddition was employed as a key step to construct the target fluorenones, while a highly efficient reduction from 1,4-diarylfluorenones to 1,4-diarylfluorenes is developed by using of sodium sulfide nonahydrate as reductant. The final products are confirmed by 1H NMR, 13C NMR and mass spectrometry.

UR - https://www.scopus.com/pages/publications/84887084893

U2 - 10.3987/COM-13-12813

DO - 10.3987/COM-13-12813

M3 - 文章

AN - SCOPUS:84887084893

SN - 0385-5414

VL - 87

SP - 2333

EP - 2341

JO - Heterocycles

JF - Heterocycles

IS - 11

ER -

Synthesis of 1,4-diarylfluorenone and 1,4-diarylfluorene

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